Now showing 1 - 10 of 36
  • Publication
    Annealing Effects on Polycrystalline Silicon Germanium (SiGe) Thin Films grown on Nanostructured Silicon Substrates using Thermal Evaporation Technique
    ( 2022-10-01) ;
    Eop T.S.
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    ;
    Sopian K.
    ;
    ;
    Zaidi S.H.
    Polycrystalline SiGe thin films have been formed after thermal annealing of formerly vacuum evaporated a-Ge layers. The a-Ge thin films were deposited onto nanostructured Si substrates via low-cost thermal evaporation method. Then, the films were annealed in a furnace at temperatures ranging from 400 °C to 1000 °C resulting in crystal growth of the SiGe layers. In general, the annealing temperature for polycrystalline SiGe is between 600 °C – 800 °C. The crystalline structure of the SiGe layer is improved as a function of increased temperature. This is shown by the low FWHM of about 5.27 as compared to the commercially available Ge substrates where the FWHM value is about 5.06. This method also produces more relax Ge layer where the strain value is 0.261.
  • Publication
    Mesoporous Structure of Doped and Undoped PEG on Ag/TiO2 Thin Film
    In this reaserch, photocatalyst silver titanium dioxide was doped and modified by Polyethylene Glycol (PEG). The purpose of the present study was to analyse the synthesized Ag/TiO2 thin film doped and undoped PEG. Ag/TiO2 thin films on silicon wafer have been prepared by sol-gel spin coating. The samples were characterized by Grazing Incidence X-ray diffraction (GIXRD), Field Emission Scanning Electron Microscopy (FESEM) and Atomic Force Microscope (AFM). The doped and undoped PEG Ag/TiO2 thin films showed a mesoporous TiO2 matrix which includes TiO2 crystallites of 10-20 nm in size and small Ag nanoparticles (white spots) with various sizes ranging from 10 to 30 nm. However, doped PEG Ag/TiO2 thin film showed the Ag nanoparticles became agglomerates but still remained roughly uniform on the surface.
  • Publication
    Annealing effects on polycrystalline silicon germanium (SiGe) thin films grown on nanostructured silicon substrates using thermal evaporation technique
    ( 2022-10) ;
    Eop, T. S.
    ;
    ;
    Sopian, K.
    ;
    ;
    Zaidi, S. H.
    Polycrystalline SiGe thin films have been formed after thermal annealing of formerly vacuum evaporated a-Ge layers. The a-Ge thin films were deposited onto nanostructured Si substrates via low-cost thermal evaporation method. Then, the films were annealed in a furnace at temperatures ranging from 400 °C to 1000 °C resulting in crystal growth of the SiGe layers. In general, the annealing temperature for polycrystalline SiGe is between 600 °C – 800 °C. The crystalline structure of the SiGe layer is improved as a function of increased temperature. This is shown by the low FWHM of about 5.27 as compared to the commercially available Ge substrates where the FWHM value is about 5.06. This method also produces more relax Ge layer where the strain value is 0.261.
  • Publication
    Interdigitated electrodes as impedance and capacitance biosensors: A review
    Interdigitated electrodes (IDEs) are made of two individually addressable interdigitated comb-like electrode structures. IDEs are one of the most favored transducers, widely utilized in technological applications especially in the field of biological and chemical sensors due to their inexpensive, ease of fabrication process and high sensitivity. In order to detect and analyze a biochemical molecule or analyte, the impedance and capacitance signal need to be obtained. This paper investigates the working principle and influencer of the impedance and capacitance biosensors. The impedance biosensor depends on the resistance and capacitance while the capacitance biosensor influenced by the dielectric permittivity. However, the geometry and structures of the interdigitated electrodes affect both impedance and capacitance biosensor. The details have been discussed in this paper.
  • Publication
    Effect of graphene oxide on microstructure and optical properties of TiO2 thin film
    ( 2019-01-01)
    Azani A.
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    ;
    Razak K.A.
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    ;
    Mohd Salleh M.A.A.
    ;
    Abdul Razak M.F.S.
    ;
    ;
    Ramli M.M.
    ;
    ;
    Chobpattana V.
    GO/TiO2 thin films have been synthesized from titanium (IV) isopropoxide (TTIP) by a sol-gel method. The films were deposited onto a glass substrate using spin coating deposition technique then were subjected to annealed process at 350 °C. The different amount of graphene oxide (GO) was added into the parent solution of sol in order to investigate the microstructure, topography, optical band gap and photocatalytic activity of the thin films. The prepared thin films were characterized by atomic force microscopy (AFM), scanning electron microscopy (SEM), UV-VIS spectrophotometry and degradation of methylene blue (MB). AFM images reveal a rougher surface of GO/TiO2 thin film than bare TiO2 thin film due to GO particles. Moreover, the SEM images showed the formation of semispherical microstructure of bare TiO2 changes to some larger combined molecules with GO addition. The UV-Vis spectrophotometer results show that with optical direct energy gap decreases from 3.30 to 3.18 eV after GO addition due to the effect of high surface roughness and bigger grain size. Furthermore, the optical results also indicated that GO improved the optical properties of TiO2 in the visible range region.
  • Publication
    Microstructure evolution of Ag/TiO2 thin film
    ( 2021) ; ; ;
    Mohd Izrul Izwan Ramli
    ;
    ; ;
    Kazuhiro Nogita
    ;
    Hideyuki Yasuda
    ;
    Marcin Nabiałek
    ;
    Jerzy J. Wysłocki
    Ag/TiO2 thin films were prepared using the sol-gel spin coating method. The microstructural growth behaviors of the prepared Ag/TiO2 thin films were elucidated using real-time synchrotron radiation imaging, its structure was determined using grazing incidence X-ray diffraction (GIXRD), its morphology was imaged using the field emission scanning electron microscopy (FESEM), and its surface topography was examined using the atomic force microscope (AFM) in contact mode. The cubical shape was detected and identified as Ag, while the anatase, TiO2 thin film resembled a porous ring-like structure. It was found that each ring that coalesced and formed channels occurred at a low annealing temperature of 280 °C. The energy dispersive X-ray (EDX) result revealed a small amount of Ag presence in the Ag/TiO2 thin films. From the in-situ synchrotron radiation imaging, it was observed that as the annealing time increased, the growth of Ag/TiO2 also increased in terms of area and the number of junctions. The growth rate of Ag/TiO2 at 600 s was 47.26 µm2/s, and after 1200 s it decreased to 11.50 µm2/s and 11.55 µm2/s at 1800 s. Prolonged annealing will further decrease the growth rate to 5.94 µm2/s, 4.12 µm2/s and 4.86 µm2/s at 2400 s, 3000 s and 3600 s, respectively.
  • Publication
    Surface Modification of GO/TiO2 Thin Film by Sodium Dodecyl Sulphate for Photocatalytic Applications
    Photocatalyst material titanium dioxide (TiO2) and graphene oxide (GO) were used to improve the self-cleaning properties of thin films. The sol–gel spin-coating method was successfully used to synthesize GO/TiO2 thin films. Surface modification was applied to optimize the self-cleaning capabilities by adding several concentrations of sodium dodecyl sulfate (SDS) (0.1 w/v%, 0.2 w/v%, 0.3 w/v%, 0.4 w/v%, and 0.5 w/v%) to the parent solution. The synthesized thin films were investigated using scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray diffraction, UV-visible spectroscopy, water contact angle analysis, and photocatalytic analysis. The AFM and SEM images revealed that as the SDS amount increased, the particles became less agglomerated, and the roughness of the surface reduced from 2.54 × 102 nm to 0.83 × 102 nm. The wettability analysis showed that when SDS increased to 0.4 w/v%, the water contact angle dropped to 15.30°, implying that the thin film exhibits hydrophilic qualities. A decrease in the GO/TiO2 band gap was obtained linearly with the increase in SDS addition from 3.17 eV to 2.75 eV. Finally, the improvement of the surface coating and reduction of the band gap enhanced the photocatalytic activity, which degraded 78.97% of methylene blue, which was obtained by 0.4SDS.
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  • Publication
    Factors of Controlling the Formation of Titanium Dioxide (TiO2) Synthesized using Sol-gel Method - A Short Review
    ( 2022-01-24)
    Abdul Razak K.
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    ; ; ;
    Mahmed N.
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    Azani A.
    ;
    Chobpattana V.
    There have been experiments on TiO2 thin films synthesized utilizing sol-gel techniques. The sol-gel method is a straightforward technology that gives numerous benefits to the researcher, for instance, material's reliability, reproducibility, and controllability. Following from there, it can be utilized to make high-quality nano-structured thin films. According to previous studies, the TiO2 films' characteristics occur to be highly dependent on the production parameters and initial materials utilized. Controlling the formation of TiO2 thin films with the sol-gel method was momentarily discussed here.
      2
  • Publication
    The effect of GO/TiO2 thin film during photodegradation of methylene blue dye
    Titanium (IV) isopropoxide (TTIP) was used to synthesize GO/TiO2 thin films using a sol-gel spin-coating method onto a glass substrate, undergoing an heat tretment at 350 °C. Several amounts of graphene oxide (GO) (0-20mg) were weighed into a sol solution of TiO2 to produce GO/TiO2 thin films. The thin film samples were characterized by X-ray diffraction (XRD) to analyze the samples’ phase and by scanning electron microscopy (SEM) to analyze the samples’ microstructure. Physical testing such as water contact angle (WCA) was analyzed using an optical microscope with J-Image software. In contrast, the optical band gap and photodegradation of methylene blue under sunlight irradiation of the thin film was analyzed using UV-VIS spectrophotometry. GO5 thin film sample showed low-intensity anatase phase formation, where the microstructure revealed a larger surface area with the addition of GO. WCA reveals that GO/TiO2 thin film exhibits super hydrophilic properties where the angle decreases from 37.83° to 4.11°. The optical result shows that GO has improved the absorption edges by expanding into visible regions. Moreover, due to the existence of GO 3.30 eV band gap energy of TiO2 decreases from to 3.18 eV obtained by GO5. The improved adsorption edge allows Ti3+, O2 and interstitial states to be formed in low valence states with energy underneath than in the TiO2 band gap. Therefore, the photodegradation of methylene blue (MB) dye increases from 48 % to 59 % in the GO/TiO2 thin film.
      4  1
  • Publication
    Potential Applications of Geopolymer Cement-Based Composite as Self-Cleaning Coating: A Review
    Nowadays, concepts of self-cleaning have received great attention in construction building materials. Self-cleaning with the presence of photocatalyst has been applied in building materials to overcome the problem of building surfaces becoming dirty after exposure for a long time in highly polluted areas. To date, the concept of green blending materials has led to the development of a new binding material for green materials, which is geopolymer with an addition of photocatalyst. This review focused on the development of conventional self-cleaning paste, including the method of preparation and the impact of adding photocatalyst on physical and mechanical properties. However, although self-cleaning has been widely applied in conventional cement paste, its applications in geopolymers are still in the early stages of development and require more research. Therefore, this paper also intended to review the current knowledge on properties of geopolymer cement-based composite and its potential to be applied as a self-cleaning coating.
      1