Safizan Shaari
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Safizan Shaari
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Safizan, Shaari
Alternative Name
Shaari, Safizan
Shaari, S.
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Scopus Author ID
55807708700
Researcher ID
AAR-5562-2021

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  • Publication
    The effect of solvents on the performance of organic light-emitting diodes
    ( 2020-01-08)
    Ismail N.A.N.
    ;
    Safizan Shaari
    ;
    Juhari N.
    ;
    Norhayati Sabani
    ;
    Mohd Fairus Ahmad
    ;
    Zakaria N.F.
    In this paper, we investigate the solvent effect on the performance of surface roughness, absorption spectrum of MEH-PPV thin films and J-V characteristics for MEH-PPV OLED device. The 5 mg emissive layer of poly [2-methoxy-5(2' -ethylhexyloxy)-1, 4-phenylenevinylene), MEH-PPV was diluted with 1ml toluene and 1 ml different mixture of solvent (80% toluene+20 % chloroform) which gives the concentration of 5 mgml-1 respectively. The surface roughness of MEH-PPV film was reduced to 0.3 nm and the red-shifted maximum peak wavelength value were obtained when mixture solvent was used. However, J-V gives higher turn on voltage ∼17 V for the device used mixture solvent compared to device prepared by toluene solvent. Apparently, the two different combination of aromatic and non-aromatic solvent significantly gives an effect on thin films properties and electrical properties of MEH-PPV OLED device.
  • Publication
    Numerical Simulation and Parameters Variation of Silicon Based Self-Switching Diode (SSD) and the Effect to the Physical and Electrical Properties
    ( 2020-12-14)
    Tan Y.L.
    ;
    Zakaria N.F.
    ;
    Shahrir Rizal Kasjoo
    ;
    Safizan Shaari
    ;
    Muammar Mohamad Isa
    ;
    Mohd Khairuddin Md Arshad
    ;
    Rahim A.F.A.
    Investigation of SOI based self-switching diode (SSD) by numerical simulation for RF -DC harvesting application is presented. The rectification performance of the SSD is based on the curvature coefficient, ? and current responsivity, ß which are closely related to the I-V characteristic of a non-linear device. In this work, the structural parameters are varied to observe the electrical and physical characteristics with the aid of ATLAS Silvaco simulation tools. The rectification performance in each variation is then compared, with the highest value of ? and ß observed at 25.20 V and 12.60 V, respectively. By identifying and understanding these control factors and their effects, distinctive variations of the structural parameters by using a more deliberate optimization method can be proposed for further improvement on the rectification performance.
  • Publication
    Visible Light-Assisted Charge Extraction in High-Band-Gap SrTiO3 through the Integration of a Triplet Sensitizer-Emitter Thin Film
    ( 2024-01-22)
    Jie K.V.Y.
    ;
    Mohd Fairus Ahmad
    ;
    Mohmad A.R.
    ;
    Ismail A.M.
    ;
    Mohd Natashah Norizan
    ;
    Ramli M.M.
    ;
    Safizan Shaari
    ;
    Sulaiman Y.
    ;
    Shamsul Amir Abdul Rais
    ;
    Shazlina Johari
    A challenge in PV designs, including those with an electron transport layer (ETL), is the presence of ‘parasitic absorbers’. These are layers that absorb light without significantly converting it to electrical current, impacting the total external quantum efficiency (EQE). Strontium titanate (STO), a high-band-gap (3.20 eV) perovskite metal oxide, holds promise as an electron transport layer (ETL) for solar energy harvesting. Despite STO’s potential, it primarily operates in the UV spectrum, not fully utilizing the broader light range, and hence can be the source of parasitic absorbers. In this study, we report a significant enhancement in the EQE of STO through the integration of a triplet sensitizer-emitter (TSE) system, designed to upconvert the visible spectrum into UV light and improve the charge extraction from STO. The TSE system uses carbazolyl dicyanobenzene (4CzIPN) as a sensitizer and p-terphenyl (TP) as an emitter. To investigate the EQE of such a system, we fabricate STO as a PV cell. The revised PV cell architecture (ITO/TiO2/STO/TSE/PEDOT:PSS/Al) is a modification of the conventional configurations (ITO/TiO2/STO/PEDOT:PSS/Al). With the TSE thin film, the modified STO PV cell shows better charge extraction under sunlight compared to the standard STO PV cell, indicating that the upconversion process can enhance the hole conductions from STO to PEDOT:PSS through the TSE system. We noted an EQE increase with intense light of λ > 345 nm in thicker TSE layers and a decrease in the EQE under similar light intensity in thinner TSE layers. The Kelvin probe force measurement (KPFM) data showed that the TSE layer receives holes from STO under illumination. Additionally, time-resolved photoluminescence (TRPL) experiments showed that the TSE/STO thin film is able to produce UV emission after irradiation with lower energy light. Then, the EQE variation in thicker TSE layers under intense irradiation can be attributed to the solid-state upconversion, indicating its thickness-dependent performance. These findings underline the strategies for maximizing the utilization of the solar spectrum in PV applications.
  • Publication
    Solvent Effect on the Electrical and Structural Properties for MEH-PPV Organic Light Emitting Diodes (OLED)
    ( 2021-03-01)
    Ismail N.A.N.
    ;
    Safizan Shaari
    ;
    Juhari N.
    ;
    Norhayati Sabani
    ;
    Ahmad M.F.
    ;
    Zakaria N.F.
    In this paper, the performance of the electrical properties (J-V) and surface roughness of MEH-PPV based organic light-emitting diodes (OLED) towards solvent effect was investigated. The MEH-PPV layer was deposited using spin coating technique at fixed spun speed of 3000 rpm. Two different solvents, toluene and chloroform (CHCl3) and mixture toluene:CHCl3 with the ratio of 4:1 and 1:4 were used to dilute MEH-PPV at fixed concentration of 5 mgml-1. Apparently, the mixture of solvent makes the surface roughness of the MEH-PPV films reduced to 0.15 nm and 3.59 nm under the ratio 4:1 and 1:4 respectively. Besides, the mixture solvents makes the value of turn on voltage was dropped to ∼7.2 V and ∼9 V respectively compared to non-mixture solvent. The combination of different solvent apparently gives an effect on the electrical and structural properties of organic light-emitting diode.
  • Publication
    Silicon Self-Switching Diode (SSD) as a Full-Wave Bridge Rectifier in 5G networks frequencies
    ( 2022)
    Tan Yi Liang
    ;
    Nor Farhani Zakaria
    ;
    Shahrir Rizal Kasjoo
    ;
    Safizan Shaari
    ;
    Muammar Mohamad Isa
    ;
    Arun Kumar Singh
    ;
    Mohd Khairuddin Md Arshad
    The rapid growth of wireless technology has improved the network’s technology from 4G to 5G, with sub-6 GHz being the centre of attention as the primary communication spectrum band. To effectively benefit this exclusive network, the improvement in the mm-wave detection of this range is crucial. In this work, a silicon self-switching device (SSD) based full-wave bridge rectifier was proposed as a candidate for a usable RF-DC converter in this frequency range. SSD has a similar operation to a conventional pn junction diode, but with advantages in fabrication simplicity where it does not require doping and junctions. The optimized structure of the SSD was cascaded and arranged to create a functional full-wave bridge rectifier with a quadratic relationship between the input voltage and outputs current. AC transient analysis and theoretical calculation performed on the full-wave rectifier shows an estimated cut-off frequency at ~12 GHz, with calculated responsivity and noise equivalent power of 1956.72 V/W and 2.3753 pW/Hz1/2, respectively. These results show the capability of silicon SSD to function as a full-wave bridge rectifier and is a potential candidate for RF-DC conversion in the targeted 5G frequency band and can be exploited for future energy harvesting application.
      2  13
  • Publication
    Hybrid statistical and numerical analysis in structural optimization of silicon-based RF Detector in 5G Network
    ( 2022-02-01)
    Tan Yi Liang
    ;
    Nor Farhani Zakaria
    ;
    Shahrir Rizal Kasjoo
    ;
    Safizan Shaari
    ;
    Muammar Mohamad Isa
    ;
    Mohd Khairuddin Md Arshad
    ;
    Arun Kumar Singh
    ;
    Sharizal Ahmad Sobri
    In this study, a hybrid statistical analysis (Taguchi method supported by analysis of variance (ANOVA) and regression analysis) and numerical analysis (utilizing a Silvaco device simulator) was implemented to optimize the structural parameters of silicon-on-insulator (SOI)-based self-switching diodes (SSDs) to achieve a high responsivity value as a radio frequency (RF) detector. Statistical calculation was applied to study the relationship between the control factors and the output performance of an RF detector in terms of the peak curvature coefficient value and its corresponding bias voltage. Subsequently, a series of numerical simulations were performed based on Taguchi’s experimental design. The optimization results indicated an optimized curvature coefficient and voltage peak of 26.4260 V−1 and 0.05 V, respectively. The alternating current transient analysis from 3 to 10 GHz showed the highest mean current at 5 GHz and a cut-off frequency of approximately 6.50 GHz, indicating a prominent ability to function as an RF detector at 5G related frequencies.
      4  3
  • Publication
    A review of visible-to-UV photon upconversion systems based on triplet–triplet annihilation photon upconversion
    ( 2022-12)
    Kelvin Voon Yan Jie
    ;
    Mohd Fairus Ahmad
    ;
    Muhammad Mahyiddin Ramli
    ;
    Safizan Shaari
    ;
    Arif Mawardi Ismail
    ;
    Yusran Sulaiman
    Due to the tunable spectrum range and potential application under non-coherent solar irradiation, triplet-triplet annihilation based molecular photon upconversion (TTA-UC) systems represent a compelling study field for a variety of photonic implementations. There were studies on the incorporation of TTA-UC technology with photovoltaic technology, which made it possible to further improve the energy harvest performance through the utilisation of the wasted spectrum. However, many TTA-UC studies are limited to energy upconversion within the visible spectrum range. For photovoltaic cells with a higher band gap, which harvest the higher energy spectrum (UV region), an efficient Vis-to-UV upconversion is preferred. The Vis-to-UV TTA-UC system was first introduced in 2006. Recently, more studies were conducted to discover the Vis-to-UV upconversion system with high quantum efficiency and low excitation intensity such as the nanocrystal sensitizerbased system and the thermally activated delayed fluorescence sensitizer-based system. Recent studies in the solvent system of Vis-to-UV upconversion system had demonstrated the dependence of the couple photostability on the solvent and extended the solvent selection to inorganic solvent. In this review, we are reviewing the research background of the Vis-to-UV TTA-UC system and discussing the current challenges and potential developments in this research area.
      1  8
  • Publication
    Fabrication of Strontium Titanate thin film with pre-crystallized layer via sol-gel spin coating method
    ( 2022-12)
    Kelvin Voon Yan Jie
    ;
    Mohd Fairus Ahmad
    ;
    Muhammad Mahyiddin Ramli
    ;
    Safizan Shaari
    ;
    Arif Mawardi Ismail
    ;
    Yusran Sulaiman
    The technique of pre-crystallized layer is introduced in the strontium titanate (STO) thin film fabrication to improve the coating thickness and the crystallinity. The STO thin films were fabricated on glass substrates via the spin coating method with STO precursor solution that was synthesized through the sol-gel process. The characteristics of the thin films were analyzed through X-ray diffraction (XRD) analysis, profilometry, UV-Vis spectra analysis and scanning electron microscopy (SEM) analysis. In the present study, the samples of 20 layers and 25 layers (deposited on the pre-crystallized layer) exhibited better crystallinity as compared with the samples of 5 layers, 10 layers and 15 layers (without the pre-crystallized layer). The samples of 25 layers exhibited the highest film thickness (224 nm), highest absorbance intensity and the highest XRD peak intensity at 32, 40, 47 and 58°, which represent the planes (110), (111), (200) and (210), respectively. The pre-crystallized layer served as the mechanical support for further layer deposition.
      1  7
  • Publication
    Temperature effects on electrical and structural properties of MEH-PPV/PEIE OLED Device
    ( 2020-06-16)
    Nurul Afiqah Nor Ismail
    ;
    Safizan Shaari
    ;
    Mohd Fairus Ahmad
    ;
    Norhayati Sabani
    ;
    Nurjuliana Juhari
    ;
    Nor Farhani Zakaria
    This paper explores the performance of configuration ITO/MEH-PPV/PEIE/Al OLED under the variations of temperature. The MEH-PPV and MEH-PPV/PEIE thin film were deposited on ITO substrates using spin coating technique with fixed spin speed of 3000 rpm and baked at low temperature ranging from 90 °C to 180 °C, respectively. The surface roughness values for MEH-PPV and MEH-PPV/PEIE films were analysed using AFM with 5 μm ' 5 μm scanning area. The roughness of MEH-PPV thin films were reduced from 2.825 nm to 1.625 nm when temperature increased. Contrary to MEH-PPV/PEIE films where the roughness increased linearly up to 3.397 nm when the temperature increased. The maximum absorption peak spectrum obtained from UV-Visible (UV-Vis) was found at 500 nm to 510 nm when baked temperature were varied. Furthermore, the turn on voltage from J-V characteristics gives no specific pattern across different temperature and agreed with the trend of surface roughness values. The turn-on voltage at T = 150 °C gives the lowest value of 3 V. Overall, the variations of low temperature gives an effects on structural and electrical properties of this OLED configuration.
      4  3
  • Publication
    Modification of Photoanode Surface Structure via Image Analysis on Organic Polymer Material based for Dye-Sensitized Solar Cell (DSSC) Applications
    ( 2021-12-01)
    Nur Liyana Mohd Rosli
    ;
    Norhayati Sabani
    ;
    Mohd Fairus Ahmad
    ;
    Mohd. Azarulsani Md. Azidin
    ;
    Nurjuliana Juhari
    ;
    Nor Farhani Zakaria
    ;
    Mohd Natashah Norizan
    ;
    Safizan Shaari
    In this study, the experiment on the modification of the photoanode with organic polymer material as copolymer template for dye-sensitized solar cell (DSSC) applications has been conducted. The two organic copolymer templates are polystyrene sphere (PS) and poly[2-methoxy-5(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV). The modification photoanodes were made using Dr. Blade’s method. These organic copolymer templates were added to improve the surface of the mesoporous titanium dioxide (TiO2) layer, which is used as the main component in DSSC photoanode. The unmodified TiO2 photoanode has poor aggregation and porosity of TiO2. The addition of either MEH-PPV or PS sphere to the photoanode layer was found to affect the surface of mesoporous TiO2 in terms of porosity, particle size distribution and shape. The analysis of the TiO2 modification was conducted using an image analysis processing method via a 2D scanning electron microscope (SEM) image. The image analysis processing method used was the ImageJ program. The DSSC of modified photoanode is fabricated using metal complex dye, Ruthenium (N719) dye. The data collected from the ImageJ program showed that by adding organic copolymer templates into TiO2, the porosity of TiO2 decreased from 45 % to 42 %. From the photovoltaic analysis obtained, the J-V characteristic is recorded with the photoanode of TiO2 mixed with 1.00 wt% MEH-PPV gave the highest efficiency, which is 0.01 % with the following parameters – Voc = 0.43 V, Jsc = 0.17 mA/cm2 and FF = 0.20. Meanwhile, the photoanode of TiO2 mixed with 0.50 wt% PS sphere gave the highest efficiency which is 0.08 % with the following parameters – Voc = 0.39 V, Jsc = 0.86 mA/cm2 and FF = 0.25.
      1