Now showing 1 - 9 of 9
  • Publication
    The effects of various concentrations of NaOH on the Inter-Particle Gelation of a Fly Ash Geopolymer Aggregate
    ( 2021) ; ; ; ;
    Wojciech Sochacki
    ;
    Rafiza Abdul Razak
    ;
    Katarzyna BÅ‚och
    ;
    Hamzah Fansuri
    Aggregates can be categorized into natural and artificial aggregates. Preserving natural resources is crucial to ensuring the constant supply of natural aggregates. In order to preserve these natural resources, the production of artificial aggregates is beginning to gain the attention of researchers worldwide. One of the methods involves using geopolymer technology. On this basis, this current research focuses on the inter-particle effect on the properties of fly ash geopolymer aggregates with different molarities of sodium hydroxide (NaOH). The effects of synthesis parameters (6, 8, 10, 12, and 14 M) on the mechanical and microstructural properties of the fly ash geopolymer aggregate were studied. The fly ash geopolymer aggregate was palletized manually by using a hand to form a sphere-shaped aggregate where the ratio of NaOH/Na2SiO3 used was constant at 2.5. The results indicated that the NaOH molarity has a significant effect on the impact strength of a fly ash geopolymer aggregate. The highest aggregate impact value (AIV) was obtained for samples with 6 M NaOH molarity (26.95%), indicating the lowest strength among other molarities studied and the lowest density of 2150 kg/m3. The low concentration of sodium hydroxide in the alkali activator solution resulted in the dissolution of fly ash being limited; thus, the inter-particle volume cannot be fully filled by the precipitated gels.
  • Publication
    The Effects of Various Concentrations of NaOH on the Inter-Particle Gelation of a Fly Ash Geopolymer Aggregate
    ( 2021) ; ; ; ;
    Wojciech Sochacki
    ;
    Katarzyna BÅ‚och
    ;
    Hamzah Fansuri
    ;
    Rafiza Abdul Razak
    Aggregates can be categorized into natural and artificial aggregates. Preserving natural resources is crucial to ensuring the constant supply of natural aggregates. In order to preserve these natural resources, the production of artificial aggregates is beginning to gain the attention of researchers worldwide. One of the methods involves using geopolymer technology. On this basis, this current research focuses on the inter-particle effect on the properties of fly ash geopolymer aggregates with different molarities of sodium hydroxide (NaOH). The effects of synthesis parameters (6, 8, 10, 12, and 14 M) on the mechanical and microstructural properties of the fly ash geopolymer aggregate were studied. The fly ash geopolymer aggregate was palletized manually by using a hand to form a sphere-shaped aggregate where the ratio of NaOH/Na2SiO3 used was constant at 2.5. The results indicated that the NaOH molarity has a significant effect on the impact strength of a fly ash geopolymer aggregate. The highest aggregate impact value (AIV) was obtained for samples with 6 M NaOH molarity (26.95%), indicating the lowest strength among other molarities studied and the lowest density of 2150 kg/m3. The low concentration of sodium hydroxide in the alkali activator solution resulted in the dissolution of fly ash being limited; thus, the inter-particle volume cannot be fully filled by the precipitated gels.
  • Publication
    Bahan geopolimer : Pemprosesan, Pencirian dan Aplikasi
    Buku Bahan Geopolimer: Pemprosesan, Pencirian dan Aplikasi adalah sebuah buku yang membincangkan beberapa aspek penting mengenai bahan geopolimer seperti pemprosesan, perincian, aplikasi dan sifat bahan geopolimer dalam teknologi konkrit. Buku ini juga menerangkan secara terperinci tentang bahan geopolimer dari aspek teori, pemprosesan, pencirian dan aplikasi yang sesuai dijadikan sebagai bahan rujukan dan panduan kepada pelajar, penyelidik dan pengamal industri.
  • Publication
    Mechanical performance, microstructure, and porosity evolution of fly ash geopolymer after ten years of curing age
    ( 2023)
    Ikmal Hakem A. Aziz
    ;
    ; ; ; ;
    Jitrin Chaiprapa
    ;
    Catleya Rojviriya
    ;
    Petrica Vizureanu
    ;
    Andrei Victor Sandu
    ;
    ; ;
    This paper elucidates the mechanical performance, microstructure, and porosity evolution of fly ash geopolymer after 10 years of curing age. Given their wide range of applications, understanding the microstructure of geopolymers is critical for their long-term use. The outcome of fly ash geopolymer on mechanical performance and microstructural characteristics was compared between 28 days of curing (FA28D) and after 10 years of curing age (FA10Y) at similar mixing designs. The results of this work reveal that the FA10Y has a beneficial effect on strength development and denser microstructure compared to FA28D. The total porosity of FA10Y was also lower than FA28D due to the anorthite formation resulting in the compacted matrix. After 10 years of curing age, the 3D pore distribution showed a considerable decrease in the range of 5–30 µm with the formation of isolated and intergranular holes.
  • Publication
    Artificial lightweight aggregates made from pozzolanic material: A review on the method, physical and mechanical properties, thermal and microstructure
    ( 2022)
    Dickson Ling Chuan Hao
    ;
    ;
    Marwan Kheimi
    ;
    ; ;
    Dumitru Doru Burduhos Nergis
    ;
    Hamzah Fansuri
    ;
    Ratna Ediati
    ;
    Rosnita Mohamed
    ;
    As the demand for nonrenewable natural resources, such as aggregate, is increasing worldwide, new production of artificial aggregate should be developed. Artificial lightweight aggregate can bring advantages to the construction field due to its lower density, thus reducing the dead load applied to the structural elements. In addition, application of artificial lightweight aggregate in lightweight concrete will produce lower thermal conductivity. However, the production of artificial lightweight aggregate is still limited. Production of artificial lightweight aggregate incorporating waste materials or pozzolanic materials is advantageous and beneficial in terms of being environmentally friendly, as well as lowering carbon dioxide emissions. Moreover, additives, such as geopolymer, have been introduced as one of the alternative construction materials that have been proven to have excellent properties. Thus, this paper will review the production of artificial lightweight aggregate through various methods, including sintering, cold bonding, and autoclaving. The significant properties of artificial lightweight aggregate, including physical and mechanical properties, such as water absorption, crushing strength, and impact value, are reviewed. The properties of concrete, including thermal properties, that utilized artificial lightweight aggregate were also briefly reviewed to highlight the advantages of artificial lightweight aggregate.
  • Publication
    Properties and morphology of fly ash based Alkali Activated Material (AAM) paste under steam curing condition
    ( 2022) ;
    Sh. Nur Syamimi Sy. Izman
    ;
    ; ; ;
    Rosnita Mohamed
    This paper details the properties, microstructures, and morphologies of the fly ash-based alkali-activated material (AAM), also known as geopolymers, under various steam curing temperatures. The steam curing temperature result in subsequent high strengths relative to average curing temperatures. However, detailed studies involving the use of steam curing for AAM remain scarce. The AAM paste was prepared by mixing fly ash with an alkali activator consisting of sodium silicate (Na2SiO3) and sodium hydroxide (NaOH). The sample was steam cured at 50°C, 60°C, 70°C, and 80°C, and the fresh paste was tested for its setting time. The sample also prepared for compressive strength, density, and water absorption testings. It was observed that the fastest time for the fly ash geopolymer to start hardening was at 80°C at only 10 minutes due to the elevated temperature quickening the hydration of the paste. The compressive strength of the AAM increased with increasing curing time from 3 days to 28 days. The AAM’s highest compressive strength was 61 MPa when the sample was steam cured at 50°C for 28 days. The density of AAM was determined to be ~2122 2187 kg/m3 , while its water absorption was ~6.72-8.82%. The phase analyses showed the presence of quartz, srebrodolskite, fayalite, and hematite, which indirectly confirms Fe and Ca’s role in the hydration of AAM. The morphology of AAM steam-cured at 50°C showed small amounts of unreacted fly ash and a denser matrix, which resulted in high compressive strength.
  • Publication
    Article the effects of various concentrations of naoh on the inter-particle gelation of a fly ash geopolymer aggregate
    Aggregates can be categorized into natural and artificial aggregates. Preserving natural resources is crucial to ensuring the constant supply of natural aggregates. In order to preserve these natural resources, the production of artificial aggregates is beginning to gain the attention of researchers worldwide. One of the methods involves using geopolymer technology. On this basis, this current research focuses on the inter-particle effect on the properties of fly ash geopolymer aggregates with different molarities of sodium hydroxide (NaOH). The effects of synthesis parameters (6, 8, 10, 12, and 14 M) on the mechanical and microstructural properties of the fly ash geopolymer aggregate were studied. The fly ash geopolymer aggregate was palletized manually by using a hand to form a sphere-shaped aggregate where the ratio of NaOH/Na2SiO3 used was constant at 2.5. The results indicated that the NaOH molarity has a significant effect on the impact strength of a fly ash geopolymer aggregate. The highest aggregate impact value (AIV) was obtained for samples with 6 M NaOH molarity (26.95%), indicating the lowest strength among other molarities studied and the lowest density of 2150 kg/m3 . The low concentration of sodium hydroxide in the alkali activator solution resulted in the dissolution of fly ash being limited; thus, the inter-particle volume cannot be fully filled by the precipitated gels.
  • Publication
    Geopolymer coating paste on concrete for photocatalytic performance
    Construction materials mainly used Portland cement as raw materials mainly caused global warming effect around the world. This article report a review on a research work carried out on the use of geopolymer coating on the concrete surface with catalyst for a good adsorption and efficiency via photocatalytic activity using sunlight. The geopolymer paste deposited by coating on the concrete or other building construction surface. The geopolymer paste were prepared by mixing aluminosilicates material with alkaline activator added with catalyst materials such as titanium dioxide and zinc oxide. The performance of geopolymer coating in removal of dyes reported comparable with other materials. Photocatalytic activity performance evaluate by adsorption of dyes onto geopolymer.
  • Publication
    Performance of Sintered Pozzolanic Artificial Aggregates as Coarse Aggregate Replacement in Concrete
    The abundant increase in waste quantities year by year and the depletion of natural resources worldwide are the major concerns among researchers. Recycling and reusing various types of natural or by-product material waste from industry become highlighted in the recent study. The growing demand for concrete and the production of artificial aggregate become crucial in the construction industry. Artificial aggregate can be produced either by sintering, auto-clave or cold bonding method. Although auto-clave and cold bonding methods can minimize energy consumption, the selection of the sintering method always leads to high quality and better properties of artificial aggregates produced. The use of sintering methods to produce artificial aggregate made from pozzolanic material focuses on the use of volcanic ash as raw material activated by geopolymerization process to produce artificial lightweight aggregate-based geopolymer will be summarized in this chapter. This chapter discusses the result of the physical and mechanical properties of artificial lightweight aggregate or known as sintered geopolymer volcanic ash artificial lightweight aggregate (SGVA). The interfacial transition zone (ITZ) of sintered geopolymer volcanic ash artificial lightweight aggregate (SGVA) is presented. The performance of sintered geopolymer volcanic ash artificial lightweight aggregate (SGVA) in concrete is also discussed.