Options
Sam Sung Ting
Preferred name
Sam Sung Ting
Official Name
Sam, Sung Ting
Alternative Name
Sam, Sung Ting
Sung Ting, Sam
Tingf, Sam Sung
Ting, Sam Sung
Sam, S. T.
Sam, T. S.
Main Affiliation
Scopus Author ID
57198446841
Researcher ID
AAU-8590-2020
Now showing
1 - 10 of 20
-
PublicationInfluence of filler surface modification on static and dynamic mechanical responses of rice husk reinforced linear low-density polyethylene composites( 2021)
;B. Jeż ;M. Nabiałek ;Hazizan Md AkilFiller surface modification has become an essential approach to improve the compatibility problem between natural fillers and polymer matrices. However, there is limited work that concerns on this particular effect under dynamic loading conditions. Therefore, in this study, both untreated and treated low linear density polyethylene/rice husk composites were tested under static (0.001 s–1, 0.01 s–1 and 0.1 s–1) and dynamic loading rates (650 s–1, 900 s–1 and 1100 s–1) using universal testing machine and split Hopkinson pressure bar equipment, respectively. Rice husk filler was modified using silane coupling agents at four different concentrations (1, 3, 5 and 7% weight percentage of silane) at room temperature. This surface modification was experimentally proven by Fourier transform infrared and Field emission scanning electron microscopy. Results show that strength properties, stiffness properties and yield behaviour of treated composites were higher than untreated composites. Among the treated composites, the 5% silane weight percentage composite shows the optimum mechanical properties. Besides, the rate of sensitivity of both untreated and treated composites also shows great dependency on strain rate sensitivity with increasing strain rate. On the other hand, the thermal activation volume shows contrary trend. For fracture surface analysis, the results show that the treated LLDPE/RH composites experienced less permanent deformation as compared to untreated LLDPE/RH composites. Besides, at dynamic loading, the fracture surface analysis of the treated composites showed good attachment between RH and LLDPE. -
PublicationInfluence of filler surface modification on static and dynamic mechanical responses of rice husk reinforced linear low-density polyethylene composites( 2021)
;B. Jeż ;M. Nabiałek ;Hazizan Md AkilFiller surface modification has become an essential approach to improve the compatibility problem between natural fillers and polymer matrices. However, there is limited work that concerns on this particular effect under dynamic loading conditions. Therefore, in this study, both untreated and treated low linear density polyethylene/rice husk composites were tested under static (0.001 s –1, 0.01 s –1 and 0.1 s –1) and dynamic loading rates (650 s –1, 900 s –1 and 1100 s –1) using universal testing machine and split Hopkinson pressure bar equipment, respectively. Rice husk filler was modified using silane coupling agents at four different concentrations (1, 3, 5 and 7% weight percentage of silane) at room temperature. This surface modification was experimentally proven by Fourier transform infrared and Field emission scanning electron microscopy. Results show that strength properties, stiffness properties and yield behaviour of treated composites were higher than untreated composites. Among the treated composites, the 5% silane weight percentage composite shows the optimum mechanical properties. Besides, the rate of sensitivity of both untreated and treated composites also shows great dependency on strain rate sensitivity with increasing strain rate. On the other hand, the thermal activation volume shows contrary trend. For fracture surface analysis, the results show that the treated LLDPE/RH composites experienced less permanent deformation as compared to untreated LLDPE/RH composites. Besides, at dynamic loading, the fracture surface analysis of the treated composites showed good attachment between RH and LLDPE. -
PublicationInsight on the structural aspect of ENR-50/TiO2 hybrid in KOH/C3H8O medium revealed by NMR spectroscopy( 2020)
;Omar S. Dahham ;Mohamad Abu Bakar ;Abdulkader M. AlakrachAwad A. Al-rashdiThe ring-opening reactions (ROR) of epoxide groups in epoxidized natural rubber/titania (ENR-50/TiO2) hybrid in potassium hydroxide/isopropanol medium were examined using NMR spectroscopy and supported by the FTIR technique. The thermal behaviour of the hybrid was also studied using TG/DTG and DSC analyses. The 1H NMR results suggested that 16.82% of ROR occurred in the hybrid, while the 13C NMR results exhibited five new peaks at δ 19.5, 71.0, 73.7, 91.7 and 94.4 ppm in the hybrid. 2D NMR, such as HMQC, HMBC and COSY techniques, further scrutinized these assignments. The FTIR spectrum exhibited Ti-O-C characteristics via the peak at 1028 cm−1. The TG/DTG results showed four steps of thermal degradation at 44–148, 219–309, 331–489 and 629–810 °C due to the existence of Ti moieties along with a polymer chain mixture (intact and ring-opened epoxide groups) of ENR-50, which in turn led to an increase in the Tg value of the hybrid to 27 °C compared to that of purified ENR-50 at −17.72 °C. -
PublicationPhotocatalytic degradation of sugarcane vinasse using ZnO photocatalyst: operating parameters, kinetic studies, phytotoxicity assessments, and reusability( 2021)Kim-Mun EngPhotocatalytic degradation performance is highly related to optimized operating parameters such as initial concentration, pH value, and catalyst dosage. In this study, the impact of various parameters on the photocatalytic degradation of anaerobi‑ cally digested vinasse (AnVE) has been determined through decolourization and chemical oxygen demand (COD) reduction efciency using zinc oxide (ZnO) photocatalyst. In this context, the application of photocatalytic degradation in treating sugarcane vinasse using ZnO is yet to be explored. The COD reduction efciency and decolourization achieved 83.40% and 99.29%, respectively, under the conditions of 250 mg/L initial COD concentration, pH 10, and 2.0 g/L catalyst dosage. The phytotoxicity assessment was also conducted to determine the toxicity of AnVE before and after treatment using mung bean (Vigna radiata). The reduction of root length and the weight of mung bean indicated that the sugarcane vinasse contains enormous amounts of organic substances that afect the plant's growth. The toxicity reduction in the AnVE solution can be proved by UV–Vis absorption spectra. Furthermore, the catalyst recovery achieved 93% in the reusability test. However, the COD reduction efciency and decolourization were reduced every cycle. It was due to the depletion of the active sites in the catalyst with the adsorption of organic molecules. Thus, it can be concluded that the photocatalytic degradation in the treatment of AnVE was efective in organic degradation, decolorization, toxicity reduction and can be reused after the recovery process.
-
PublicationProcessing, tensile and morphological characteristics of polylactic acid/chitosan biocomposites prepared by melt compounding technique( 2020)
;N. H. I. Kamaludin ;H. Ismail ;A. RusliA. A. N. GunnyBiodegradable polymers of polylactic acid (PLA) and chitosan (Cs) has a great potential as alternative candidates to replace conventional synthetic plastic apart to reduce the plastic waste pollution due to the unique properties of superior mechanical strength, feasible processability and rapid degradation. In this work, PLA/Cs biocomposites were prepared via melt compounding and compression moulding techniques in the absence of any plasticizer and additive. The effect of chitosan loading (2.5, 5, 7.5, 10 php) on processing, tensile and morphological characteristics of PLA/Cs were evaluated using internal mixer, universal testing machine and field emission scanning electron microscopy (FESEM), respectively. Processing characteristic indicates PLA/Cs biocomposites demonstrated higher processing torque in comparison to neat PLA due to the increase in melt viscosity and decrease in chain mobility of the polymeric materials. Tensile test results revealed that the maximum strength (54.60 ± 0.51 MPa) and tensile elastic modulus (2.67 ± 0.01 GPa) was attained by PLA/2.5Cs biocomposite. In fact, the addition of chitosan content up to 10 php results in significant decreased in tensile strength and elongation at break of 23.38 ± 0.37 MPa and 0.96 ± 0.04 %, respectively. This is supported by the electron micrograph observation of the PLA/2.5Cs tensile fractured surfaces that exhibits uniform dispersion and good interfacial adhesion between chitosan and PLA matrix which signifies higher tensile properties. However, more agglomeration and poor filler-matrix interaction was observed with further addition of chitosan content of above 7.5 php which implies deterioration in tensile properties. The results suggest that the incorporation of low chitosan loading improve the processing, tensile and polymer compatibility in PLA/Cs biocomposites. -
PublicationThermal properties of nanocellulose‐reinforced composites: a review( 2019)
;P. G. GanNanocellulose has received increasing attention in science and industry in recent years as a nanoscale material for the reinforcement of polymer matrix composites due to its superior mechanical properties, renewability, and biodegradability. New nanocellulose sources, modifications, and treatments are under development to reduce the high energy required during production and to create a more suitable industrial-scale production process. Thus, this paper reviews plant-based nanocellulose composites and their properties, with a focus on their thermal-related characteristics. The purpose of this review is to establish for readers the impact of the incorporation of nanocellulose on the thermal and dynamic mechanical properties of nanocellulose composites. Understanding of the thermal properties is important for researchers to assess the suitability of the nanocomposites for a variety of applications in response to new and evolving societal requirements. -
PublicationMechanical and dielectric properties of hybrid carbon nanotubes-woven glass fibre reinforced epoxy laminated composites via the electrospray deposition method( 2021)
;Muhammad Razlan Zakaria ;Nur Aishahatul Syafiqa Mohammad Khairuddin ;Hazizan Md Akil ;Muhammad Bisyrul Hafi OthmanHerein, the effects of multi-walled carbon nanotubes (CNTs) on the mechanical and dielectric performance of hybrid carbon nanotube-woven glass fiber (GF) reinforced epoxy laminated composited are investigated. CNTs are deposited on woven GF surface using an electrospray deposition method which is rarely reported in the past. The woven GF deposited with CNT and without deposited with CNT are used to produce epoxy laminated composites using a vacuum assisted resin transfer moulding. The tensile, flexural, dielectric constant and dielectric loss properties of the epoxy laminated composites were then characterized. The results confirm that the mechanical and dielectric properties of the woven glass fiber reinforced epoxy laminated composited increases with the addition of CNTs. Field emission scanning electron microscope is used to examine the post damage analysis for all tested specimens. Based on this finding, it can be prominently identified some new and significant information of interest to researchers and industrialists working on GF based products -
PublicationInsights into modified sequencing batch reactor for the treatment of sugarcane vinasse: role of recirculation process( 2022-12-01)Ng H.H.The application of the recirculation process in the biological wastewater treatment process was considered as an effective approach in promoting biomass retention and mixing intensity, enhancing the performance of treating wastewater. In this study, a recirculated sequencing batch reactor (R-SBR) was developed in the treatment of anaerobically digested vinasse. The comparative study of the conventional sequencing batch reactor (without recirculation process) and R-SBR was determined through the treatment performances and kinetic studies. The chemical oxygen demand and ammonium reduction of R-SBR (52.5 ± 8.0% and 31.7 ± 7.9%) were higher than the conventional sequencing batch reactor (31.8 ± 4.3% and 17.3 ± 5.3%) at the feed flow rate of 1.0 L/day. This result revealed that the enhancement of the mass transfer between activated sludge and substrate could improve the biodegradation of the R-SBR. Moreover, the effect of feed flow rate as a significant factor to achieve effective biodegradation was determined in the R-SBR system. The maximum chemical oxygen demand reduction (63.0%) and ammonium reduction (41.3%) of R-SBR were achieved at the lowest feed flow rate (1.0 L/day) from 1.0 to 5.0 L/day. The chemical oxygen demand reduction of R-SBR could be explained by using pseudo-first-order kinetics with rate constant (k1) (0.0356 day−1). The kinetic study revealed that the R-SBR achieved the most effective performance at the lowest feed flow rate. Thus, the recirculation process as a feasible process improved the treatment performance in the R-SBR system at low feed flow rate.
-
PublicationPhotocatalytic Degradation of Sugarcane Vinasse Using ZnO Photocatalyst: Operating Parameters, Kinetic Studies, Phytotoxicity Assessments, and Reusability( 2022-02-01)Eng K.M.Abstract: Photocatalytic degradation performance is highly related to optimized operating parameters such as initial concentration, pH value, and catalyst dosage. In this study, the impact of various parameters on the photocatalytic degradation of anaerobically digested vinasse (AnVE) has been determined through decolourization and chemical oxygen demand (COD) reduction efficiency using zinc oxide (ZnO) photocatalyst. In this context, the application of photocatalytic degradation in treating sugarcane vinasse using ZnO is yet to be explored. The COD reduction efficiency and decolourization achieved 83.40% and 99.29%, respectively, under the conditions of 250 mg/L initial COD concentration, pH 10, and 2.0 g/L catalyst dosage. The phytotoxicity assessment was also conducted to determine the toxicity of AnVE before and after treatment using mung bean (Vigna radiata). The reduction of root length and the weight of mung bean indicated that the sugarcane vinasse contains enormous amounts of organic substances that affect the plant's growth. The toxicity reduction in the AnVE solution can be proved by UV–Vis absorption spectra. Furthermore, the catalyst recovery achieved 93% in the reusability test. However, the COD reduction efficiency and decolourization were reduced every cycle. It was due to the depletion of the active sites in the catalyst with the adsorption of organic molecules. Thus, it can be concluded that the photocatalytic degradation in the treatment of AnVE was effective in organic degradation, decolorization, toxicity reduction and can be reused after the recovery process. Graphical abstract: [Figure not available: see fulltext.].
-
PublicationInfluence of Glucose Supplementation on the Organic Removal and Biomass Growth in Anaerobically Digested Vinasse (AnVE) by Using Aerobic Sequencing Batch Reactor (SBR)( 2022-01-01)Deák G.This paper analyses the effect of glucose supplementation in the treatment of anaerobically digested vinasse (AnVE) through reduction performance and biomass growth by using aerobic SBR system. The result revealed that the COD and ammonium reduction with the addition of glucose supplementation (65.3 ± 6.0 and 30.0 ± 5.5%) was greater than the reactor without glucose supplementation (23.6 ± 10.8 and 18.7 ± 6.0%). This can be due to the additional glucose as the carbon source for microbe metabolism nutrients. The biomass growth in the reactor with glucose supplementation increased rapidly over time, while there was no obvious biomass growth shown in the reactor without the addition of glucose. It is because glucose supplementation increased biomass accumulation in biomass production. The increment of biomass in the reactor with glucose supplementation can be further explained by the F/M ratio and biomass yield. The F/M ratio reduced when the biomass growth increased. Thus, the biomass yield started to decrease after the operation in week 2, until it reached maximum biomass growth. Therefore, it concluded that the addition of glucose supplementation in the treatment of AnVE showed a positive effect on the removal performance and biomass growth by using aerobic SBR.