Now showing 1 - 10 of 32
  • Publication
    Regression analysis of the dielectric and morphological properties for porous Nanohydroxyapatite/Starch composites: a correlative study
    This paper aims to investigate the dielectric properties, i.e., dielectric constant (ε′), dielectric loss factor (ε″), dielectric tangent loss (tan δ), electrical conductivity (σ), and penetration depth (Dp), of the porous nanohydroxyapatite/starch composites in the function of starch proportion, pore size, and porosity over a broad band frequency range of 5 MHz–12 GHz. The porous nanohydroxyapatite/starch composites were fabricated using different starch proportions ranging from 30 to 90 wt%. The results reveal that the dielectric properties and the microstructural features of the porous nanohydroxyapatite/starch composites can be enhanced by the increment in the starch proportion. Nevertheless, the composite with 80 wt% of starch proportion exhibit low dielectric properties (ε′, ε″, tan δ, and σ) and a high penetration depth because of its highly interconnected porous microstructures. The dielectric properties of the porous nanohydroxyapatite/starch composites are highly dependent on starch proportion, average pore size, and porosity. The regression models are developed to express the dielectric properties of the porous nanohydroxyapatite/starch composites (R2 > 0.96) in the function of starch proportion, pore size, and porosity from 1 to 11 GHz. This dielectric study can facilitate the assessment of bone scaffold design in bone tissue engineering applications.
  • Publication
    Formation of bio-based derived dicalcium silicate ceramics via mechanochemical treatment: physical, XRD, SEM and FTIR analyses
    ( 2023-07)
    Siti Nur Hazwani Yunus
    ;
    ; ; ;
    Nur Hazlinda Jakfar
    ;
    ;
    Emma Ziezie Mohd Tarmizi
    ;
    Zainal Abidin Talib
    Beta-dicalcium silicate plays an important role in modern technology, but its tendency for polymorphic transformation results in the dusting phenomenon, is a major challenge. Therefore, mechanochemical treatment is used to reduce the particle size to retain the stability of the polymorph. In this study, pure dicalcium silicate ceramics of β-monoclinic structure with P 121/c1 space group were synthesized using calcium oxide and silicate powders derived from calcined eggshells and rice husks, respectively. The powders were mixed in a 2:1 molar ratio by mechanochemical treatment and heat-treated in the air at temperatures ranging from 900°C to 1100°C for 2 h. The results reveal that pure betadicalcium silicate formed at 1100°C without adding stabilizers. The properties of the pristine and sintered bodies were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM). SEM revealed that the grain and pore sizes increase with rising sintering temperatures. FTIR spectra indicate the existence of Si-O bonds in -4 4 SiO tetrahedrons on all the samples. The sample sintered at 1000°C attains the lowest bulk density (1.2463 g/cm3), whereas the apparent porosity is the highest (62.5%). The reason for this trend is due to the decomposition of carbonate into CO2 gas. The densification onset for the sample sintered at 1100°C as the bulk density rises and grain size achieves 6.06 μm. This study further explains the effect of sintering temperatures on the physical, structural, and morphological properties of Ca2SiO4 which would also be useful for further optimization of its use.
  • Publication
    Regression analysis of the dielectric and morphological properties for Porous Nanohydroxyapatite/Starch composites: a correlative study
    This paper aims to investigate the dielectric properties, i.e., dielectric constant (ε′), dielectric loss factor (ε″), dielectric tangent loss (tan δ), electrical conductivity (σ), and penetration depth (Dp), of the porous nanohydroxyapatite/starch composites in the function of starch proportion, pore size, and porosity over a broad band frequency range of 5 MHz–12 GHz. The porous nanohydroxyapatite/starch composites were fabricated using different starch proportions ranging from 30 to 90 wt%. The results reveal that the dielectric properties and the microstructural features of the porous nanohydroxyapatite/starch composites can be enhanced by the increment in the starch proportion. Nevertheless, the composite with 80 wt% of starch proportion exhibit low dielectric properties (ε′, ε″, tan δ, and σ) and a high penetration depth because of its highly interconnected porous microstructures. The dielectric properties of the porous nanohydroxyapatite/starch composites are highly dependent on starch proportion, average pore size, and porosity. The regression models are developed to express the dielectric properties of the porous nanohydroxyapatite/starch composites (R2 > 0.96) in the function of starch proportion, pore size, and porosity from 1 to 11 GHz. This dielectric study can facilitate the assessment of bone scaffold design in bone tissue engineering applications.
  • Publication
    Dielectric spectroscopy technique for carbohydrate characterization of fragrant rice, brown rice and white rice
    ( 2017-11-20) ;
    Kok Yeow You
    ;
    Lee KimYee
    ;
    Abbas Z.
    ;
    ; ; ;
    Lee Y.S.
    This study was conducted to investigate the feasibility of microwave dielectric spectroscopic technique in characterizing commercial rice due to different level of moisture content. There are some unethical rice industry runner mixes good qualities of rice which can be sold at high price with low cost and quality of rice to maximize profit. It causes fraudulency in business and great lost in term of money to nation who take rice as staple food. It happens frequently in Asian country which is active in agricultural activities. This technique is implemented using Keysight E8362B network analyzer in conjunction with an Keysight 85070E dielectric probe ranging from 200 MHz to 10 GHz. The samples of study are commercially available at market, namely fragrant rice, white rice, and brown rice, respectively. These are the popular and favorite rice for Malaysian due its delicacy and affordable price. Nutrient level for fragrant rice, white rice, and brown rice in terms of protein, moisture, carbohydrate and fat are different and unique. It leads to various electromagnetic responses toward frequency. Dielectric and reflection measurement were conducted to characterize these rice. The presence of polar and non-polar molecules in nutrient of rice causes variation of dielectric and reflection behavior over the operating frequency range.
  • Publication
    Nonlinear optical characterization of phosphate glasses based on ZnO using the Z-scan technique
    ( 2013-06-07)
    Masoumeh Shokati Mojdehi
    ;
    Wan Mahmood Mat Yunus
    ;
    ;
    Zainal Abidin Talib
    ;
    N. Tamchek
    The nonlinear optical properties of a phosphate vitreous system [(ZnO)x −(MgO)30−x −(P2O5)70], where x = 8, 10, 15, 18, and 20 mol% synthesized through the melt-quenching technique have been investigated by using the Z-scan technique. In the experiment, a continuous-wave laser with a wavelength of 405 nm was utilized to determine the sign and value of the nonlinear refractive (NLR) index and the absorption coefficient with closed and opened apertures of the Z-scan setup. The NLR index was found to increase with the ZnO concentration in the glass samples by an order of 10−10 cm2 ·W−1. The real and imaginary parts of the third-order nonlinear susceptibility were calculated by referring tothe NLR index (n2) and absorption coefficient (β) of the samples. The value of the third-order nonlinear susceptibility was presented by nonlinear refractive or absorptive behavior of phosphate glasses for proper utilization in nonlinear optical devices. Based on the measurement, the positive sign of the NLR index shows a self-focusing phenomenon. The figures of merit for each sample were calculated to judge the potential of phosphate glasses for application in optical switching.
  • Publication
    Effect of multi-walled carbon nanotube loading on the dielectric properties of polylactic acid
    Dielectric materials which capable to store charges are constantly being developed and improved for electronic applications such as in microelectronic integrated circuits (ICs). In this study, polylactic acid (PLA)/multiwalled carbon nanotube (MWCNT) composites are prepared and their dielectric properties are investigated. PLA/MWCNT composites have PLA as the matrix and MWCNT as filler with a loading of 1 wt%. The composites are porous composites achieved by using solvent casting and particulate leaching (SCPL) method. A frequency range of 1 kHz to 1 MHz is applied to measure the dielectric properties at room temperature. The PLA/MWCNT composites are categorized as low-k dielectric materials looking at the results of the dielectric test.
  • Publication
    Mineral composition, crystallinity and dielectric evaluation of Bamboo Salt, Himalaya Salt, and Ba’kelalan salt content
    ( 2024) ; ; ; ;
    Ong Hong Liang
    ;
    Tan Xiao Jian
    ;
    Lee Kim Yee
    ;
    You Kok Yeow
    ;
    Emma Ziezie Mohd Tarmizi
    ;
    Mohd Riza Mohd Roslan
    ;
    Siti Aishah Baharuddin
  • Publication
    Microwave dielectric analysis on porous hydroxyapatite/starch composites with various ratio of hydroxyapatite to starch
    This study aims to investigate the dielectric response of the porous hydroxyapatite/starch composites by varying the starch proportion in determining the feasibility of the microwave sample characterization technique in bone tissue engineering. The porous hydroxyapatite/starch composites were fabricated by using natural starch (gelatinization and retrogradation) through the solvent casting and particulate leaching technique. The dielectric constant (ϵ′) and loss factor (ϵ″) of the complex permittivity of the porous hydroxyapatite/starch composites were measured in the Ku band frequency of 12.4-18.0 GHz. ϵ′ and ϵ″ of the porous composites increase with frequency. The highly porous composite that due to higher starch proportion exhibit higher ϵ′ and ϵ″, resulting in the significant dielectric responses.
  • Publication
    Lumped-element circuit modeling for composite scaffold with nano-hydroxyapatite and wangi rice starch
    Mechanistic studies of the interaction of electromagnetic (EM) fields with biomaterials has motivated a growing need for accurate models to describe the EM behavior of biomaterials exposed to these fields. In this paper, biodegradable bone scaffolds were fabricated using Wangi rice starch and nano-hydroxyapatite (nHA). The effects of porosity and composition on the fabricated scaffold were discussed via electrical impedance spectroscopy analysis. The fabricated scaffold was subjected to an electromagnetic field within the X-band and Ku-band (microwave spectrum) during impedance/dielectric measurement. The impedance spectra were analyzed with lumped-element models. The impedance spectra of the scaffold can be embodied in equivalent circuit models composed of passive components of the circuit, i.e., resistors, inductors and capacitors. It represents the morphological, structural and chemical characteristics of the bone scaffold. The developed models describe the impedance characteristics of plant tissue. In this study, it was found that the ε′ and ε″ of scaffold composites exhibited up and down trends over frequencies for both X-band and Ku-band. The circuit models presented the lowest mean percentage errors of Z′ and Z″, i.e., 3.60% and 13.80%, respectively.
  • Publication
    Dielectric properties of Nephelium Lappaceum tropical wood
    Dielectric properties of rambutan wood (Nephelium Lappaceum) were investigated in three anisotropic directions, namely miters-cut, cross-cut, and rib-cut. Dielectric constants and dielectric loss factors were measured at ambient temperatures by using an impedance analyzer. The dielectric constant decreased as frequency increased from 4 to 1 MHz. Among the wood specimens, the rib-cut direction has the lowest dielectric constant, while the cross-cut direction has the highest value. A dielectric dispersion occurred within frequencies 100 Hz to 10 kHz, which corresponding to a relaxation peak as observed on dielectric loss factor spectra. The relaxation peak value of the dielectric loss factors shifted towards higher frequencies in the sequence of rib-cut, miters-cut, and cross-cut specimen. Above 500 Hz, the cross-cut specimen has the highest value conductivity than others. Generally, these variations were subjected to the anatomical structure in the wood, such as parenchyma, ray cell, vessel cell, and fiber cell.