Now showing 1 - 9 of 9
  • Publication
    Thermal insulation and mechanical properties in the presence of glass bubble in fly ash geopolymer paste
    ( 2022-01-01)
    Noor Fifinatasha Shahedan
    ;
    ; ; ; ;
    Ikmal Hakem Abdul Aziz
    ;
    Kadir A.A.
    ;
    Sandu A.V.
    ;
    The density, compressive strength, and thermal insulation properties of fly ash geopolymer paste are reported. Novel insulation material of glass bubble was used as a replacement of fly ash binder to significantly enhance the mechanical and thermal properties compared to the geopolymer paste. The results showed that the density and compressive strength of 50% glass bubble was 1.45 g/ cm3 and 42.5 MPa, respectively, meeting the standard requirement for structural concrete. Meanwhile, the compatibility of 50% glass bubbles tested showed that the thermal conductivity (0.898 W/mK), specific heat (2.141 MJ/m3K), and thermal diffusivity (0.572 mm2/s) in meeting the same requirement. The improvement of thermal insulation properties revealed the potential use of glass bubbles as an insulation material in construction material.
      1  37
  • Publication
    Thermal Insulation and Mechanical Properties in the Presence of Glas Bubble in Fly Ash Geopolymer Paste
    The density, compressive strength, and thermal insulation properties of fly ash geopolymer paste are reported. Novel insulation material of glass bubble was used as a replacement of fly ash binder to significantly enhance the mechanical and thermal properties compared to the geopolymer paste. The results showed that the density and compressive strength of 50% glass bubble was 1.45 g/ cm3 and 42.5 MPa, respectively, meeting the standard requirement for structural concrete. Meanwhile, the compatibility of 50% glass bubbles tested showed that the thermal conductivity (0.898 W/mK), specific heat (2.141 MJ/m3K), and thermal diffusivity (0.572 mm2/s) in meeting the same requirement. The improvement of thermal insulation properties revealed the potential use of glass bubbles as an insulation material in construction material.
      40  8
  • Publication
    Producing Metal Powder from Machining Chips Using Ball Milling Process: A Review
    ( 2023-07-01) ; ; ;
    Yin A.T.M.
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    ; ;
    Nemeș O.
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    Sandu A.V.
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    Vizureanu P.
    ;
    Abdellah A.E.h.
    In the pursuit of achieving zero emissions, exploring the concept of recycling metal waste from industries and workshops (i.e., waste-free) is essential. This is because metal recycling not only helps conserve natural resources but also requires less energy as compared to the production of new products from virgin raw materials. The use of metal scrap in rapid tooling (RT) for injection molding is an interesting and viable approach. Recycling methods enable the recovery of valuable metal powders from various sources, such as electronic, industrial, and automobile scrap. Mechanical alloying is a potential opportunity for sustainable powder production as it has the capability to convert various starting materials with different initial sizes into powder particles through the ball milling process. Nevertheless, parameter factors, such as the type of ball milling, ball-to-powder ratio (BPR), rotation speed, grinding period, size and shape of the milling media, and process control agent (PCA), can influence the quality and characteristics of the metal powders produced. Despite potential drawbacks and environmental impacts, this process can still be a valuable method for recycling metals into powders. Further research is required to optimize the process. Furthermore, ball milling has been widely used in various industries, including recycling and metal mold production, to improve product properties in an environmentally friendly way. This review found that ball milling is the best tool for reducing the particle size of recycled metal chips and creating new metal powders to enhance mechanical properties and novelty for mold additive manufacturing (MAM) applications. Therefore, it is necessary to conduct further research on various parameters associated with ball milling to optimize the process of converting recycled copper chips into powder. This research will assist in attaining the highest level of efficiency and effectiveness in particle size reduction and powder quality. Lastly, this review also presents potential avenues for future research by exploring the application of RT in the ball milling technique.
      7  25
  • Publication
    The Suitability of Photocatalyst Precursor Materials in Geopolymer Coating Applications: A Review
    Today, the building and construction sector demands environmentally friendly and sustainable protective coatings using inorganic coating materials for safe, non-hazardous, and great performance. Many researchers have been working on sustainable solutions to protect concrete and metal infrastructures against corrosion and surface deterioration with the intention of introducing green alternatives to conventional coatings. This article presents a review of developments of geopolymer pastes doped with different types of photocatalyst precursors including factors affecting geopolymer properties for enhancing coating with photocatalytic performance. Photodegradation using geopolymer photocatalyst has great potential for resolving harmless substances and removing pollutants when energized with ultraviolet (UV) light. Although geopolymer is a potentially new material with great properties, there has been less research focusing on the development of this coating. This study demonstrated that geopolymer binders are ideal precursor support materials for the synthesis of photocatalytic materials, with a significant potential for optimizing their distinctive properties.
      1  28
  • Publication
    Thermal insulation and mechanical properties in the presence of glass bubble in fly ash geopolymer paste
    ( 2022-01-01)
    Noor Fifinatasha Shahedan
    ;
    ; ; ; ;
    Ikmal Hakem Abdul Aziz
    ;
    Kadir A.A.
    ;
    Sandu A.V.
    ;
    The density, compressive strength, and thermal insulation properties of fly ash geopolymer paste are reported. Novel insulation material of glass bubble was used as a replacement of fly ash binder to significantly enhance the mechanical and thermal properties compared to the geopolymer paste. The results showed that the density and compressive strength of 50% glass bubble was 1.45 g/ cm3 and 42.5 MPa, respectively, meeting the standard requirement for structural concrete. Meanwhile, the compatibility of 50% glass bubbles tested showed that the thermal conductivity (0.898 W/mK), specific heat (2.141 MJ/m3K), and thermal diffusivity (0.572 mm2/s) in meeting the same requirement. The improvement of thermal insulation properties revealed the potential use of glass bubbles as an insulation material in construction material.
      1
  • Publication
    Potential of soil stabilization using Ground Granulated Blast Furnace Slag (GGBFS) and Fly Ash via Geopolymerization method: A Review
    ( 2022-01-01)
    Syafiadi Rizki Abdila
    ;
    ; ;
    Nergis D.D.B.
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    ; ;
    Sandu A.V.
    ;
    Vizureanu P.
    ;
    Syafwandi
    Geopolymers, or also known as alkali-activated binders, have recently emerged as a viable alternative to conventional binders (cement) for soil stabilization. Geopolymers employ alkaline activation of industrial waste to create cementitious products inside treated soils, increasing the clayey soils’ mechanical and physical qualities. This paper aims to review the utilization of fly ash and ground granulated blast furnace slag (GGBFS)-based geopolymers for soil stabilization by enhancing strength. Previous research only used one type of precursor: fly ash or GGBFS, but the strength value obtained did not meet the ASTM D 4609 (<0.8 Mpa) standard required for soil-stabilizing criteria of road construction applications. This current research focused on the combination of two types of precursors, which are fly ash and GGBFS. The findings of an unconfined compressive strength (UCS) test on stabilized soil samples were discussed. Finally, the paper concludes that GGBFS and fly-ash-based geo-polymers for soil stabilization techniques can be successfully used as a binder for soil stabilization. However, additional research is required to meet the requirement of ASTM D 4609 standard in road construction applications, particularly in subgrade layers.
      2
  • Publication
    Silica Bonding Reaction on Fly Ash Based Geopolymer Repair Material System with Incorporation of Various Concrete Substrates
    ( 2022-01-01) ;
    Ikmal Hakem A. Aziz
    ;
    Zailani W.W.A.
    ;
    ; ;
    Sandu A.V.
    ;
    Loke Siu Peng
    This paper presents an experimental investigation on the mechanical properties and microstructure of geopolymer repair materials mixed using fly ash (FA) and concrete substrates. An optimal combination of FA and concrete substrate was determined using the compressive test of geopolymer mortar mixed with various concrete substrate classes. It was found that the contribution of (C35/45) concrete substrates with the FA geopolymer mortar increases the 28-day bonding strength by 25.74 MPa. The microstructure analysis of the samples using scanning electron microscopy showed the denser structure owing to the availability of high calcium and iron elements distribution. These metal cations (Ca2+ and Fe3+) are available at OPC concrete substrate as a result from the hydration process reacted with alumina-silica sources of FA and formed calcium aluminate silicate hydrate (C-A-S-H) gels and Fe-bonding linkages.
      3
  • Publication
    Potential Applications of Geopolymer Cement-Based Composite as Self-Cleaning Coating: A Review
    Nowadays, concepts of self-cleaning have received great attention in construction building materials. Self-cleaning with the presence of photocatalyst has been applied in building materials to overcome the problem of building surfaces becoming dirty after exposure for a long time in highly polluted areas. To date, the concept of green blending materials has led to the development of a new binding material for green materials, which is geopolymer with an addition of photocatalyst. This review focused on the development of conventional self-cleaning paste, including the method of preparation and the impact of adding photocatalyst on physical and mechanical properties. However, although self-cleaning has been widely applied in conventional cement paste, its applications in geopolymers are still in the early stages of development and require more research. Therefore, this paper also intended to review the current knowledge on properties of geopolymer cement-based composite and its potential to be applied as a self-cleaning coating.
      8  27
  • Publication
    Crumb rubber geopolymer mortar at elevated temperature exposure
    ( 2022-01-01) ; ; ;
    Ahmad R.
    ;
    Jaya R.P.
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    ;
    Almadani M.A.
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    Wysłocki J.J.
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    Śliwa A.
    ;
    Sandu A.V.
    Low calcium fly ash is used as the main material in the mixture and the crumb rubber was used in replacing fine aggregates in geopolymer mortar. Sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) which were high alkaline solution were incorporated as the alkaline solution. The fly ash reacted with the alkaline solution forming alumino-silicate gel that binds the aggregate to produce a geopolymer mortar. The loading of crumb rubber in the fly ash based geopolymer mortar was set at 0% (CRGM-0), 5% (CRGM-5), 10% (CRGM-10), 15% (CRGM-15), and 20% (CRGM-20), respectively. NaOH solution (12M) and Na2SiO3 solution ratio is set constant at 2.5 for all geopolymer mixture and the fly ash to alkali activator ratio was kept at 2.0. The CRGM at 28 days of curing time was exposed to elevated temperature at 200◦C, 400◦C, 600◦C and 800◦C. The weight loss of the CRGM increases with increasing temperature at all elevated temperatures. However, the density and compressive strength of CRGM decrease with an increase of crumb rubber loading for all elevated temperature exposure. The compressive strength of CRGM reduced due to the fact that rubber decomposes between 200◦C and 600◦C thereby creating voids. CRGM-15 and CRGM-20 showed cracks developed with rough surface at 800◦C. Image obtained from scanning electron microscope (SEM) showed that, the CRGM changed significantly due to the decomposition of crumb rubber and evaporation of the free water at 400◦C, 600◦C and 800◦C.
      1  35