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Norhayati Sabani
Preferred name
Norhayati Sabani
Official Name
Norhayati, Sabani
Alternative Name
Sabani, N.
Sabani, Norhayati
Sabani, Norhayati Bt
Norhayati, S.
Sabani, Norhayati Binti
Main Affiliation
Scopus Author ID
54785178400
Researcher ID
AAB-8243-2022
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1 - 10 of 36
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PublicationAnalysis of power distribution in mach zehnder interferometer polymer-based waveguide for sensing applications( 2022-12)Two Mach Zehnder Interferometer (MZI) polymer-based waveguide designs namely MZI symmetrical and MZI asymmetrical structures were simulated and analyzed using Optiwave OptiBPM10. The two designs with device size of 4000μm x 300μm exhibit clear optical propagation path when light is simulated through them as well as displaying single mode profile. Highest output power was obtained by the MZI symmetrical design at 0.90 a.u, which suggests better waveguide design for sensing applications.
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PublicationA Study on Electrical Performance of SiC-based Self-switching Diode (SSD) as a High Voltage High Power Device( 2023-12-01)
;Sha’ari N.Z.A.A. ;Ahmad M.F.The Self-switching Diodes (SSDs) have been primarily researched and used in low-power device applications for RF detection and harvesting applications. In this paper, we explore the potential of SSDs in high-voltage applications with the usage of Silicon Carbide (SiC) as substrate materials which offers improved efficiency and reduced energy consumption. Optimization in terms of the variation in the interface charges, metal work function, and doping concentration values has been performed by means of a 2D TCAD device simulator. The results showed that the SSD can block up to 600 V of voltage with an optimum interface charge value of 1013 cm-2, making them suitable for higher voltage applications. Furthermore, it also found that the work function of the metal contact affected the forward voltage value, impacting the current flow in the device. Variation in doping concentrations also resulted in higher breakdown voltages and significantly increased forward current, leading to an increased power rating of 27 kW. In conclusion, the usage of 4H-SiC-based SSDs shows a usable potential for high-voltage applications with optimized parameters. The results from this research can facilitate the implementation of SSD in the development of high-power semiconductor devices for various industrial applications. -
PublicationThe effect of solvents on the performance of organic light-emitting diodes( 2020-01-08)
;Ismail N.A.N. ;Juhari N.Zakaria N.F.In this paper, we investigate the solvent effect on the performance of surface roughness, absorption spectrum of MEH-PPV thin films and J-V characteristics for MEH-PPV OLED device. The 5 mg emissive layer of poly [2-methoxy-5(2' -ethylhexyloxy)-1, 4-phenylenevinylene), MEH-PPV was diluted with 1ml toluene and 1 ml different mixture of solvent (80% toluene+20 % chloroform) which gives the concentration of 5 mgml-1 respectively. The surface roughness of MEH-PPV film was reduced to 0.3 nm and the red-shifted maximum peak wavelength value were obtained when mixture solvent was used. However, J-V gives higher turn on voltage ∼17 V for the device used mixture solvent compared to device prepared by toluene solvent. Apparently, the two different combination of aromatic and non-aromatic solvent significantly gives an effect on thin films properties and electrical properties of MEH-PPV OLED device. -
PublicationThe study and preparation of polyaniline-graphene oxide as robust counter electrode for dye-sensitized solar cells( 2022-05-18)
;Shukor A.A. ;Nawawi W.I.Badri A.The study of alternative materials and platinum-free counter electrodes (CE) for the development of dye- sensitized solar cells (DSSC) has been highlighted nowadays. Polyaniline (PANI) is one of the most common conducting polymers applied in electrochemical energy storage and conversion technologies such as supercapacitors, rechargeable batteries and fuel cells. However, PANI counter electrodes lack long-term stability due to their low surface area and large volume changes during the release of ions. In that regard, this research work focused on the modification of protonated PANI with graphene oxide (GO) at various weight percentages (wt%) in order to obtain robust CE in DSSC. The structure and formation of PANI, GO and PANI/GO were characterized by Fourier transform infrared (FT-IR) and X-ray diffraction (XRD) analyses. The absorption spectra showed all the characteristic bands of GO, PANI(ES) and PANI/GO. Meanwhile, the incorporation of GO into PANI has enhanced the crystallinity of the composite. As a result, power conversion efficiency (PCE%) of the device with PANI/GO 3 wt% as the counter electrode reaches 6.39%. The excellent photoelectric properties, simple preparation procedure and inexpensive cost allow the PANI/GO electrode to be a credible alternative for DSSCs. -
PublicationElectrochemiluminescence of carbon dots and nitrogen-doped carbon dots from a microwave-assisted method( 2023-10)
;Nurul Izzati Akmal Mohd Azman ;Muhammad Amirul Afiq Abdul Halim ;Siti Aisyah ShamsudinEiichi TamiyaThis research focuses on the use of carbon dots (CDs) and nitrogen-doped carbon dots (NCDs) synthesized using a microwave-assisted method as electrochemiluminescence (ECL) luminophores. CDs have been synthesized using citric acid, while various concentrations of nitrogen-doped CDs have been successfully obtained by varying the amount of urea from 1 to 3 g with citric acid to produce NCD1, NCD,2 and NCD3. The ECL mechanism of CDs and NCDs on screen-printed electrodes has been studied using cyclic voltammetry (CV). ECL emission from as-prepared CDs and NCDs was observed in PBS with potassium persulfate (K2S2O8) as a co-reactant. The addition of potassium chloride (KCl) as a supporting electrolyte displays fast electroreduction of CDs and K2S2O8 to expedite the generation of CDs and peroxydisulfate radicals that simultaneously increase ECL intensity. Furthermore, as the concentration of nitrogen-doped CDs increases, so does the intensity of the ECL. NCD3 shows the highest ECL intensity by an increment of 86.4% in comparison to CDs in PBS with the addition of K2S2O8 and KCl. Finally, optimization of ECL measurement was carried out in terms of CV potential range, concentration of luminophore, supporting electrolyte, and co-reactant using NCD3 luminophore. The CV potential range at 0 to -2 V shows 50 mV of early CV reverse onset potential that resulted in an increase of 52.9% ECL intensity. Meanwhile, 30x dilution of NCD3, 0.1 M of supporting electrolyte KCl, and 0.1 M of co-reactant K2S2O8 show the optimum value to obtain high ECL intensity. -
PublicationSolvent Effect on the Electrical and Structural Properties for MEH-PPV Organic Light Emitting Diodes (OLED)( 2021-03-01)
;Ismail N.A.N. ;Juhari N. ;Ahmad M.F.Zakaria N.F.In this paper, the performance of the electrical properties (J-V) and surface roughness of MEH-PPV based organic light-emitting diodes (OLED) towards solvent effect was investigated. The MEH-PPV layer was deposited using spin coating technique at fixed spun speed of 3000 rpm. Two different solvents, toluene and chloroform (CHCl3) and mixture toluene:CHCl3 with the ratio of 4:1 and 1:4 were used to dilute MEH-PPV at fixed concentration of 5 mgml-1. Apparently, the mixture of solvent makes the surface roughness of the MEH-PPV films reduced to 0.15 nm and 3.59 nm under the ratio 4:1 and 1:4 respectively. Besides, the mixture solvents makes the value of turn on voltage was dropped to ∼7.2 V and ∼9 V respectively compared to non-mixture solvent. The combination of different solvent apparently gives an effect on the electrical and structural properties of organic light-emitting diode. -
PublicationPhotoluminescence measurement of triplet sensitizer-emitter solution using a customized 3D-printed sample holder( 2024-06)
;Kelvin Voon Yan JieThis study explores the photoluminescence (PL) measurement of triplet sensitizer-emitter (TSE) solutions using a custom 3D-printed sample holder, within the context of triplet-triplet annihilation based molecular photon upconversion (TTA-UC) systems targeting the Vis-to-UV spectral region. TTA-UC converts low-energy visible photons to higher-energy ultraviolet (UV) photons, holding promise for solar energy harvesting and photonics applications. Two TSE couples, 4CzIPN/TP and 4CzIPN/QP, were investigated, and their upconverted fluorescence spectra showed peaks at 344 nm and 354 nm / 370 nm, respectively, confirming efficient upconversion capabilities. The 3D-printed sample holder facilitated reproducible PL measurements, enabling the calculation of quantum yields (ΦUC). The 4CzIPN/TP and 4CzIPN/QP couples exhibited low quantum yields (0.028% and 0.043%, respectively), suggesting the need for improved deoxygenation methods to enhance the triplet-triplet annihilation process and overall quantum efficiency. Despite modest yields, successful UV upconverted fluorescence observation underscores the feasibility of the Vis-to-UV TTA-UC system. This study provides insights into TTA-UC optimization and demonstrates the utility of the 3D-printed sample holder for affordable and precise PL measurements, paving the way for future advancements in photonics and solar energy applications. -
PublicationElectrochemical study of TiO2 thin film on aluminium electrode for glucose detection( 2020-01-08)
;Yen F.S. ;Halim N.H.A.This paper presents the fabrication of Interdigitated Electrodes (IDEs) towards the detection of glucose. The transducer is constructed based on IDE because of its single layer electrode structure. Majority of IDE used metal such as gold and nickel as the electrodes because of their excellent electrical performances. However, in this paper, aluminium is applied as metal of electrodes not only because of its stable material but also trying to investigate the interaction between aluminium metal and Titanium dioxide, TiO2 with glucose detection. Titanium dioxide has been utilized as thin film on the deposited aluminium electrodes to increase the interaction between aluminium electrodes with different concentration of glucose solution. The designs of IDEs interdigitated array (IDBA) and interdigitated ring array (IDRA) are performed by using AUTOCAD and it is printed on a transparency paper as a mask. Customary photolithography methods with positive resist are applied to transfer the pattern on a silicon wafer in this fabrication process. Then, the fabricated IDEs are viewed and examined under Scanning Electron Microscope (SEM) and Atomic Force Microscope (AFM) to verify the surface morphology and topology. The electrochemical performance of IDEs is observed through cyclic voltammogram characteristics performed using potentiostat. In the nut shell, both IDBA and IDRA are tested within 0 to 100 mM range of glucose concentration. -
PublicationModification of photoanode surface structure via image analysis on organic polymer material based for dye-sensitized solar cell (DSSC) applications( 2021-12)
;N. Rosli ;MF Ahmad ;NF ZakariaIn this study, the experiment on the modification of the photoanode with organic polymer material as copolymer template for dye-sensitized solar cell (DSSC) applications has been conducted. The two organic copolymer templates are polystyrene sphere (PS) and poly[2- methoxy-5(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV). The modification photoanodes were made using Dr. Blade’s method. These organic copolymer templates were added to improve the surface of the mesoporous titanium dioxide (TiO₂) layer, which is used as the main component in DSSC photoanode. The unmodified TiO₂ photoanode has poor aggregation and porosity of TiO₂. The addition of either MEH-PPV or PS sphere to the photoanode layer was found to affect the surface of mesoporous TiO₂ in terms of porosity, particle size distribution and shape. The analysis of the TiO2 modification was conducted using an image analysis processing method via a 2D scanning electron microscope (SEM) image. The image analysis processing method used was the ImageJ program. The DSSC of modified photoanode is fabricated using metal complex dye, Ruthenium (N719) dye. The data collected from the ImageJ program showed that by adding organic copolymer templates into TiO₂, the porosity of TiO₂ decreased from 45 % to 42 %. From the photovoltaic analysis obtained, the J-V characteristic is recorded with the photoanode of TiO₂ mixed with 1.00 wt% MEH-PPV gave the highest efficiency, which is 0.01 % with the following parameters – Voc = 0.43 V, Jsc = 0.17 mA/cm2 and FF = 0.20. Meanwhile, the photoanode of TiO₂ mixed with 0.50 wt% PS sphere gave the highest efficiency which is 0.08 % with the following parameters – Voc = 0.39 V, Jsc = 0.86 mA/cm2 and FF = 0.25. -
PublicationElectrochemical detection of heavy metal ions using gold nanoparticles on carbon dots extracted from curry leaves( 2024-06)
;Aidil Safiy Kamarul Ariffin ;Nurul Izzati Akmal Mohd AzmanSiti Aisyah ShamsudinCarbon dots (CDs) have attracted attention due to their versatility in electronic and optical properties based on precursor and type of synthesis process. Recently, many researchers have focused on using natural resources or wastes to form CDs. Four samples of CDs have been synthesized from curry leaves using a microwave-assisted approach at heating powers of 700 and 800 V with durations of 5 and 8 minutes. UV-Vis and FTIR spectra reveal the existence of carbon graphitic elements with carboxyl and hydroxyl functional groups on the surfaces of CDs. CVs of AuNPs/CDs/GS electrodes in ferricyanide disclosed that as-synthesized CDs produced using a lower heating power of 700 W exhibit pronounced electrocatalytic activity with sluggish electron transfer kinetics. Conversely, as-synthesized CDs created with a higher heating power of 800 W demonstrate reduced electrocatalytic activity but rapid electron transfer kinetics. Electrochemical detection of Pb2+ ions was observed through a sharp peak around -0.42 to -0.438 V, while detection of Hg2+ ions was observed through two anodic peaks around +0.334 to +0.408 V during a forward scan in acetate buffer (pH 4.5) on AuNPs/CDs/GS electrodes when tested individually. These distinct peaks also appeared in mixture solutions, with a slight reduction in peak current density that suggests the selectivity of the AuNPs/CDs/GS electrodes towards Pb2+ and Hg2+ ion detection. The optimum AuNPs/CDs/GS electrode for sensitive and selective detection of Pb2+ and Hg2+ was recorded using CDs D as a functional supporting matrix for AuNPs that was synthesized using a heating power of 800 W for 8 minutes.