Abdul Haqi Ibrahim
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Abdul Haqi Ibrahim
Official Name
Ibrahim, Abdul Haqi
Alternative Name
Ibrahim, A H
Main Affiliation
Water Research and Environmental Sustainable Growth (WAREG)
Scopus Author ID
36617479700

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  • Publication
    Hybrid system of photocatalytic fuel cell and Fenton process for electricity generation and degradation of Reactive Black 5
    ( 2017-01-01)
    Noradiba Nordin
    ;
    Ho Li Ngee
    ;
    Ong Soon An
    ;
    Abdul Haqi Ibrahim
    ;
    Wong Yee Shian
    ;
    Lee Sin Li
    ;
    Oon Yoong Sin
    ;
    Oon Yoong Ling
    A novel hybrid system composed of a photocatalytic fuel cell (PFC) and Fenton reactor was developed with the aim to degrade the azo dye Reactive Black 5 (RB5) and generate electricity. Compared to previously established system of bioelectro-Fenton system, microbial fuel cell (MFC) system has significant challenge in the development and operation system. Therefore, PFC is used instead of MFC to generate electrons for the Fenton system. The effect of azo dye (RB5) on each PFC and Fenton reactor was investigated. The experimental results showed that maximum power output was achieved in the absence of dye in the Fenton reactor of this hybrid system. Furthermore, higher degradation efficiency of RB5 could also be observed in the PFC reactor in this hybrid system.
  • Publication
    Influence of leachate matrix on oxidation performance of ozonation and aops
    ( 2022-12-15)
    Kow S.H.
    ;
    Fahmi Muhammad Ridwan
    ;
    Che Zulzikrami Azner Abidin
    ;
    Najihah Abdul Rashid
    ;
    Naimah Ibrahim
    ;
    Abdul Haqi Ibrahim
    ;
    Ong Soon An
    ;
    Wikurendra E.A.
    ;
    Handayani D.
    Landfill leachate is a critical environmental issue that should be adequately treated to prevent it from spreading to the environment. This study explored the influence of raw leachate matrix and treated leachate matrix on O3, O3/H2O2, and O3/PS performance. O3 and AOPs were conducted in a laboratory-scale batch reactor. The findings showed the degradation of p-cresol, COD, and humic substances was much slower in treated leachate matrix than in raw leachate matrix. However, color was found easier to remove in treated leachate. The results revealed a synergic effect between molecular O3 and dissolved organic matter in the raw leachate as the O3 performance was enhanced in the presence of raw leachate matrix, except for color removal. The highest degradation of more than 90% was achieved in O3 /H2 O2 to remove COD, p-cresol, and humic substances, although it is the most affected by the leachate matrix. This study provides vital insight into the notable performance of O3 /PS in color removal regardless of the influence of leachate matrix, suggesting that the sulfate radical-induced oxidation outperformed O3 and O3 /H2 O2 in reducing nitrogen-containing compounds.
      1  40
  • Publication
    Effect of ozonation on COD fractionation of wastewater from poultry processing industry
    ( 2020-06-10)
    Fahmi Muhammad Ridwan
    ;
    Che Zulzikrami Azner Abidin
    ;
    Abdul Haqi Ibrahim
    ;
    Kan S.L.E.
    ;
    Loong J.E.
    ;
    Roshasmawi Abdul Wahab
    The objectives of this study were to evaluate the effect of ozonation on the solubility and biodegradability of wastewater from poultry processing industry. In addition, the wastewater also characterized based on the COD fractionation. The wastewater sample used was collected from Advance Chicken Processing (M) Sdn. Bhd., Perlis, Malaysia. Ozonation process was carried out in a semi-batch glass reactor which has a 2 L volume. The COD fractionation of poultry wastewater indicated that non-biodegradable COD is predominant compare to other fractions. However, the wastewater is containing higher percentage biodegradable COD comprehensively. It is expected that ozonation treatment would transform both particulate and soluble non-biodegradable COD towards biodegradable constituent that easily remove by biodegradation. The removal of COD was significant at ozonation duration up to 5 min. However, COD removal efficiency was only increased slightly with the increased of the ozonation duration after 5 min. This may be due to the fact that ozonation for long time would possibly producing constituent that inhibit ozone dissociation.
      3  23
  • Publication
    Iron removal efficiency in synthetic Acid Mine Drainage (AMD) treatment using peat soil
    ( 2022-01-01)
    Mohd Syazwan Mohd Halim
    ;
    Abdul Haqi Ibrahim
    ;
    Tengku Nuraiti Tengku Izhar
    ;
    Suhaina Ismail
    ;
    Ku Esyra Hani Ku Ishak
    ;
    Moncea Andreea
    Acid mine drainage (AMD) formation is due to the sulfide minerals reaction either chemically or biologically when exposed to atmospheric conditions. The AMD formation often occurred in the region involved with anthropogenic activities, including mining, agricultural plantation, urban development and logging. Treatment of AMD is a challenging part of most mining operations around the world. Selection of method treatment is crucial depending on the area’s geological, mineralogical, topography and AMD characteristic. There are two types of method treatment; active and passive treatment method. In this study, passive treatment method was adopted; which is successive alkalinity producing system (SAPS). The study aims to analyze effect of variable parameters on iron (Fe) concentration and propose optimum operating condition for AMD treatment. Peat soil and limestone aggregate was used as treatment media in treatment tank. Synthetic AMD was formulated using sulphuric acid (H2SO4) and iron sulfate (FeSO4) to represent actual AMD. Once the synthetic AMD was introduced, water samples were collected and analyzed using UV–Vis test after 6 to 48 h’ retention time. Based on the analysis, the proposed methodology has successfully reduced more than 85% iron content only after 6 h of retention time. The maximum Fe removal percentage recorded was 95%, using the higher peat soil depth configuration. The statistical analysis results show that the optimum operating condition for SAPS with high Fe removal is using high peat soil depth. Experiments with higher peat soil depth provide satisfactory results in treating the high initial Fe concentration regardless of the retention time for the AMD treatment.
      4  2
  • Publication
    Assessment of heavy metal pollution in sediments and in Phragmites Australis from Argeş River
    ( 2022-01-01)
    Marcu, Ecaterina
    ;
    Deák, György
    ;
    Ciobotaru Irina-Elena
    ;
    Burlacu, Iasmina-Florina
    ;
    Tociu, Carmen
    ;
    Abdul Haqi Ibrahim
    There are several species of macrophyte which have the ability to absorb heavy metals from water and, therefore, are used to retain and remove them. In the present paper, the concentrations of heavy metals (Zn, Cu, Ni, Cd, Pb and Cr) were investigated in sediment samples from the Argeș River and their potential transfer from sediments to Phragmites australis was evaluated. The extent of sediment pollution with heavy metals and the potential risk to the aquatic environment were estimated based on the following indexes: bioaccumulation, geoaccumulation, ecological risk, translocation, contamination, etc. The metals concentrations in the analyzed sediments were, generally, below the limits of national legislation.
      8
  • Publication
    Peat soil for synthetic acid mine drainage treatment: Characteristic study
    ( 2020-12-29)
    Halim, Mohd Syazwan Mohd
    ;
    Abdul Haqi Ibrahim
    ;
    Tengku Nuraiti Tengku Izhar
    ;
    Ismail S.
    ;
    Mohamed Jaafar Z.F.
    Acid Mine Drainage (AMD) is an untreated outflow of acidic water from metal or coal mines. Improper treatment of the harmful effluent causes major environmental concern and remains as an unsolved problem for mining operators worldwide. The untreated AMD contains high concentration of several heavy metals despite low pH level. Iron (Fe) is most dominant element of heavy metal spotted in the AMD water and must be filtered and treated before being released to open water bodies. Current practises by the industries adopted two categories of AMD treatment methods, namely active and passive treatments. Passive treatment method was adopted into this study by using successive alkalinity producing system (SAPS) to reduce Fe concentration in the AMD. Strict regulations by mine operators to acquire on-site AMD, led to use of synthetic AMD. Peat soil was introduced as organic substrate treatment media, as compared to common materials used such as mushroom spent, wood shaving and animal manure. In this research the peat soil was characterized and its effectiveness to filter the Fe content was assessed using laboratory scale studies. Prior to the test, the natural peat soil was analyzed via Scanning Electron Microscopy (SEM) analysis, Energy Dispersive X-Ray (EDX) analysis and carbon-hydrogen-nitrogen-sulphur (CHNS) element analysis. After going through laboratory tests, the peat soil residues were assessed through SEM-EDX analysis to determine the trapped Fe content. The natural peat soil does not contain any Fe substance. However, the analyzed peat soil residues showed that, approximately one to four percent of the Fe were found in the peat soil residues. The use of the peat soil for the AMD treatment in SAPS method is applicable and can be used as alternative organic substrate for treatment media.
      4  22
  • Publication
    Reactive Green 19 degradation using O3/S2 O8(2-) process: Intermediates and proposed degradation pathway
    ( 2022-01-01)
    Mohd Razali N.A.
    ;
    Che Zulzikrami Azner Abidin
    ;
    Ong Soon An
    ;
    Fahmi Muhammad Ridwan
    ;
    Abdul Haqi Ibrahim
    ;
    Siti Nasuha Sabri
    ;
    Kow Su Huan
    ;
    Safya Abdul Malik
    The massive drawbacks of conventional wastewater treatment have led to a demand investigation about new advanced wastewater treatment technology. The issue can be addressed via advanced oxidation processes (AOPs) as witnessed recently. Therefore, the objective of this study was to investigate the performance of ozone/persulfate ((Formula presented.)) process to assess its use as potential degradation of diazo dye which is Reactive Green 19 (RG19). In this work, efficiency, color, and COD removal were investigated over a range of initial pH, persulfate concentration and initial concentration of RG19. The amount of sodium persulfate ((Formula presented.)) was varied at different levels (20–100 mM) relative to precursor radical to assess the optimum usage of persulfate concentration for RG19 degradation. Evidence that RG19 could degrade efficiently had occurred at 100 mg/L, initial pH 9, 60 mM persulfate concentration was identified by FTIR and GC/MS analysis. The results revealed that RG19 could achieve complete decolorization easily as compared to mineralization. In addition, RG19 degradation pathway gave the best representation of level degradation. The GC/MS and FTIR results exhibited the proposed RG19 degradation pathway that involved the characteristic of sulfonic group, (Formula presented.) accompanied with (Formula presented.) became as an indicator of their structure broken down one by one. The degradation products such as oxalic acid, formic acids and others were analyzed and finally converted to carbon dioxide and water. The diazo dye structure itself aided with (Formula presented.) has its superior characteristic as an aid for the efficient degradation process.
      1
  • Publication
    Electro-oxidation as Tertiary Treatment Techniques for Removal of Palm Oil Mill Effluent
    ( 2020-07-09)
    Che Zulzikrami Azner Abidin
    ;
    Fahmi Muhammad Ridwan
    ;
    Abdul Haqi Ibrahim
    ;
    Nazerry Rosmady Rahmat
    ;
    Farah Mohamed Hussein N.
    ;
    Razi Ahmad
    The production of palm oil, though, results in the generation of huge quantities of polluted wastewater normally referred as palm oil mill effluent (POME). It gives adverse impacts to the environment, particularly if it is not properly treated. POME are known to have various types of liquids, residual oil and suspended solid as it has very high strength waste in its untreated form. Although conventional biological processes are normally efficient for the degradation of pollutants occurring in wastewater, most of these compounds are not effectively removed. As a result, further treatment is needed to meet more stringent discharge standards of Department of Environment (DOE), Malaysia. This research focused on treatment of POME by using electro-oxidation process (EO). It was done to identify the performance of EO process for colour, chemical oxygen demand (COD), suspended solids (SS), and Ammoniacal-nitrogen NH3-N) removal as well as the relative effects of different operational parameters such as pH, type of electrodes and contact time. The pH was varied between 3 and 11, using Ferum (Fe) and Aluminium (Al) electrode, and contact time from 0 to 120 min. The most suitable pH, contact time and type of electrode were pH 3, 120 min and Aluminium electrode, respectively. Therefore, EO process at specified level can be used as an efficient and effective post-treatment technology to meet the standard regulatory requirements.
      5  32
  • Publication
    Study of O3/S2O82- Advanced Oxidation Processes (AOPs) for removal of dye industrial effluents
    ( 2019)
    Che Zulzikrami Azner Abidin
    ;
    Fahmi Muhammad Ridwan
    ;
    Ong Soon An
    ;
    Abdul Haqi Ibrahim
    ;
    Sabri Siti Nasuha
    ;
    Razali Nur Aqilah
    This research was carried out to study the efficiency of O3/S2O82- system in removal of Reactive Red 120 (RR120) dye sample. Different operating parameter such as pH, initial dye concentration and persulfate dosage were studied to evaluate the performance on removing colour and COD. The removal of colour and COD achieved higher efficiency at pH 7, 100 mg/L of initial dye concentration and persulfate dosage of 5 g S2O82-/1 g RR120. O3/S2O82- with the most effective conditions experienced effective decolourization and degradation of organic pollutants than O3 only. Furthermore, it achieved faster breakdown of azo bond and aromatic groups than O3 after treatment as observed with UV-Vis absorption spectra. The FT-IR analysis obtained new absorption peak that represents alkenes after 20 min of O3 treatment whereas mostly of the absorption bands of O3/S2O82- flattened.
      1  6
  • Publication
    Elemental characterization of Airborne Particulate Matter (APM) in Parit Buntar and Nibong Tebal
    ( 2006)
    Abdul Haqi Ibrahim
    ;
    Nor Azam Ramli
    ;
    Mohd Talib Latif
    Study had being conducted to investigate the chemical properties of Airborne Particulate Matter (APM) which present in the ambient air of Parit Buntar Town and Nibong Tebal Town. These towns are located in Northen Perak and in southern part of Seberai Perai, Penang respectively. Non-reactive carbon tape was attached onto an aluminium stub to collect APM. The stub was exposed to the air for 24 hours to collect APM which will be deposited naturally due to the gravity action. Stub containing APM was analyzed by Energy Dispersive X-ray (EOX) to obtain elemental components. Results obtained from the analysis have shown that carbon (organic carbon or! and elemental carbon), 0 , AI, Si and other species such as Ca, K, Fe and Mg are the common elements present in the A PM.
      7  27