Now showing 1 - 9 of 9
  • Publication
    Evaluation of the effect of silica fume on amorphous fly ash geopolymers exposed to elevated temperature
    ( 2021)
    Ong Huey Li
    ;
    ; ;
    Ridho Bayuaji
    ;
    ; ; ;
    Ng Hui Teng
    ;
    Marcin Nabiałek
    ;
    Bartlomiej Jeż
    ;
    Ng Yong Sing
    The properties of amorphous geopolymer with silica fume addition after heat treatment was rarely reported in the geopolymer field. Geopolymer was prepared by mixing fly ash and alkali activator. The silica fume was added in 2% and 4% by weight. The geopolymer samples were cured at room temperature for 28 days before exposed to an elevated temperature up to 1000 °C. The incorporation of 2% silica fume did not cause significant improvement in the compressive strength of unexposed geopolymer. Higher silica fume content of 4% reduced the compressive strength of the unexposed geopolymer. When subjected to elevated temperature, geopolymer with 2% silica fume retained higher compressive strength at 1000 °C. The addition of silica fume in fly ash geopolymer caused a lower degree of shrinkage and expansion, as compared to geopolymer without the addition of silica fume. Crystalline phases of albite and magnetite were formed in the geopolymer at 1000 °C.
  • Publication
    Fabrication and characterization of ZnO nanostructures for DNA detection
    Zinc oxide (ZnO), a representative of group II-IV metal-oxide semiconductor material is widely studied in the current research community. ZnO with its wide direct band-gap (3.37eV) and high exciton binding energy (60meV) providing the advantages of their electrical and optical properties. Due to these unique properties and easiness to grow using bottom-up approach combines with high isoelectric point, toxic-free, high surface-area-to-volume ratio, biosafe, and biocompatible, ZnO nanostructures have great interest in the application of biosensor. The aim of this research work is to synthesis, fabricate, and characterize ZnO nanostructures based sensor for DNA immobilization and hybridization detection. Two types of ZnO nanostructures were studied, namely thin films and nanorods (NRs). Highly transparent ZnO thin films were successfully synthesized using ease and low-cost sol-gel spin-coating method. ZnO NRs with nanoscale possessed high crystalline structure was further grown from the asprepared thin films through low-temperature hydrothermal growth. In this thesis, we studied the influence of different solvents on the structure, optical and electrical properties of the ZnO nanostructures. Four types of solvents namely methanol, ethanol, isopropanol, and 2-methoxyethanol had been chosen for ZnO seed solution preparation. The observed results using FESEM indicated that the nanoparticles and nanorods with the size less than 40 nanometer and 60 nanometer, respectively were successfully synthesized. The investigation on optical properties using UV-Vis-NIR spectrophotometer confirmed ZnO is classified as a wide band gap semiconductor material. In order to fabricate a biosensor with high sensitivity and selectivity, a gold nanoparticles (GNPs) were selected for the surface modification of ZnO nanostructures which later formed gold-thiolate conjugation with thiol-modified ssDNA probes. Two approaches were used for the immobilization and hybridization of DNA detection, which were dielectric analysis and electrochemical analysis. DNA detection using dielectric analyzer was done on interdigitated electrodes gold modified ZnO thin films. The developed sensor clearly differentiated complementary and non-complementary of target DNA through the measurement of capacitance, permittivity, and impedance. DNA detection using electrochemical analysis with cyclic voltammetry confirmed surface ZnO NRs modified with (3-Aminopropyl)triethoxysilane (APTES) and gold nanoparticles provided better detection of target DNA in comparison with those only contained gold nanoparticles.
  • Publication
    Low temperature annealed zinc oxide nanostructured thin film-based transducers: Characterization for sensing applications
    ( 2015)
    R. Haarindraprasad
    ;
    ; ;
    Muhammad Kashif
    ;
    P. Veeradasan
    ;
    S. R. Balakrishnan
    ;
    ;
    The performance of sensing surfaces highly relies on nanostructures to enhance their sensitivity and specificity. Herein, nanostructured zinc oxide (ZnO) thin films of various thicknesses were coated on glass and p-type silicon substrates using a sol-gel spin-coating technique. The deposited films were characterized for morphological, structural, and optoelectronic properties by high-resolution measurements. X-ray diffraction analyses revealed that the deposited films have a c-axis orientation and display peaks that refer to ZnO, which exhibits a hexagonal structure with a preferable plane orientation (002). The thicknesses of ZnO thin films prepared using 1, 3, 5, and 7 cycles were measured to be 40, 60, 100, and 200 nm, respectively. The increment in grain size of the thin film from 21 to 52 nm was noticed, when its thickness was increased from 40 to 200 nm, whereas the band gap value decreased from 3.282 to 3.268 eV. Band gap value of ZnO thin film with thickness of 200 nm at pH ranging from 2 to 10 reduces from 3.263eV to 3.200 eV. Furthermore, to evaluate the transducing capacity of the ZnO nanostructure, the refractive index, optoelectric constant, and bulk modulus were analyzed and correlated. The highest thickness (200 nm) of ZnO film, embedded with an interdigitated electrode that behaves as a pH-sensing electrode, could sense pH variations in the range of 2-10. It showed a highly sensitive response of 444 μAmM-1cm-2 with a linear regression of R2 =0.9304. The measured sensitivity of the developed device for pH per unit is 3.72μA/pH.
  • Publication
    Effective synthesis of silicon carbide nanotubes by microwave heating of blended silicon dioxide and multi-walled carbon nanotube
    Silicon carbide nanotube (SiCNTs) has been proven as a suitable material for wide applications in high power, elevated temperature and harsh environment. For the first time, we reported in this article an effective synthesis of SiCNTs by microwave heating of SiO2 and MWCNTs in molar ratio of 1:1, 1:3, 1:5 and 1:7. Blend of SiO2 and MWCNTs in the molar ratio of 1:3 was proven to be the most suitable for the high yield synthesis of β-SiCNTs as confirmed by X-ray diffraction pattern. Only SiCNTs were observed from the blend of MWCNTs and SiO2 in the molar ratio of 1:3 from field emission scanning electron microscopy imaging. High magnification transmission electron microscopy showed that tubular structure of MWCNT was preserved with the inter-planar spacing of 0.25 nm. Absorption bands of Si-C bond were detected at 803 cm-1 in Fourier transform infrared spectrum. Thermal gravimetric analysis revealed that SiCNTs from ratio of 1:3 showed the lowest weight loss. Thus, our synthetic process indicates high yield conversion of SiO2 and MWCNTs to SiCNTs was achieved for blend of SiO2 and MWCNTs in molar ratio of 1:3.
  • Publication
    Effect of temperature of oxalic acid on the fabrication of porous anodic alumina from A1-Mn alloys
    The influence of temperature of oxalic acid on the formation of well-ordered porous anodic alumina on Al-0.5 wt% Mn alloys was studied. Porous anodic alumina has been produced on Al-0.5 wt% Mn substrate by single-step anodising at 50 V in 0.5 M oxalic acid at temperature ranged from 5°C to 25°C for 60 minutes. The steady-state current density increased accordingly with the temperature of oxalic acid. Hexagonal pore arrangement was formed on porous anodic alumina that was formed in oxalic acid of 5, 10 and 15°C while disordered porous anodic alumina was formed in oxalic acid of 20 and 25°C. The temperature of oxalic acid did not affect the pore diameter and interpore distance of porous anodic alumina. Both rate of increase of thickness and oxide mass increased steadily with increasing temperature of oxalic acid, but the current efficiency decreased as the temperature of oxalic acid increased due to enhanced oxide dissolution from pore wall.
  • Publication
    Comparative mechanical and microstructural properties of high calcium fly ash one-part geopolymers activated with Na2SiO3-anhydrous and NaAlO2
    ( 2021)
    Ooi Wan-En
    ;
    ; ; ; ; ;
    Ong Shee-Ween
    ;
    Ng Hui-Teng
    ;
    Ng Yong-Sing
    ;
    ;
    Long-Yuan Li
    This paper investigates the effect of varying solid alkali activators on the fresh and hardened properties and microstructural changes of one-part geopolymers (OPGs). Single and binary solid alkali activators were used to activate high calcium fly ash. The alkali activators were either solely sodium metasilicate (Na2SiO3) or a combination of sodium aluminate (NaAlO2) and sodium metasilicate (Na2SiO3). The OPG activated with anhydrous Na2SiO3 achieved an excellent 28-day compressive strength of 83.6 MPa while OPG activated with NaAlO2 and Na2SiO3 attained a compressive strength of 45.1 MPa. The Na2SiO3-activated OPG demonstrated better fluidity than the OPG activated with NaAlO2 and Na2SiO3 due to the thixotropic behaviour caused by the NaAlO2. The Na2SiO3-activated OPG consisted of sodium-calcium aluminium silicate hydrate ((N,C)-A-S-H) gel phase, while the OPG activated with NaAlO2 and Na2SiO3 comprised of the coexistence of sodium aluminium silicate hydrate (N-A-S-H) and calcium aluminium silicate hydrate (C-A-S-H) gel phases. Regardless of the distinctive properties, the OPGs are adequate for building materials applications.
  • Publication
    Morphological, structural, and electrical characterization of sol-gel-synthesized ZnO nanorods
    ( 2013-02-03)
    M. Kashif
    ;
    ;
    M. E. Ali
    ;
    ;
    Syed M. Usman Ali
    ZnO nanorods were grown on thermally oxidized p-type silicon substrate using sol-gel method. The SEM image revealed high-density, well-aligned, and perpendicular ZnO nanorods on the oxidized silicon substrate. The XRD profile confirmed thec-axis orientation of the nanorods. PL measurements showed the synthesized ZnO nanorods have strong ultraviolet (UV) emission. The electrical characterization was performed using interdigitated silver electrodes to investigate the stability in the current flow of the fabricated device under different ultraviolet (UV) exposure times. It was notified that a stable current flow was observed after 60 min of UV exposure. The determination of stable current flow after UV exposure is necessary for UV-based gas sensing and optoelectronic devices.
  • Publication
    Hydrothermal growth zinc oxide nanorods for pH sensor application
    The aim of this work is to apply synthesized zinc oxide (ZnO) Nanorods using hydrothermal (HTL) growth technique for pH sensor application. The highly crystallite of ZnO Nanorods was obtained by anneal the growth ZnO Nanorods in furnace at 200°C for 2 hours. Besides that, XRD analysis shows the produced ZnO Nanorods belonged to the (002) plane. Furthermore, Scanning Electron Microscope (SEM) images confirm that the ZnO Nanorods with hexagonal-faceted structural were successfully produced by HTL growth technique. In addition, Ultraviolet–visible (UV-Vis) spectrophotometer analysis shows that the synthesized ZnO belongs to the wide band gap semiconductor material. The growing ZnO Nanorods were then subjected to electrical measurement with various pH levels. The outcome demonstrates that the current rises as the solution changes from acidic to alkaline. Overall, our study shows a relationship between the electrical as well as the structural characteristics of ZnO Nanorods at various pH levels.