Now showing 1 - 10 of 38
  • Publication
    Remazol orange dye sensitized solar cell
    Water based Remazol Orange was utilized as the dye sensitizer for dye sensitized solar cell. The annealing temperature of TiO2 working electrode was set at 450 °C. The performance of the device was investigated between dye concentrations of 0.25 mM and 2.5 mM at three different immersion times (3, 12 and 24 hours). The adsorption peak of the dye sensitizer was evaluated using UV-Vis-Nir and the device performance was tested using solar cell simulator. The results show that the performance was increased at higher dye concentration and longer immersion time. The best device performance was obtained at 0.2% for dye concentration of 2.5 mM immersed at 24 hours.
  • Publication
    Effect of sodium ion addition on copper selenide/chitosan film towards electrical and shielding efficiency improvement
    ( 2024-06)
    Nurul Najiha Mazu
    ;
    Hazeem Ikhwan Mazlan
    ;
    Josephine Ying Chyi Liew
    ;
    Nurul Huda Osman
    ;
    ;
    Ali Reshak
    The operation of electronic devices can be disrupted by unwanted electromagnetic signals, affecting its operation. Deploying electromagnetic shielding is a viable solution to minimize the impact of electromagnetic interference (EMI). The conventional methods of electromagnetic shielding use metal gaskets to safeguard sensitive electronic components, which have drawbacks of cost and weight. Hence, electromagnetic shielding polymer can be an alternative to replace metal gaskets. This work investigates the effect of sodium ion (Na) addition to copper selenide/chitosan (CuSe/Ch) film for electromagnetic shielding applications. The shielding polymers were produced using solution casting methods, while the CuSe was synthesized using the chemical coprecipitation method. Impedance spectroscopy and two port waveguide methods were used to characterize the prepared polymer's electrical properties and shielding efficiency. The results indicate that Na incorporation in the CuSe/Ch film resulted in a 47 % decrease in bulk resistivity and increased DC conductivity from 6.07 × 10-6 S/cm to 3.69 × 10˗5 S/cm. The AC conductivity of films containing Na demonstrates a similar level of conductivity at lower frequencies, followed by a sharp increase at higher frequencies, indicating a more substantial influence of Na at higher frequencies. Higher absorption shielding efficiency (SEA) and lower reflection shielding efficiency (SER) were achieved by introducing Na into the CuSe chitosan film. The Na/CuSe/Ch film shows higher total shielding efficiency at an average of 20 dB, equivalent to 99 % of the EM power shield.
  • Publication
    Single wall carbon nanotubes dispersion study of different dye molecules and chitosan
    Carbon Nanotubes (CNTs) is known for their hydrophobicity ability. However, this ability can become the bottleneck for the application of CNTs where a highly dispersion of materials are needed. In this project, different dispersing agents were investigated namely dye molecules and chitosan. Three different dyes are studied with different concentration, including 0.05 % of chitosan. The dispersion quality is determined by examining through UV-Vis-NIR. The best dispersion quality investigated here is when the concentration of dye molecules is higher, which is around 2.5 mM.
  • Publication
    Effect of Ni on the suppression of sn whisker formation in Sn-0.7Cu solder joint
    ( 2021) ; ;
    Andrei Victor Sandu
    ;
    ; ;
    Noor Zaimah Mohd Mokhtar
    ;
    Jitrin Chaiprapa
    The evolution of internal compressive stress from the intermetallic compound (IMC) Cu6Sn5 growth is commonly acknowledged as the key inducement initiating the nucleation and growth of tin (Sn) whisker. This study investigates the effect of Sn-0.7Cu-0.05Ni on the nucleation and growth of Sn whisker under continuous mechanical stress induced. The Sn-0.7Cu-0.05Ni solder joint has a noticeable effect of suppression by diminishing the susceptibility of nucleation and growth of Sn whisker. By using a synchrotron micro X-ray fluorescence (µ-XRF) spectroscopy, it was found that a small amount of Ni alters the microstructure of Cu6Sn5 to form a (Cu,Ni)6Sn5 intermetallic layer. The morphology structure of the (Cu,Ni)6Sn5 interfacial intermetallic layer and Sn whisker growth were investigated by scanning electron microscope (SEM) in secondary and backscattered electron imaging mode, which showed that there is a strong correlation between the formation of Sn whisker and the composition of solder alloy. The thickness of the (Cu,Ni)6Sn5 IMC interfacial layer was relatively thinner and more refined, with a continuous fine scallop-shaped IMC interfacial layer, and consequently enhanced a greater incubation period for the nucleation and growth of the Sn whisker. These verification outcomes proposes a scientifically foundation to mitigate Sn whisker growth in lead-free solder joint.
  • Publication
    Remazol orange dye sensitized solar cell using graphene oxide and reduced graphene oxide working electrode
    (Universiti Malaysia Perlis (UniMAP), 2018-12) ;
    Siti S. Mat isa
    ;
    ;
    N. Rosli
    Dye Sensitized Solar Cell (DSSC) is said as a potential solar device which offers easy, cheaper and greener materials and preparation process. However, the efficiency of this device is still an ultimate problem and challenge. In this paper, an organic Remazol orange dye was used as the DSSC dye sensitizer which prepared with different working electrodes. The different working electrodes consist of Titanium Dioxide (TiO2) with Graphene Oxide (GO) and TiO2 with reduced Graphene Oxide (rGO). In order to analyze the adsorption characteristics of GO and rGO, the solution was tested using Ultraviolet-Visible-Near Infrared Spectrophotometry and the surface morphology of all mixed pastes was observed under Atomic Force Microscopy and Scanning Electron Microscope. Then, the device performance was tested under illumination of solar cell simulator. From overall results, the efficiency for all tested devices was quite low from expectation. For this work, the performance of TiO2-rGO DSSC at 0.138% is 84.7% higher compared to the TiO2-GO DSSC which was 0.021%. This result was obtained when the working electrode and dye less exposed to the light during dye preparation process at 24 hours soaking time.
  • Publication
    Automated monitoring system for transmission system laboratory model
    (Universiti Malaysia Perlis (UniMAP), 2018-12)
    MN Mohtar
    ;
    MA Osman
    ;
    Transmission System Laboratory Model (TSLM) is a model of power transmission systems use to facilitate the studies of power system. TSLM replicates a power transmission system mimicking the real transmission line. The input and output voltage reading on the current TSLM requires a manual measurement using multimeter. The lack of real time monitoring is rectified in this work. This works propose an automated real time measurement and display system for real time voltage input and output monitoring on the TSLM. An imbedded custom made digital voltmeter and a digital display is used for real time monitoring.
  • Publication
    rGO-SWCNT hybrid for counter electrode in dye sensitized solar cell
    (Universiti Malaysia Perlis (UniMAP), 2018-12)
    M. R. Muda
    ;
    Siti S. Mat Isa
    ;
    Towards platinum free counter electrode in dye sensitized solar cells, some carbon-based materials like carbon nanotubes and graphene are fully utilized due to their extraordinary properties such as high aspect ratio and conductivity. In this paper, single-walled carbon nanotubes (SWCNT), reduced graphene oxide (rGO) and hybrid structure of rGO-SWCNT spray coated counter electrodes were compared with graphite as the reference material. The morphology of these materials was analyzed with FESEM and FTIR. The DSSC performance was then measured using solar simulator. The current-voltage (I-V) characteristics show that the rGO-SWCNT counter electrode result the excellent performance with efficiency of ~1.86 %, 95.2 % better than graphite. This higher performance was attributed by the complete oxygen-functional group removal during reduction process which offers large active surface area for electro-photocatalytic activity, higher conductivity, better structure and properties compared to the individual forms.
  • Publication
    Optimization of soaking time for graphitization of oil palm trunk waste
    (AIP Publishing, 2023) ; ; ;
    H. S. S. A. Syed
    ;
    R. M. S. Syah
    Synthetic graphite was synthesized from oil palm trunk chip in controlled heating condition or pyrolysis process. The soaking time was varied in the range of 2.5 hours, 3 hours, and 3.5 hours. While the heating rate and heating temperature was constant at 20 °/min and 500°C accordingly. After heat treatment process, the samples were characterized by X-Ray Diffraction (XRD) and analyzed using X'Pert Highscore Plus software. Synthetic graphite phase was analyzed by XRD and it was further supported by Fourier Transform Infrared (FTIR) Spectroscopy analysis to verify existence of functional group. The morphological study was carried out by using Scanning Electron Microscope (SEM). Based on the analysis, it was confirmed that synthetic graphite was successfully synthesized at 3hours soaking time with 500 °C and 20 °/min heating rate. Synthetic graphite was observed in the form of amorphous carbon based on the XRD diffraction pattern that match with the reference code of 00-041-1487.
      20  2
  • Publication
    Surface Modification of GO/TiO2 Thin Film by Sodium Dodecyl Sulphate for Photocatalytic Applications
    Photocatalyst material titanium dioxide (TiO2) and graphene oxide (GO) were used to improve the self-cleaning properties of thin films. The sol–gel spin-coating method was successfully used to synthesize GO/TiO2 thin films. Surface modification was applied to optimize the self-cleaning capabilities by adding several concentrations of sodium dodecyl sulfate (SDS) (0.1 w/v%, 0.2 w/v%, 0.3 w/v%, 0.4 w/v%, and 0.5 w/v%) to the parent solution. The synthesized thin films were investigated using scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray diffraction, UV-visible spectroscopy, water contact angle analysis, and photocatalytic analysis. The AFM and SEM images revealed that as the SDS amount increased, the particles became less agglomerated, and the roughness of the surface reduced from 2.54 × 102 nm to 0.83 × 102 nm. The wettability analysis showed that when SDS increased to 0.4 w/v%, the water contact angle dropped to 15.30°, implying that the thin film exhibits hydrophilic qualities. A decrease in the GO/TiO2 band gap was obtained linearly with the increase in SDS addition from 3.17 eV to 2.75 eV. Finally, the improvement of the surface coating and reduction of the band gap enhanced the photocatalytic activity, which degraded 78.97% of methylene blue, which was obtained by 0.4SDS.
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  • Publication
    The effect of GO/TiO2 thin film during photodegradation of methylene blue dye
    Titanium (IV) isopropoxide (TTIP) was used to synthesize GO/TiO2 thin films using a sol-gel spin-coating method onto a glass substrate, undergoing an heat tretment at 350 °C. Several amounts of graphene oxide (GO) (0-20mg) were weighed into a sol solution of TiO2 to produce GO/TiO2 thin films. The thin film samples were characterized by X-ray diffraction (XRD) to analyze the samples’ phase and by scanning electron microscopy (SEM) to analyze the samples’ microstructure. Physical testing such as water contact angle (WCA) was analyzed using an optical microscope with J-Image software. In contrast, the optical band gap and photodegradation of methylene blue under sunlight irradiation of the thin film was analyzed using UV-VIS spectrophotometry. GO5 thin film sample showed low-intensity anatase phase formation, where the microstructure revealed a larger surface area with the addition of GO. WCA reveals that GO/TiO2 thin film exhibits super hydrophilic properties where the angle decreases from 37.83° to 4.11°. The optical result shows that GO has improved the absorption edges by expanding into visible regions. Moreover, due to the existence of GO 3.30 eV band gap energy of TiO2 decreases from to 3.18 eV obtained by GO5. The improved adsorption edge allows Ti3+, O2 and interstitial states to be formed in low valence states with energy underneath than in the TiO2 band gap. Therefore, the photodegradation of methylene blue (MB) dye increases from 48 % to 59 % in the GO/TiO2 thin film.
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