Umi Fazara Md Ali
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Umi Fazara Md Ali
Official Name
Umi Fazara, Md Ali
Alternative Name
Ali, Umi Fazara Md
Md. Ali, Umi Fazara
Umi Fazara, M. A.
Main Affiliation
Scopus Author ID
57195513638
Researcher ID
AAU-4840-2020

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  • Publication
    Advancement in recycling waste tire activated carbon to potential adsorbents
    ( 2022-12-01)
    Umi Fazara Md Ali
    ;
    Hussin F.
    ;
    Subash Chandra Bose Gopinath
    ;
    Aroua M.K.
    ;
    Khamidun M.H.
    ;
    Jusoh N.
    ;
    Naimah Ibrahim
    ;
    Ahmad S.F.K.
    Waste tires have been identified as one of the contributors to environmental problems and the issue of inadequate landfill spaces. The lack of consistent and systematic approaches such as specific regulations/laws or mechanisms of waste management to waste tires, limited application of technology for recycling waste tires and lack of awareness on the impacts of waste tires problem, make waste tires a source of environmental pollution. Various researches have been conducted on recycling waste tires into polymer bends, and materials to harden concretes, fuels and adsorbent. Researchers suggested that pyrolysis is the current trend of recycling waste tire to harvest the saleable pyrolysis oil and the recycled carbon black. Therefore, this review attempts to compile relevant knowledge about the potential of adsorbent derived from waste tires to be applied in the removal of various types of pollutants like heavy metals, organic pollutants, dye and air/gaseous pollutant. Studies were carried out on revealing the properties and the characteristics of activated carbon derived from waste tire as effective adsorbent which influence the application performance at liquid or gas phase. In addition, the challenges in the production of activated carbon derived from waste tire were discussed.
  • Publication
    Sulfur dioxide removal by calcium-modified fibrous KCC-1 mesoporous silica: kinetics, thermodynamics, isotherm and mass transfer mechanism
    ( 2022-04-01)
    Hanif M.A.
    ;
    Naimah Ibrahim
    ;
    Khairuddin Md Isa
    ;
    Umi Fazara Md Ali
    ;
    Tuan Abdullah T.A.
    ;
    Jalil A.A.
    The removal of sulfur dioxide from industrial flue gas through dry flue gas desulfurization method commonly involves the use of adsorption process with porous sorbent. The efficiency of this process is highly dependent on the adsorption capacity and the adsorption rate of SO2 onto the sorbent materials. The use of KCC-1 mesoporous silica modified with calcium metal additives (Ca/KCC-1) in SO2 adsorption is examined in a fixed bed reactor system. The adsorption capacity of Ca/KCC-1 is found to be critically governed by the reaction temperature and inlet SO2 concentration where low values of both parameters are favorable to achieve the highest adsorption capacity of 3241.94 mg SO2/g sorbent. SO2 molecules are adsorbed on the surface of Ca/KCC-1 by both physisorption and chemisorption processes as assumed by the Avrami kinetic model. Thermodynamic study shows that the process is exothermic and spontaneous in nature, and changes from an ordered stage on the surface of KCC-1 towards an increasingly random stage. The process is well explained by Freundlich isotherm model indicating a slightly heterogeneous process and moderate adsorption capacity. The adsorption stage is limited by film diffusion at the initial stage and by intraparticle diffusion during the transfer of SO2 into the network of pores before adsorption takes place on the active sites.
  • Publication
    Adsorption of carbon dioxide (CO2) by activated carbon derived from waste coffee grounds
    ( 2021-05-24)
    Lim H.K.
    ;
    Umi Fazara Md Ali
    ;
    Razi Ahmad
    ;
    Aroua M.K.
    Currently, three are several agricultural bio-based materials have been successfully utilized as gas adsorbents. In this study, waste coffee grounds (WCGs) have been selected as a potential precursor of Carbon Dioxide (CO2) adsorbents. The preparation parameters for activated carbon derived from WCGs were optimized using Response Surface Methodology (RSM). The optimized preparation parameters were found to be 1:3.67 impregnation ratio of acid, 533oC of carbonization temperature and 1.13 hours of activation time, which resulted in 23.6 wt% of yield. The physical and chemical characteristics of WCGAC in terms of surface morphology, carbon content, ash content and yield were also investigated. The CO2 breakthrough time using WCGAC were carried out at the temperatures of 30, 40, and 60°C. It was found that WCGAC shows a longer CO2 breakthrough times (5 mins) and a higher adsorption capacity (4.33 mg CO2/g adsorbent) at 30oC.
  • Publication
    Evaluation of phenol formaldehyde resin synthesized from sugarcane bagasse bio-oil under optimized parameters
    ( 2022-04-01)
    Ahmad S.F.K.
    ;
    Umi Fazara Md Ali
    ;
    Khairuddin Md Isa
    ;
    Subash Chandra Bose Gopinath
    Bio-oil from biomass is considered as a potential substitute to partially replace phenol in the preparation of phenol formaldehyde resin as replacement to the commercial phenol which high in cost. However, the percentages of bio-oil substitutions need to be determined to ensure that the performance is good as the commercial ones. The aim of this research is to identify the optimum conditions for synthesizing phenol formaldehyde resin (PF) and determines the percentages of bio-oil substitutions by manipulating the synthesizing variables such as formaldehyde to phenol (F/P) catalyst ratio (NaOH/P), catalyst ratio and duration using one-factor-at-time method. The effect of each manipulated variables on shear strength was compared to the Chinese National Standard for PF resin shear strength. Bio-based phenolic resins are synthesized using the optimum conditions by replacing 10, 20, 30 and 40% of phenol with bio-oil from the pyrolysis of sugarcane bagasse. The results obtained shown that the optimum conditions to synthesize phenol formaldehyde resin is at F/P molar ratio of 2.0, catalyst ratio of 0.6 and duration of 3 hour. The results of bio-based phenolic resins bonding performance shows that substitution percentage of bio-oil up to 20% at most gives good performance compared to the pure PF resin.
  • Publication
    Oil palm waste-derived reduced graphene oxide (rGO) for dynamic adsorption of dye in a fixed-bed system
    ( 2024-01-01)
    Mohd Ali Jinnah S.N.H.
    ;
    Umi Fazara Md Ali
    ;
    Subash Chandra Bose Gopinath
    ;
    Naimah Ibrahim
    ;
    Razi Ahmad
    ;
    Mohamed Zuki F.
    This study focuses on investigating the dynamic adsorption of Rhodamine B (RhB) from reduced graphene oxide (rGO) derived from oil palm waste. The synthesis of rGO from palm kernel shell (PKS) was achieved through double oxidation and carbonization method, resulting in a yield of 73.5 wt%. The reduction of oxygen-containing functionalities process using PKS was confirmed by FTIR spectroscopy, microscopic evaluation, and X-ray diffraction analyses. Laboratory-scale fixed-bed experiments were conducted with various process parameters. Both PKS and rGO were used as adsorbents, and a comparison was made based on breakthrough curve analysis, adsorption capacity and percentage removal of dye. The adsorption kinetics of RhB on PKS and rGO were best described by the non-linear Yoon-Nelson model, with a high adsorption capacity of 88.32 mg/g and 195.24 mg/g respectively. Using both PKS and rGO, the maximum adsorption capacity was observed when using 10 cm bed depth column, inlet dye concentration of 5 mg/L, flow rate of 12 mL/min and pH of 7. PKS exhibited good dye removal with an efficiency of 66.54%. Meanwhile, the exothermic behavior highlighted the potential of utilizing rGO for maximum dye removal, achieving an efficiency of 90.35%. This study justifies rGO as a cost-effective superior dye removal adsorbent, providing new prospect for large-scale dye removal.
  • Publication
    Study on characterization of bio-oil derived from sugarcane bagasse (Saccharum barberi) for application as biofuel
    ( 2022-04-01)
    Ahmad S.F.K.
    ;
    Umi Fazara Md Ali
    ;
    Isa K.M.
    ;
    Subash Chandra Bose Gopinath
    Lignocellulosic biomass especially, sugarcane bagasse Saccharum barberi sp., appears to be a more suitable material for partial substitution of transport fuel (diesel) than Saccharum officinarum sp., due to its structural similarity to transport fuel (diesel). Besides that, less research has been implemented on this type of species. Bio-oil can be implemented as biodiesel by processing it further using chemical reactions such as hydrodeoxygenation and cracking with zeolite catalyst. Hence, the purpose of this study is to determine the compatibility of pyrolytic bio-oil produced from Saccharum barberi sp. in comparison with S. officinarum sp. for use as transport fuel (diesel) in automotive applications. This purpose can be accomplished by comparing the oil’s bio-physiochemical properties for both species. The experiment is conducted on a bench-scale on which bio-oil of Saccharum barberi sp. is secured from the catalytic pyrolysis process at a temperature of 500°C and heating rate of 50°C/min with the addition of ZSM-Zeolite catalyst. Thermogravimetric analysis of Saccharum barberi sp. reveals that cellulose is more reactive than lignin, evidenced by the high percentage of weight loss at temperatures ranging from 251°C to 390°C. The high contents of carbon (40.7%) and hydrogen (6.50%), as well as slight traces of sulphur (0.08%) and nitrogen (0.85%), in bio-oil (Saccharum barberi sp.) indicate that it is conceivable to be partially used for replacement in biofuel production. Overall physiochemical properties reveal that Saccharum barberi sp. shows more potential than S. officinarum sp. Gas chromatography–mass spectrometry analysis reveals that bio-oil consists of high amounts of aromatic hydrocarbon (26.2%), phenol (14.8%) and furfural (13.0%) in comparison to S. officinarum sp.
      25  1
  • Publication
    Non-functionalized oil palm waste-derived reduced graphene oxide for methylene blue removal: Isotherm, kinetics, thermodynamics, and mass transfer mechanism
    ( 2023-01-01)
    Ab Aziz N.A.H.
    ;
    Umi Fazara Md Ali
    ;
    Anis Atikah Ahmad
    ;
    Mohd Irfan Hatim Mohamed Dzahir
    ;
    Khamidun M.H.
    ;
    Muhammad Faiq Abdullah
    The discharge of colored effluents from industries is one of the significant sources of water pollution. Therefore, there is a growing demand for efficient and low-cost treatment methods. An adsorption process with reduced graphene oxide (rGO) synthesized using a novel double carbonization and oxidation method from the natural precursor of oil palm empty fruit bunch (OPEFB) as adsorbent is a promising approach for addressing the problem. In this study, OPEFB biochar was mixed with ferrocene with a ratio of 5:1 (m/m) and oxidized under nitrogen flow at a temperature of 300 °C for 20 min, which resulted in 75.8 wt% of yield. The potential of the synthesized rGO as an effective adsorbent for dye removal from water and wastewater was explored using methylene blue (MB) as a model. Several factors were investigated, including adsorbent dosage, initial concentration, contact time, and pH, to obtain the optimum adsorption condition through batch studies. The physical and chemical characteristics of the rGO in terms of functional groups, surface morphology, elemental composition, and crystallinity phase were determined through characterization. The nonlinear isotherms were appropriated using several error functions to describe the adsorption isotherm with a maximum adsorption capacity of 50.07 mg/g. The kinetic study demonstrates that MB's adsorption fits the PFO kinetic model and agrees with Bangham's interpretation of pore diffusion. The adsorption mechanism was found to be physisorption on the multilayer heterogeneous surface of the rGO involving π-π interaction, hydrophobic association, and electrostatic interaction. The thermodynamics study showed that the process was spontaneous and exothermic. The mass transfer mechanism study shows that the adsorption is controlled by intraparticle diffusion and involves complex pathways. The study found that the novel non- functionalized rGO could remove cationic dyes from water and wastewater.
      2
  • Publication
    Surface alkali promotion of carbon dioxide hydrogenation for conservation of carbon sources: Cyclic voltammetry study
    ( 2020-01-01)
    Tan S.Y.
    ;
    Naimah Ibrahim
    ;
    Umi Fazara Md Ali
    ;
    Sara Yasina Yusuf
    ;
    Aroua M.K.
    Conversion of CO2 captured from biogas upgrading process into useful chemicals or fuels e.g. methane is an attractive route towards conservation of carbon sources. Sustainable hydrogenation route could be achieved by combining the process with hydrogen generated from water electrolysis. In this work, cyclic voltammetry was used as preliminary technique to probe the electrochemical behaviour of Na-modified Pt/YSZ as model catalyst under CO2 hydrogenation. The reaction is irreversible and the voltammogram features are not easily distinguishable under reaction conditions. The increase in cathodic peak height and the decrease in peak potential with addition of sodium at low coverage (0.32%) indicated that the charge transfer reaction was enhanced and thus the methanation reaction could be electrochemically promoted given sufficient amount of H2 flow. However, increasing Na coverage was found to decrease the current hysteresis possibly due to formation of sodium compounds such as carbonates or oxides that populate the three-phase-boundary (tpb) active sites, thus deactivating the catalyst.
      1  15
  • Publication
    Advancement in recycling waste tire activated carbon to potential adsorbents
    ( 2022-12-01)
    Umi Fazara Md Ali
    ;
    Hussin F.
    ;
    Subash Chandra Bose Gopinath
    ;
    Aroua M.K.
    ;
    Khamidun M.H.
    ;
    Jusoh N.
    ;
    Naimah Ibrahim
    ;
    Syahirah Faraheen Kabir Ahmad
    Waste tires have been identified as one of the contributors to environmental problems and the issue of inadequate landfill spaces. The lack of consistent and systematic approaches such as specific regulations/laws or mechanisms of waste management to waste tires, limited application of technology for recycling waste tires and lack of awareness on the impacts of waste tires problem, make waste tires a source of environmental pollution. Various researches have been conducted on recycling waste tires into polymer bends, and materials to harden concretes, fuels and adsorbent. Researchers suggested that pyrolysis is the current trend of recycling waste tire to harvest the saleable pyrolysis oil and the recycled carbon black. Therefore, this review attempts to compile relevant knowledge about the potential of adsorbent derived from waste tires to be applied in the removal of various types of pollutants like heavy metals, organic pollutants, dye and air/gaseous pollutant. Studies were carried out on revealing the properties and the characteristics of activated carbon derived from waste tire as effective adsorbent which influence the application performance at liquid or gas phase. In addition, the challenges in the production of activated carbon derived from waste tire were discussed.
      1  19
  • Publication
    Microplastics in facial cleanser: extraction, identification, potential toxicity, and continuous-flow removal using agricultural waste–based biochar
    ( 2023-05-01)
    Hanif M.A.
    ;
    Naimah Ibrahim
    ;
    Farrah Aini Dahalan
    ;
    Umi Fazara Md Ali
    ;
    Masitah Hasan
    ;
    Ayu Wazira Azhari
    ;
    Jalil A.A.
    Microplastic (MP) is an emerging contaminant of concern due to its ubiquitous quantity in the environment, small size, and potential toxicity due to strong affinity towards other contaminants. In this work, MP particles (5–300 μm) were extracted from a commercial facial cleanser and determined to be irregular polyethylene (PE) microbeads based on characterization with field emission scanning electron microscopy (FESEM) and Raman spectroscopy. The potential of extracted MP acting as toxic pollutants’ vector was analyzed via adsorption of methylene blue and methyl orange dye where significant dye uptake was observed. Synthetic wastewater containing the extracted MP was subjected to a continuous-flow column study using palm kernel shell and coconut shell biochar as the filter/adsorbent media. The prepared biochar was characterized via proximate and ultimate analysis, FESEM, contact angle measurement, atomic force microscopy (AFM), and Fourier transform infrared (FTIR) spectroscopy to investigate the role of the biochar properties in MP removal. MP removal performance was determined by measuring the turbidity and weighing the dry mass of particles remaining in the effluent following treatment. Promising results were obtained from the study with highest removal of MP (96.65%) attained through palm kernel shell biochar with particle size of 0.6–1.18 mm and continuous-flow column size of 20 mm. Graphical abstract: [Figure not available: see fulltext.].
      6  23