Masitah Hasan
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Preferred name
Masitah Hasan
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Masitah, Hasan
Alternative Name
Hasan, Masitah
Masitah, H.
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Scopus Author ID
57217411844
Researcher ID
HLU-8488-2023

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  • Publication
    Comparative Study of Sulfur Dioxide Removal Using Mesoporous Silica KCC-1 and SBA-15
    ( 2022-01-01)
    Muhammad Adli Hanif
    ;
    Naimah Ibrahim
    ;
    Khairuddin Md Isa
    ;
    Masitah Hasan
    ;
    Tuan Abdullah T.A.
    ;
    Jalil A.A.
    Sulfur dioxide (SO2) emitted into the atmosphere by fossil fuel burning in the industries posed significant negative effects on humans and the environment. SO2 removal performance of two mesoporous silica: KCC-1 and SBA-15, are compared through breakthrough experiments on a lab-scale fixed bed reactor. The mesoporous silicas were characterized via nitrogen (N2) adsorption-desorption isotherm and field emission scanning electron microscopy (FESEM). KCC-1 demonstrates characteristics of capillary condensation and non-uniform slit-shaped pores while SBA-15 displays characteristic of a narrow range of mesopores with minimal network effects. Surface area, total pore volume and average pore diameter of KCC-1 are significantly greater than SBA-15 due to the presence of dendrimeric fibrous morphology. Under tested conditions, SO2 adsorption capacities of KCC-1 and SBA-15 are 614.01 mg/g and 274.64 mg/g, respectively. Superior performance by KCC-1 can be attributed to better accessibility of SO2 towards the active sites due to higher surface area provided by the dendrimer fibers.
      1
  • Publication
    Optimization of copper adsorption from synthetic wastewater by oil palm-based adsorbent using Central Composite Design
    ( 2020-06-10)
    Wong H.W.
    ;
    Naimah Ibrahim
    ;
    Muhammad Adli Hanif
    ;
    Norazian Mohamed Noor
    ;
    Sara Yasina Yusuf
    ;
    Masitah Hasan
    Oil palm empty fruit bunch (EFB) was chemically activated by phosphoric acid and heat treatment to produce porous activated carbon (AC) for adsorption of copper ions from synthetic wastewater using static batch test. Copper adsorption process was optimized using Response Surface Method (RSM) by varying four operating parameters i.e. pH (A), initial concentration (B), adsorbent dosage (C) and contact time (D) through a quadratic model developed based on Central Composite Design (CCD) approach. Within the tested parameter range, copper adsorption was found to be at optimum condition at pH 5, initial concentration of 200 mg/L, adsorbent dosage of 0.55 g per 200 mL copper solution and contact time of 2.5 hours, yielding 52.5% of copper removal. A good agreement was achieved by comparing the predicted model with experimental data (R2=0.9618). All four operating parameters tested are significant in affecting the adsorption process, with pH being the most significant with an F-value of 171.70. The interaction between pH and initial concentration (AB) has the most significant interacting effects (F-value of 18.30), while quadratic effects of pH (A2) and adsorbent dosage (C2) are most significant with F-values of 62.80 and 42.58 respectively.
      3  3
  • Publication
    Column-based removal of high concentration microplastics in synthetic wastewater using granular activated carbon
    ( 2023-01-01)
    Amirah Mohd Napi N.n.
    ;
    Naimah Ibrahim
    ;
    Adli Hanif M.
    ;
    Masitah Hasan
    ;
    Farrah Aini Dahalan
    ;
    Syafiuddin A.
    ;
    Boopathy R.
    Microplastic (MP) is an emerging contaminant of concern due to its abundance in the environment. Wastewater treatment plant (WWTP) can be considered as one of the main sources of microplastics in freshwater due to its inefficiency in the complete removal of small MPs. In this study, a column-based MP removal which could serve as a tertiary treatment in WWTPs is evaluated using granular activated carbon (GAC) as adsorbent/filter media, eliminating clogging problems commonly caused by powder form activated carbon (PAC). The GAC is characterized via N2 adsorption–desorption isotherm, field emission scanning electron microscopy, and contact angle measurement to determine the influence of its properties on MP removal efficiency. MPs (40–48 μm) removal up to 95.5% was observed with 0.2 g/L MP, which is the lowest concentration tested in this work, but still higher than commonly used MP concentration in other studies. The performance is reduced with further increase in MP concentration (up to 1.0 g/L), but increasing the GAC bed length from 7.5 to 17.5 cm could lead to better removal efficiencies. MP particles are immobilized by the GAC predominantly by filtration process by being entangled with small GAC particles/chips or stuck between the GAC particles. MPs are insignificantly removed by adsorption process through entrapment in GAC porous structure or attachment onto the GAC surface.
      1
  • Publication
    Performance of rubber seed shell adsorbents for removal of methylene blue dye in aqueous solution
    ( 2021-02-23)
    Thevdarshni Chanderan
    ;
    Masitah Hasan
    ;
    Zulfakar Mokhtar
    ;
    Naimah Ibrahim
    Regeneration of rubber seed shell (RSS) in producing an effective low-cost activated carbon (AC) through chemical activation using H3PO4. Adsorption of methylene blue (MB) by raw, AC1 (impregnation ratio 1:1) and AC2 (impregnation ratio 1:3) carbons were analyzed to discover its adsorption capacity. The effects of various experimental parameters: pH of solution, initial concentration, contact time and adsorbent dosage were analyzed. Characterization of adsorbents produced were performed using SEM, ash content, iodine number and BET. Overall performance of the adsorbents was investigated by employing the optimum values obtained in the batch adsorption studies. This study revealed that the carbon with higher impregnation ratio (AC2) has the highest removal efficiency of MB at 91.4%. Specific surface area, iodine adsorption number and ash content for AC2 are 317.6 m2/g, 676.9 mg/g and 2.6%, respectively. This study revealed the primacy of chemically activated carbons with higher impregnation ratio (AC2) for the removal of MB.
      1
  • Publication
    Adsorption of diclofenac sodium using low-cost activated carbon in a fixed-bed column
    ( 2022-12-15)
    Fadirah Fadzail
    ;
    Masitah Hasan
    ;
    Naimah Ibrahim
    ;
    Zulfakar Mokhtar
    ;
    Asih A.Y.P.
    ;
    Syafiuddin A.
    In recent years, the presence of pharmaceutical contaminants, such as diclofenac sodium (DCF) in water bodies and their potential influence on aquatic organisms gained much attention. As a result of high demand and usage by consumers, in addition to incomplete removal during wastewater treatment, pharmaceutical contaminants will end up on water surfaces. To mitigate this problem, the elimination of DCF by employing activated carbon derived from Dillenia Indica peels was evaluated. The adsorption of DCF was performed in a continuous process. The findings showed that the adsorption of DCF was favorable at a lower flow rate, greater bed height, and initial DCF concentration, with the highest removal percentage of 44.93%. To assess the characteristics of the breakthrough curve of DCF, the adsorption data were used to match three distinct adsorption models, namely, Boharts and Adam, Yoon-Nelson, and Thomas. The breakthrough results were well-fitted with these models, as the values of R2 for all models and parameters were higher than 0.88. Thus, it was concluded that the activated carbon from Dillenia Indica can effectively remove DCF from an aqueous solution.
      2  10
  • Publication
    Microplastics in facial cleanser: extraction, identification, potential toxicity, and continuous-flow removal using agricultural waste–based biochar
    ( 2023-05-01)
    Hanif M.A.
    ;
    Naimah Ibrahim
    ;
    Farrah Aini Dahalan
    ;
    Umi Fazara Md Ali
    ;
    Masitah Hasan
    ;
    Ayu Wazira Azhari
    ;
    Jalil A.A.
    Microplastic (MP) is an emerging contaminant of concern due to its ubiquitous quantity in the environment, small size, and potential toxicity due to strong affinity towards other contaminants. In this work, MP particles (5–300 μm) were extracted from a commercial facial cleanser and determined to be irregular polyethylene (PE) microbeads based on characterization with field emission scanning electron microscopy (FESEM) and Raman spectroscopy. The potential of extracted MP acting as toxic pollutants’ vector was analyzed via adsorption of methylene blue and methyl orange dye where significant dye uptake was observed. Synthetic wastewater containing the extracted MP was subjected to a continuous-flow column study using palm kernel shell and coconut shell biochar as the filter/adsorbent media. The prepared biochar was characterized via proximate and ultimate analysis, FESEM, contact angle measurement, atomic force microscopy (AFM), and Fourier transform infrared (FTIR) spectroscopy to investigate the role of the biochar properties in MP removal. MP removal performance was determined by measuring the turbidity and weighing the dry mass of particles remaining in the effluent following treatment. Promising results were obtained from the study with highest removal of MP (96.65%) attained through palm kernel shell biochar with particle size of 0.6–1.18 mm and continuous-flow column size of 20 mm. Graphical abstract: [Figure not available: see fulltext.].
      1
  • Publication
    Removal of naproxen using low-cost Dillenia Indica peels as an activated carbon
    ( 2022-01-01)
    Fadirah Fadzail
    ;
    Masitah Hasan
    ;
    Zulfakar Mokhtar
    ;
    Naimah Ibrahim
    A batch adsorption process of naproxen (NPX) using activated carbon derived from Dillenia Indica peel was performed at the laboratory scale. NPX was selected as an adsorbate due to its toxicity and large occurrence in water. The study was conducted to examine the ability of prepared activated carbon in adsorbing the NPX. The adsorption was conducted at various initial concentrations of NPX, contact time, adsorbent dosage, and pH. Results of batch adsorption showed that the maximum adsorption was reached at lower pH and adsorbent dosage of 0.4 g. 8 h is needed for the adsorption to reached equilibrium. Langmuir, Freundlich, Dubinin-Radushkevich and Temkin isotherm have been used to analyse the properties of the adsorption process. The data are best suited for the Langmuir and Temkin isotherm and the adsorption follows a pseudo-second order model for kinetic study. The results suggest that the adsorption behave as a monolayer and the process is controlled by chemisorption mechanism. The adsorption capacity of 10.76 mg/g concluded that the activated carbon prepared from Dillenia Indica peel is effective in removing NPX from the water.
      1  10
  • Publication
    Microplastics and nanoplastics: Recent literature studies and patents on their removal from aqueous environment
    ( 2022-03-01)
    Hanif M.A.
    ;
    Naimah Ibrahim
    ;
    Farrah Aini Dahalan
    ;
    Umi Fazara Md Ali
    ;
    Masitah Hasan
    ;
    Jalil A.A.
    The presence of microplastics (MP) and nanoplastics (NP) in the environment poses significant hazards towards microorganisms, humans, animals and plants. This paper is focused on recent literature studies and patents discussing the removal process of these plastic pollutants. Microplastics and nanoplastics can be quantified by counting, weighing, absorbance and turbidity and can be further analyzed using scanning electron microscopy (SEM), dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, surface-enhanced Raman spectroscopy and Raman tweezers. Mitigation methods reported are categorized depending on the removal characteristics: (i) Filtration and separation method: Filtration and separation, electrospun nanofiber membrane, constructed wetlands; (ii) Capture and surface attachment method: coagulation, flocculation and sedimentation (CFS), electrocoagulation, adsorption, magnetization, micromachines, superhydrophobic materials and microorganism aggregation; and (iii) Degradation method: photocatalytic degradation, microorganism degradation and thermal degradation; where removal efficiency between 58 and 100% were reported. As these methods are significantly distinctive, the parameters which affect the MP/NP removal performance e.g., pH, type of plastics, presence of interfering chemicals or ions, surface charges etc. are also discussed. 42 granted international patents related to microplastics and nanoplastics removal are also reviewed where the majority of these patents are focused on separation or filtration devices. These devices are efficient for microplastics up to 20 μm but may be ineffective for nanoplastics or fibrous plastics. Several patents were found to focus on methods similar to literature studies e.g., magnetization, CFS, biofilm and microorganism aggregation; with the addition of another method: thermal degradation.
      15  1
  • Publication
    Microplastics and nanoplastics: Recent literature studies and patents on their removal from aqueous environment
    ( 2022-03-01)
    Muhammad Adli Hanif
    ;
    Naimah Ibrahim
    ;
    Farrah Aini Dahalan
    ;
    Umi Fazara Md Ali
    ;
    Masitah Hasan
    ;
    Jalil A.A.
    The presence of microplastics (MP) and nanoplastics (NP) in the environment poses significant hazards towards microorganisms, humans, animals and plants. This paper is focused on recent literature studies and patents discussing the removal process of these plastic pollutants. Microplastics and nanoplastics can be quantified by counting, weighing, absorbance and turbidity and can be further analyzed using scanning electron microscopy (SEM), dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, surface-enhanced Raman spectroscopy and Raman tweezers. Mitigation methods reported are categorized depending on the removal characteristics: (i) Filtration and separation method: Filtration and separation, electrospun nanofiber membrane, constructed wetlands; (ii) Capture and surface attachment method: coagulation, flocculation and sedimentation (CFS), electrocoagulation, adsorption, magnetization, micromachines, superhydrophobic materials and microorganism aggregation; and (iii) Degradation method: photocatalytic degradation, microorganism degradation and thermal degradation; where removal efficiency between 58 and 100% were reported. As these methods are significantly distinctive, the parameters which affect the MP/NP removal performance e.g., pH, type of plastics, presence of interfering chemicals or ions, surface charges etc. are also discussed. 42 granted international patents related to microplastics and nanoplastics removal are also reviewed where the majority of these patents are focused on separation or filtration devices. These devices are efficient for microplastics up to 20 μm but may be ineffective for nanoplastics or fibrous plastics. Several patents were found to focus on methods similar to literature studies e.g., magnetization, CFS, biofilm and microorganism aggregation; with the addition of another method: thermal degradation.
      1  7
  • Publication
    Effect of Aeration Rate on Specific Oxygen Uptake Rate (SOUR) in Treating Chemical Oxygen Demand (COD) in Domestic Wastewater
    ( 2024-01-01)
    Zubir A.A.A.
    ;
    Farrah Aini Dahalan
    ;
    Kamarudin N.S.
    ;
    Naimah Ibrahim
    ;
    Ong Soon An
    ;
    Nabilah Aminah Lutpi
    ;
    Masitah Hasan
    ;
    Nor Azizah Parmin
    Specific oxygen uptake rate (SOUR) is significant parameter to determine the microbial activity and examined the effluent quality in biological wastewater treatment. Chemical oxygen demand (COD) is the major indicator in monitoring the effluent quality in relation on its removal mainly depends on the microbial activity in the activated sludge. So, this research is conducted to study the effect of aeration rate on SOUR and determined the best oxygen requirement in removing COD in domestic wastewater. The procedure was carried out by using domestic wastewater as the seed sludge in sequencing batch reactor. The reactor with working volume of 2L was operating 6 cycles in 24 hours with five phases (feeding, aeration, settle, draw and idle). The aeration time is fixed to 2.5 hours. The dissolved oxygen and COD readings were recorded with four types of aeration rate adjusted at 1L, 2L, 3L and 4L / min daily for 7 days. The result indicates that, 3L/min gives the highest SOUR which reflects that the high activity of microbial in this condition. Besides, the effluent also shows the highest COD removal efficiency on 3L/min of aeration rate. So, as a conclusion the best oxygen requirement for the microbial to carry out their activities on aeration rate of 3L/min.
      1