Now showing 1 - 10 of 21
  • Publication
    Analysis of power distribution in mach zehnder interferometer polymer-based waveguide for sensing applications
    Two Mach Zehnder Interferometer (MZI) polymer-based waveguide designs namely MZI symmetrical and MZI asymmetrical structures were simulated and analyzed using Optiwave OptiBPM10. The two designs with device size of 4000μm x 300μm exhibit clear optical propagation path when light is simulated through them as well as displaying single mode profile. Highest output power was obtained by the MZI symmetrical design at 0.90 a.u, which suggests better waveguide design for sensing applications.
  • Publication
    A brief overview of detectors used for terahertz imaging systems
    ( 2020-01-08) ;
    Mohd Mokhar, Mohd Bazli
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    This paper presents a short review on terahertz imaging systems based on several types of technology used in the terahertz detection schemes. Some commercial products from ThruVision Systems Limited Company have utilized GaAs Schottky diode detector at 0.25 THz to produce passive terahertz images for public and homeland security. On the other hand, TeraSense Group Incorporated Company has developed and invented a ground-breaking technology which employs sensor consisting of a matrix of plasmonic semiconductor detectors in their latest products to generate terahertz images in the 0.1 - 1.0 THz frequency range. Recently, the utilization of two-terminal unipolar nanodiodes, known as the self-switching diodes (SSDs), as terahertz detectors has shown promising results. The planar structure of SSD not only enables the device to operate at high frequencies due to low intrinsic parasitic capacitance, but also allows the realization of the device using only a single lithography step. This makes the fabrication process of SSDs faster, more simple, and at lower cost when compared to other electronic devices such as Schottky diodes. The development and recent achievement of SSDs as terahertz detectors are also presented in this paper.
  • Publication
    Electrochemiluminescence of carbon dots and nitrogen-doped carbon dots from a microwave-assisted method
    ( 2023-10)
    Nurul Izzati Akmal Mohd Azman
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    Muhammad Amirul Afiq Abdul Halim
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    ; ; ; ;
    Siti Aisyah Shamsudin
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    Eiichi Tamiya
    This research focuses on the use of carbon dots (CDs) and nitrogen-doped carbon dots (NCDs) synthesized using a microwave-assisted method as electrochemiluminescence (ECL) luminophores. CDs have been synthesized using citric acid, while various concentrations of nitrogen-doped CDs have been successfully obtained by varying the amount of urea from 1 to 3 g with citric acid to produce NCD1, NCD,2 and NCD3. The ECL mechanism of CDs and NCDs on screen-printed electrodes has been studied using cyclic voltammetry (CV). ECL emission from as-prepared CDs and NCDs was observed in PBS with potassium persulfate (K2S2O8) as a co-reactant. The addition of potassium chloride (KCl) as a supporting electrolyte displays fast electroreduction of CDs and K2S2O8 to expedite the generation of CDs and peroxydisulfate radicals that simultaneously increase ECL intensity. Furthermore, as the concentration of nitrogen-doped CDs increases, so does the intensity of the ECL. NCD3 shows the highest ECL intensity by an increment of 86.4% in comparison to CDs in PBS with the addition of K2S2O8 and KCl. Finally, optimization of ECL measurement was carried out in terms of CV potential range, concentration of luminophore, supporting electrolyte, and co-reactant using NCD3 luminophore. The CV potential range at 0 to -2 V shows 50 mV of early CV reverse onset potential that resulted in an increase of 52.9% ECL intensity. Meanwhile, 30x dilution of NCD3, 0.1 M of supporting electrolyte KCl, and 0.1 M of co-reactant K2S2O8 show the optimum value to obtain high ECL intensity.
  • Publication
    Characterization of all-optical Tofolli and Peres gates employing optimized SOA-NOLM
    In this work, all-optical reversible gates namely Tofolli and Peres are studied and characterized. The gates utilize semiconductor optical amplifier (SOA) in nonlinear loop optical mirror (NOLM). The reversible gates are performed at data rate 10 Gb/s with narrow Gaussian pulses as input signals. Delay of 130 ps and injection current of 170 mA have displayed the optimum outputs in the SOA-NOLM. Extinction ratio is greatly reduced, thus less noise interferes the logic operation in this simple technique. It is observed that Peres gate has shown a higher output power compare to Toffoli gate. This could be due to multiple amplification that are experienced by the signals. Other than the gain, injection current and delay are shown to give major effect in producing the correct bits at the outputs. The SOA-NOLM also can be cascaded for other arithmetic signal processing operation at high frequency. It is also recorded that the design consumes low power especially in small signal gain process. Thus, the design indicates its versatility to be executed in photonic integrated circuits for ultrafast signal control through fiber networks.
  • Publication
    Modification of photoanode surface structure via image analysis on organic polymer material based for dye-sensitized solar cell (DSSC) applications
    In this study, the experiment on the modification of the photoanode with organic polymer material as copolymer template for dye-sensitized solar cell (DSSC) applications has been conducted. The two organic copolymer templates are polystyrene sphere (PS) and poly[2- methoxy-5(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV). The modification photoanodes were made using Dr. Blade’s method. These organic copolymer templates were added to improve the surface of the mesoporous titanium dioxide (TiO₂) layer, which is used as the main component in DSSC photoanode. The unmodified TiO₂ photoanode has poor aggregation and porosity of TiO₂. The addition of either MEH-PPV or PS sphere to the photoanode layer was found to affect the surface of mesoporous TiO₂ in terms of porosity, particle size distribution and shape. The analysis of the TiO2 modification was conducted using an image analysis processing method via a 2D scanning electron microscope (SEM) image. The image analysis processing method used was the ImageJ program. The DSSC of modified photoanode is fabricated using metal complex dye, Ruthenium (N719) dye. The data collected from the ImageJ program showed that by adding organic copolymer templates into TiO₂, the porosity of TiO₂ decreased from 45 % to 42 %. From the photovoltaic analysis obtained, the J-V characteristic is recorded with the photoanode of TiO₂ mixed with 1.00 wt% MEH-PPV gave the highest efficiency, which is 0.01 % with the following parameters – Voc = 0.43 V, Jsc = 0.17 mA/cm2 and FF = 0.20. Meanwhile, the photoanode of TiO₂ mixed with 0.50 wt% PS sphere gave the highest efficiency which is 0.08 % with the following parameters – Voc = 0.39 V, Jsc = 0.86 mA/cm2 and FF = 0.25.
  • Publication
    Electrochemical detection of heavy metal ions using gold nanoparticles on carbon dots extracted from curry leaves
    ( 2024-06) ;
    Aidil Safiy Kamarul Ariffin
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    Nurul Izzati Akmal Mohd Azman
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    ; ; ;
    Siti Aisyah Shamsudin
    Carbon dots (CDs) have attracted attention due to their versatility in electronic and optical properties based on precursor and type of synthesis process. Recently, many researchers have focused on using natural resources or wastes to form CDs. Four samples of CDs have been synthesized from curry leaves using a microwave-assisted approach at heating powers of 700 and 800 V with durations of 5 and 8 minutes. UV-Vis and FTIR spectra reveal the existence of carbon graphitic elements with carboxyl and hydroxyl functional groups on the surfaces of CDs. CVs of AuNPs/CDs/GS electrodes in ferricyanide disclosed that as-synthesized CDs produced using a lower heating power of 700 W exhibit pronounced electrocatalytic activity with sluggish electron transfer kinetics. Conversely, as-synthesized CDs created with a higher heating power of 800 W demonstrate reduced electrocatalytic activity but rapid electron transfer kinetics. Electrochemical detection of Pb2+ ions was observed through a sharp peak around -0.42 to -0.438 V, while detection of Hg2+ ions was observed through two anodic peaks around +0.334 to +0.408 V during a forward scan in acetate buffer (pH 4.5) on AuNPs/CDs/GS electrodes when tested individually. These distinct peaks also appeared in mixture solutions, with a slight reduction in peak current density that suggests the selectivity of the AuNPs/CDs/GS electrodes towards Pb2+ and Hg2+ ion detection. The optimum AuNPs/CDs/GS electrode for sensitive and selective detection of Pb2+ and Hg2+ was recorded using CDs D as a functional supporting matrix for AuNPs that was synthesized using a heating power of 800 W for 8 minutes.
  • Publication
    Dyes extracted from Hibiscus Sabdariffa flower and Pandannus amaryllifolius leaf as natural dye sensitizer by using an alcohol-based solvent
    ( 2021-03-01)
    Rosli N.
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    Shahimin M.M.
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    Shaari S.
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    Ahmad M.F.
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    Zakaria N.
    The efficiency improvement of Dye sensitized solar cells (DSSC), the fabrication of DSSC by using metal-free organic natural dyes with a different type of solvents for the extraction of dye sensitizer was investigated. The metal-free organic Dye which comes from anthocyanin and chlorophyll dyes were dissolved by using different solvents, which are ethanol, methanol and mixture of ethanol and methanol. Anthocyanin dye was extracted from the petals of Hibiscus Sabdariffa (Roselle), and chlorophyll dye was extracted from the epidermal leaves of Pandannus amaryllifolius (Pandan). The purpose of using different solvents from alcohol-based was to determine which solvents that produce the highest effect in term of efficiency for DSSC. To confirm which solvents that produce the highest efficiency to the DSSC, the photovoltaic measurement was conducted, and the data was collected. From the photovoltaic analysis, the J-V characteristics under illumination are recorded. The sample that used anthocyanin dye extracted from Roselle flower diluted with methanol solvent gave the highest efficiency which is 0.0005% with the following parameters-Voc = 0.419 V, Jsc = 0.0057 mA/cm2 and FF = 0.24. Meanwhile, the sample that used chlorophyll dye extracted from Pandan leaves diluted with a mix of ethanol and methanol solvents gave the highest efficiency which is 0.00014% with the following parameters-Voc = 0.347 V, Jsc = 0.0016 mA/cm2 and FF = 0.25.
  • Publication
    Simulation of Terahertz Broadband Antennas for Rectenna Applications
    ( 2020-12-14)
    Mohd Mokhar M.B.
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    In this paper, we designed and simulated several self-complimentary broadband antennas for the use in rectenna applications at terahertz frequencies. Rectenna that consists of two-terminal planar nanodiode such as self-switching diode is considered as a requirement in designing the broadband antennas. Antenna's performance is then compared in terms of its return loss, gain, directivity and radiation efficiency.
  • Publication
    Optimization of MEH-PPV based single and double-layer TOLED structure by numerical simulation
    In this work, we simulated and characterized Poly [2-methoxy-5-(2’-ethylhexyloxy)-1, 4-phenylene vinylene] (MEH-PPV) based single and double-layer TOLED by using Silvaco ATLAS device simulator to achieve prominent values of electrical and optical properties of the device. MEH-PPV were used as the emitting layer (EML) in the single-layer, while addition of Poly [(3,4-ethylene dioxythiophene)-poly(styrene sulfonate)] (PEDOT-PSS) as the electron transport layer (ETL) were conducted in double-layer TOLED simulation. The EML and ETL thickness in both structures were varied between 10 – 150 nm, respectively, to observe and understand the underlying physics of the relation in the layer thickness to the electrical and optical characteristics. Furthermore, variation of the EML/ETL thickness ratio from 1:1 to 5:1 (with thickness in between 10 to 50 nm) had also been conducted. From this work, it is understood that the thickness of the EML layer plays the most important role in TOLED, and by balancing the carrier injections and recombination rate in appropriate EML/ETL thickness ratio, the electrical and optical properties can be improved. By optimizing the EML/ETL thickness and thickness ratio, an optimal forward current of 1.41 mA and luminescent power of 1.93e-18 W/μm has been achieved with both MEH-PPV and PEDOT-PSS layer thickness of 10 nm (1:1 ratio), respectively. The results from this work will assist the improvement of TOLED device to be implemented widely in low power and transparent electronic appliances.
  • Publication
    UWB triplet and quadruplet pulses generation employs nonlinear effect in semiconductor optical amplifier nonlinear loop mirror
    ( 2020-01-08)
    Zahari, Suhaila Mohd
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    ; ; ;
    Ghazali N.F.
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    Shahimin M.M.
    Ultrawideband (UWB) triplet and quadruplet pulses generation exploits nonlinear effect in semiconductor optical amplifier (SOA) in nonlinear loop mirror (NOLM) is investigated in this work. Two signals are transmitted through the SOA-NOLM simultaneously to create cross-phase modulation (XPM) effect. Firstly, the XPM causes the production of doublet which later combines for creation of triplet and quadruplet. This technique engages a proper tuning of optical delay and a selection of suitable power in all loops. Besides, injection current of the SOAs also governs the formation of these pulses. Although, frequency of the signals can be varied accordingly, the pulses are limited to certain adjustment that shifted its position in time domain. Furthermore, the set up can also be assessed for monocycle and doublet pulses by extracting the output at several positions. It can be concluded that the design may work as multiple pulses generation. All pulses are examined and compared with their electrical spectrum counterpart for validity of this approach.