Now showing 1 - 10 of 27
  • Publication
    The role of zinc chloride in enhancing mechanical, thermal and electrical performance of ethylene vinyl acetate/carbonized wood fiber conductive composite
    Carbonized natural filler can offer the production of low cost composites with an eco-friendliness value. The evolving field of electronics encourages the exploration of more functions and potential for carbonized natural filler, such as by modifying its surface chemistry. In this work, we have performed surface modification on carbonized wood fiber (CWF) prior to it being used as filler in the ethylene vinyl acetate (EVA) composite system. Zinc chloride (ZnCl2) with various contents (2 to 8 wt%) was used to surface modify the CWF and the effects of ZnCl2 composition on the surface morphology and chemistry of the CWF filler were investigated. Furthermore, the absorptive, mechanical, thermal, and electrical properties of the EVA composites containing CWF-ZnCl2 were also analyzed. SEM images indicated changes in the morphology of the CWF while FTIR analysis proved the presence of ZnCl2 functional groups in the CWF. EVA composites incorporating the CWF-ZnCl2 showed superior mechanical, thermal and electrical properties compared to the ones containing the CWF. The optimum content of ZnCl2 was found to be 6 wt%. Surface modification raised the electrical conductivity of the EVA/CWF composite through the development of conductive deposits in the porous structure of the CWF as a channel for ionic and electronic transfer between the CWF and EVA matrix.
  • Publication
    Incorporation of hybrid pre-dispersed organo-montmorillonite/destabilized bentonite nanofillers for improving tensile strength of PEVA copolymer with 40% vinyl acetate composition
    (Trans Tech Publications Ltd., 2020)
    Tuty Fareyhynn Mohammed Fitri
    ;
    ; ;
    Zaleha Mustafa
    In this work, soft and flexible poly (ethylene-co-vinyl acetate) (PEVA) with 40% vinyl acetate (VA) composition was used as matrix material to form nanocomposites with single nanofiller (organo-montmorillonite (OMMT) or Bentonite (Bent)) and hybrid nanofillers (OMMT+Bent in the ratios of 4:1, 3:2, 2:3 and 1:4). In order to achieve greater exfoliation and dispersion of the hybrid nanofillers in the PEVA matrix, the pre- dispersing and destabilization technique was applied to the O-MMT and Bent, respectively. The procedures were done prior to the melt compounding process of the nanocomposite. A tensile test was done to evaluate the mechanical properties of the resultant nanocomposites and to allow the selection of the best OMMT/Bent ratio for the production of the hybrid nanocomposite. The structure and fractured surfaces of the neat PEVA and nanocomposite were analyzed using Fourier Transform Infrared (FTIR) and Scanning Electron Microscopy (SEM), respectively. Results indicated that the addition of hybrid pre-dispersed OMMT/destabilized bentonite nanofillers into the PEVA matrix resulted in greater mechanical performance as compared to the single OMMT or single Bent nanofiller. The best achievement in the tensile strength and elongation at break of the PEVA hybrid nanocomposite was obtained when the hybrid nanofillers was added in the ratio of 4:1 (OMMT: Bent). The SEM analysis showed that the PEVA hybrid nanocomposite with 4OMMT: 1Bent had greater matrix deformation than the neat PEVA when subjected to tensile load. This mechanical deformation could be related to the increased flexibility of the PEVA chains which facilitated more energy absorption during the stretching of the material. Apparently, this mechanism acted as a matrix toughening process which allowed the increment of both tensile strength and elongation at break values of the PEVA upon the addition of the hybrid nanofillers.
  • Publication
    Interfacial Bonding Mechanisms of Natural Fibre-Matrix Composites: An Overview
    ( 2022-01-01)
    Mohammed M.
    ;
    Rasidi M.S.M.
    ;
    Mohammed A.M.
    ;
    ; ; ;
    Betar B.O.
    ;
    Dahham O.S.
    The development of natural fiber (NFr) composites for a variety of applications is on the rise. The optimization of the interfacial bonding (IFB) between the reinforcing NFr and polymer matrix is perhaps the single most critical aspect in the development of natural fibre polymer composites (NFPCs) with high mechanical performance. While the IFB is critical in determining the mechanical properties of the NFPCs, such as stress transfer, it is one of the least understood components. This article offers a summary of IFB mechanisms, different modification approaches targeted at lowering incompatibility and improving IFB, and evaluation of the impact of IFB. It has been found that 1) In general, interdiffusion, electrostatic adhesion, chemical reactions, and mechanical interlocking are accountable for the IFB; 2) the incompatibility of the fibre and matrix, which results in poor dispersion of the fiber, weak IFB, and ultimately worse composite quality, may be addressed through strategic modifications; and 3) Interfacial interactions between polymers and nanoparticles (NPs) are significantly improving their performance in areas like thermal, mechanical, robust IFB, and moisture absorption. As a result, this review study could be an important resource for scholars interested in coating and treating NFr to further enhance their surface characteristics.
      3  24
  • Publication
    Micromechanical modeling of polyamide 11 nanocomposites properties using composite theories
    The use of organically modified clays as nano-reinforcement in polymer matrices is widely investigated owing to their remarkable reinforcement at low filler loading. In this body of work, the nanocomposites were prepared by melt blending nanoclay with polyamide 11 (PA 11) utilising a twin-screw extruder in order to maximise the dispersion of clay particles within the matrix during compounding. The main aim of the work was to study the reinforcing effect of nanoclay within PA 11 using two micromechanical model namely Halpin-Tsai and Mori-Tanaka composite theories. These theories were used to predict the effective tensile modulus of PA 11 nanocomposites and the results were compared to the experimental data. In addition, the Halpin-Tsai model was used to predict the storage modulus and heat distortion temperature (HDT) of PA 11 nanocomposites. It was found that the tensile modulus for nanocomposites with a high clay aspect ratio exhibits up to 10% higher when compared to the nanocomposites with lower clay aspect ratio. Thus, it is believed that the combination of clay aspect ratio and modulus contributes to the super reinforcing effect of nanoclay within the PA 11 matrix.
      1  18
  • Publication
    Toughening mechanism of thermoplastic starch nano-biocomposite with the hybrid of nanocellulose/nanobentonite
    (Elsevier, 2023)
    Lai Di Sheng
    ;
    ; ;
    Mariatti Jaafar@Mustapha
    ;
    ;
    High flexibility and toughness are key criteria for an effective bioplastic packaging film. However, in most studies, the flexibility of thermoplastic starch (TPS) films is always neglected when targeting their tensile strength improvement. Low film flexibility has limited the development of TPS films in replacing the petrochemical-based plastic packaging films. In this communication, we report a method to produce thermoplastic corn starch (TPCS) films with excellent mechanical strength, high flexibility and high toughness through the hybridization of two natural nanofillers: nanobentonite and nanocellulose. The synergistic effect of the hybrid nanofillers can be observed through the arrangement of alternating nacre structures where the nanobentonite silicate layers are responsible for mechanical strength, while the nanocellulose promotes free volume in the TPCS matrix and triggers high film elongation at break. Structural, morphological, and thermomechanical analysis were conducted, and the detailed strengthening mechanism of the TPCS hybrid nano-biocomposite films was revealed.
      5  28
  • Publication
    Physical, mechanical and thermal properties of hybrid epoxy multi-walled carbon nanotubes silicon carbide conductive nanocomposites
    ( 2024-12)
    Nurul Hani Noor Asmadi
    ;
    Siti Salmi Samsudin
    ;
    ; ;
    This study investigates the efficacy of an epoxy composite system that incorporates hybrid nanofillers consisting of multi-walled carbon nanotubes (MWCNTs), and silicon carbide nanoparticles (SiCs), as a means of reinforcing epoxy matrices with enhanced thermal properties. The fabrication of epoxy hybrid nanocomposites was carried out through a solution mixing process involving ultrasonication and planetary centrifugal mixing. Before proceed with the analysing synergistic effect of hybrid filler ratios, the samples were first being investigated on the effect of filler loadings to determine the optimal fillers loading, and it was discussed in other study. It was found that there was a correlation between the thermal properties of the specimens and their respective filler loadings, which an increase in filler loadings led to an increase in thermal properties. The incorporation of 4 vol.% of MWCNTs resulted in a significant enhancement of the thermal conductivity of the composites, reaching a value of 0.46 W/mK. This represents a doubling of the thermal conductivity compared to that of pure epoxy (~0.2 W/mK). Moreover, the hybrid fillers loadings of 3vol.% MWCNT+1vol.% SiC shows a higher thermal conductivity value of 0.48 W/mK which indicates the synergistic effects of hybrid fillers. The epoxy matrix exhibited uniform dispersion of MWCNTs and SiCs, resulting in the establishment of thermally conductive pathways.
      15  1
  • Publication
    Network Structure and Mechanical Properties of Flexible Electronic Interconnects based on Linear Low-Density Polyethylene (LLDPE) and Liquid Silicone Rubber (LSR) Conductive Polymer Composites
    Conductive polymer composites (CPCs) with the ability to maintain high conductivity whilst remaining flexible at various operating temperatures and conditions have gained interest as potential materials for electronic interconnect applications. The ability of a polymer matrix to conduct electricity is mainly dependent on the conductive filler loadings as well as the formation of network paths within the CPCs. The main aim of this research work was to establish and understand the correlation between the network structure formation and mechanical properties of linear low-density polyethylene/copper (LLDPE/Cu) and liquid silicone rubber/copper (LSR/Cu) CPCs. Various techniques such as electron microscopy, thermal studies, four-point probe, and tensile testing were employed in this study. Furthermore, selected samples were characterized and tested using synchrotron micro-x-ray fluorescence (XRF) technique and dynamic mechanical analysis (DMA). It was found that the electrical conductivity of the CPCs increased with increasing filler loadings. Addition of Cu filler had a marginal effect on the tensile strength of both LLDPE/Cu and LSR/Cu CPCs. Nevertheless, it was found that the elongation at break for LLDPE/Cu consistently increased with the addition of Cu whereas, for LSR/Cu samples, the elongation at break decreased with the addition of Cu at various loadings. The scanning electron microscopy (SEM) micrographs obtained show that the particles of Cu were closer to one another at higher filler loadings. The data obtained revealed the potential for utilizing CPCs as flexible interconnects suitable for advanced electronic applications.
      1
  • Publication
    MicroMechanical Modeling of PolyaMide 11 nanocoMPosites ProPerties using coMPosite theories
    The use of organically modified clays as nano-reinforcement in polymer matrices is widely investigated owing to their remarkable reinforcement at low filler loading. In this body of work, the nanocomposites were prepared by melt blending nanoclay with polyamide 11 (PA 11) utilising a twin-screw extruder in order to maximise the dispersion of clay particles within the matrix during compounding. The main aim of the work was to study the reinforcing effect of nanoclay within PA 11 using two micromechanical model namely Halpin-Tsai and Mori-Tanaka composite theories. These theories were used to predict the effective tensile modulus of PA 11 nanocomposites and the results were compared to the experimental data. In addition, the Halpin-Tsai model was used to predict the storage modulus and heat distortion temperature (HDT) of PA 11 nanocomposites. It was found that the tensile modulus for nanocomposites with a high clay aspect ratio exhibits up to 10% higher when compared to the nanocomposites with lower clay aspect ratio. Thus, it is believed that the combination of clay aspect ratio and modulus contributes to the super reinforcing effect of nanoclay within the PA 11 matrix.
      1  24
  • Publication
    Physical, thermal transport, and compressive properties of epoxy composite filled with graphitic- and ceramic-based thermally conductive nanofillers
    ( 2022)
    Siti Salmi Samsudin
    ;
    ; ; ;
    Mariatti Jaafar
    ;
    Hassan A. Alshahrani
    Epoxy polymer composites embedded with thermally conductive nanofillers play an important role in the thermal management of polymer microelectronic packages, since they can provide thermal conduction properties with electrically insulating properties. An epoxy composite system filled with graphitic-based fillers; multi-walled carbon nanotubes (MWCNTs), graphene nanoplatelets (GNPs) and ceramic-based filler; silicon carbide nanoparticles (SiCs) was investigated as a form of thermal-effective reinforcement for epoxy matrices. The epoxy composites were fabricated using a simple fabrication method, which included ultrasonication and planetary centrifugal mixing. The effect of graphite-based and ceramic-based fillers on the thermal conductivity was measured by the transient plane source method, while the glass transition temperature of the fully cured samples was studied by differential scanning calorimetry. Thermal gravimetric analysis was adopted to study the thermal stability of the samples, and the compressive properties of different filler loadings (1–5 vol.%) were also discussed. The glass temperatures and thermal stabilities of the epoxy system were increased when incorporated with the graphite- and ceramic-based fillers. These results can be correlated with the thermal conductivity of the samples, which was found to increase with the increase in the filler loadings, except for the epoxy/SiCs composites. The thermal conductivity of the composites increased to 0.4 W/mK with 5 vol.% of MWCNTs, which is a 100% improvement over pure epoxy. The GNPs, SiCs, and MWCNTs showed uniform dispersion in the epoxy matrix and well-established thermally conductive pathways.
      1  11
  • Publication
    Methyl Methacrylate (MMA) treatment of Empty Fruit Bunch (EFB) to improve the properties of regenerated cellulose biocomposite films
    (MDPI, 2020)
    Salmah Husseinsyah
    ;
    Nur Liyana Izyan Zailuddin
    ;
    ;
    Chew Li Li
    ;
    Awad A. Alrashdi
    ;
    Abdulkader Alakrach
    The empty fruit bunch (EFB) regenerated cellulose (RC) biocomposite films for packaging application were prepared using ionic liquid. The effects of EFB content and methyl methacrylate (MMA) treatment of the EFB on the mechanical and thermal properties of the RC biocomposite were studied. The tensile strength and modulus of elasticity of the MMA treated RC biocomposite film achieved a maximum value when 2 wt% EFB was used for the regeneration process. The treated EFB RC biocomposite films also possess higher crystallinity index. The morphology analysis indicated that the RC biocomposite film containing MMA treated EFB exhibits a smoother and more homogeneous surface compared to the one containing the untreated EFB. The substitution of the –OH group of the EFB cellulose with the ester group of the MMA resulted in greater dissolution of the EFB in the ionic liquid solvent, thus improving the interphase bonding between the filler and matrix phase of the EF RC biocomposite. Due to this factor, thermal stability of the EFB RC biocomposite also successfully improved.
      6  14