Khor Shing Fhan
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Preferred name
Khor Shing Fhan
Official Name
Shing Fhan, Khor
Alternative Name
Khor, S. F.
Fhan, Khor Shing
Shing, Fhan Khor
Khor, Shing F.
Shing Fhan, Khor
Main Affiliation
Scopus Author ID
35242874900
Researcher ID
W-7216-2019

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  • Publication
    Regression analysis of the dielectric and morphological properties for porous Nanohydroxyapatite/Starch composites: a correlative study
    ( 2022)
    Chong You Beh
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Shukry Abdul Majid
    ;
    Khor Shing Fhan
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Emma Ziezie Mohd Tarmizi
    ;
    Kim Yee Lee
    This paper aims to investigate the dielectric properties, i.e., dielectric constant (ε′), dielectric loss factor (ε″), dielectric tangent loss (tan δ), electrical conductivity (σ), and penetration depth (Dp), of the porous nanohydroxyapatite/starch composites in the function of starch proportion, pore size, and porosity over a broad band frequency range of 5 MHz–12 GHz. The porous nanohydroxyapatite/starch composites were fabricated using different starch proportions ranging from 30 to 90 wt%. The results reveal that the dielectric properties and the microstructural features of the porous nanohydroxyapatite/starch composites can be enhanced by the increment in the starch proportion. Nevertheless, the composite with 80 wt% of starch proportion exhibit low dielectric properties (ε′, ε″, tan δ, and σ) and a high penetration depth because of its highly interconnected porous microstructures. The dielectric properties of the porous nanohydroxyapatite/starch composites are highly dependent on starch proportion, average pore size, and porosity. The regression models are developed to express the dielectric properties of the porous nanohydroxyapatite/starch composites (R2 > 0.96) in the function of starch proportion, pore size, and porosity from 1 to 11 GHz. This dielectric study can facilitate the assessment of bone scaffold design in bone tissue engineering applications.
  • Publication
    Formation of bio-based derived dicalcium silicate ceramics via mechanochemical treatment: physical, XRD, SEM and FTIR analyses
    ( 2023-07)
    Siti Nur Hazwani Yunus
    ;
    Khor Shing Fhan
    ;
    Banjuraizah Johar
    ;
    Nur Maizatul Shima Adzali
    ;
    Nur Hazlinda Jakfar
    ;
    Cheng Ee Meng
    ;
    Emma Ziezie Mohd Tarmizi
    ;
    Zainal Abidin Talib
    Beta-dicalcium silicate plays an important role in modern technology, but its tendency for polymorphic transformation results in the dusting phenomenon, is a major challenge. Therefore, mechanochemical treatment is used to reduce the particle size to retain the stability of the polymorph. In this study, pure dicalcium silicate ceramics of β-monoclinic structure with P 121/c1 space group were synthesized using calcium oxide and silicate powders derived from calcined eggshells and rice husks, respectively. The powders were mixed in a 2:1 molar ratio by mechanochemical treatment and heat-treated in the air at temperatures ranging from 900°C to 1100°C for 2 h. The results reveal that pure betadicalcium silicate formed at 1100°C without adding stabilizers. The properties of the pristine and sintered bodies were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM). SEM revealed that the grain and pore sizes increase with rising sintering temperatures. FTIR spectra indicate the existence of Si-O bonds in -4 4 SiO tetrahedrons on all the samples. The sample sintered at 1000°C attains the lowest bulk density (1.2463 g/cm3), whereas the apparent porosity is the highest (62.5%). The reason for this trend is due to the decomposition of carbonate into CO2 gas. The densification onset for the sample sintered at 1100°C as the bulk density rises and grain size achieves 6.06 μm. This study further explains the effect of sintering temperatures on the physical, structural, and morphological properties of Ca2SiO4 which would also be useful for further optimization of its use.
  • Publication
    Regression analysis of the dielectric and morphological properties for Porous Nanohydroxyapatite/Starch composites: a correlative study
    ( 2022)
    Chong You Beh
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Shukry Abdul Majid
    ;
    Khor Shing Fhan
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Emma Ziezie Mohd Tarmizi
    ;
    Kim Yee Lee
    This paper aims to investigate the dielectric properties, i.e., dielectric constant (ε′), dielectric loss factor (ε″), dielectric tangent loss (tan δ), electrical conductivity (σ), and penetration depth (Dp), of the porous nanohydroxyapatite/starch composites in the function of starch proportion, pore size, and porosity over a broad band frequency range of 5 MHz–12 GHz. The porous nanohydroxyapatite/starch composites were fabricated using different starch proportions ranging from 30 to 90 wt%. The results reveal that the dielectric properties and the microstructural features of the porous nanohydroxyapatite/starch composites can be enhanced by the increment in the starch proportion. Nevertheless, the composite with 80 wt% of starch proportion exhibit low dielectric properties (ε′, ε″, tan δ, and σ) and a high penetration depth because of its highly interconnected porous microstructures. The dielectric properties of the porous nanohydroxyapatite/starch composites are highly dependent on starch proportion, average pore size, and porosity. The regression models are developed to express the dielectric properties of the porous nanohydroxyapatite/starch composites (R2 > 0.96) in the function of starch proportion, pore size, and porosity from 1 to 11 GHz. This dielectric study can facilitate the assessment of bone scaffold design in bone tissue engineering applications.
  • Publication
    Dielectric spectroscopy technique for carbohydrate characterization of fragrant rice, brown rice and white rice
    ( 2017-11-20)
    Cheng Ee Meng
    ;
    Kok Yeow You
    ;
    Lee KimYee
    ;
    Abbas Z.
    ;
    Hasliza A Rahim @ Samsuddin
    ;
    Khor Shing Fhan
    ;
    Zulkarnay Zakaria
    ;
    Lee Y.S.
    This study was conducted to investigate the feasibility of microwave dielectric spectroscopic technique in characterizing commercial rice due to different level of moisture content. There are some unethical rice industry runner mixes good qualities of rice which can be sold at high price with low cost and quality of rice to maximize profit. It causes fraudulency in business and great lost in term of money to nation who take rice as staple food. It happens frequently in Asian country which is active in agricultural activities. This technique is implemented using Keysight E8362B network analyzer in conjunction with an Keysight 85070E dielectric probe ranging from 200 MHz to 10 GHz. The samples of study are commercially available at market, namely fragrant rice, white rice, and brown rice, respectively. These are the popular and favorite rice for Malaysian due its delicacy and affordable price. Nutrient level for fragrant rice, white rice, and brown rice in terms of protein, moisture, carbohydrate and fat are different and unique. It leads to various electromagnetic responses toward frequency. Dielectric and reflection measurement were conducted to characterize these rice. The presence of polar and non-polar molecules in nutrient of rice causes variation of dielectric and reflection behavior over the operating frequency range.
  • Publication
    Microwave dielectric analysis on porous hydroxyapatite/starch composites with various ratio of hydroxyapatite to starch
    ( 2020-07-09)
    You B.C.
    ;
    Cheng Ee Meng
    ;
    Shahriman Abu Bakar
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Eng Swee Kheng
    ;
    Mohd Shukry Abdul Majid
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Khor Shing Fhan
    This study aims to investigate the dielectric response of the porous hydroxyapatite/starch composites by varying the starch proportion in determining the feasibility of the microwave sample characterization technique in bone tissue engineering. The porous hydroxyapatite/starch composites were fabricated by using natural starch (gelatinization and retrogradation) through the solvent casting and particulate leaching technique. The dielectric constant (ϵ′) and loss factor (ϵ″) of the complex permittivity of the porous hydroxyapatite/starch composites were measured in the Ku band frequency of 12.4-18.0 GHz. ϵ′ and ϵ″ of the porous composites increase with frequency. The highly porous composite that due to higher starch proportion exhibit higher ϵ′ and ϵ″, resulting in the significant dielectric responses.
  • Publication
    Lumped-element circuit modeling for composite scaffold with nano-hydroxyapatite and wangi rice starch
    ( 2023)
    Xiao Jian Tan
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Shukry Abdul Majid
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Khor Shing Fhan
    ;
    Kim Yee Lee
    ;
    Kok Yeow You
    ;
    Che Wan Sharifah Robiah Mohamad
    Mechanistic studies of the interaction of electromagnetic (EM) fields with biomaterials has motivated a growing need for accurate models to describe the EM behavior of biomaterials exposed to these fields. In this paper, biodegradable bone scaffolds were fabricated using Wangi rice starch and nano-hydroxyapatite (nHA). The effects of porosity and composition on the fabricated scaffold were discussed via electrical impedance spectroscopy analysis. The fabricated scaffold was subjected to an electromagnetic field within the X-band and Ku-band (microwave spectrum) during impedance/dielectric measurement. The impedance spectra were analyzed with lumped-element models. The impedance spectra of the scaffold can be embodied in equivalent circuit models composed of passive components of the circuit, i.e., resistors, inductors and capacitors. It represents the morphological, structural and chemical characteristics of the bone scaffold. The developed models describe the impedance characteristics of plant tissue. In this study, it was found that the ε′ and ε″ of scaffold composites exhibited up and down trends over frequencies for both X-band and Ku-band. The circuit models presented the lowest mean percentage errors of Z′ and Z″, i.e., 3.60% and 13.80%, respectively.
  • Publication
    Effect of multi-walled carbon nanotube loading on the dielectric properties of polylactic acid
    ( 2024-03-07)
    Nur Azila Azahari
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Mohd Shukry Abdul Majid
    ;
    Maslinda A.B.
    ;
    Cheng Ee Meng
    ;
    Khor Shing Fhan
    Dielectric materials which capable to store charges are constantly being developed and improved for electronic applications such as in microelectronic integrated circuits (ICs). In this study, polylactic acid (PLA)/multiwalled carbon nanotube (MWCNT) composites are prepared and their dielectric properties are investigated. PLA/MWCNT composites have PLA as the matrix and MWCNT as filler with a loading of 1 wt%. The composites are porous composites achieved by using solvent casting and particulate leaching (SCPL) method. A frequency range of 1 kHz to 1 MHz is applied to measure the dielectric properties at room temperature. The PLA/MWCNT composites are categorized as low-k dielectric materials looking at the results of the dielectric test.
      21  2
  • Publication
    The Effect of the Amylose/Amylopectin Contents of Starch on Porosity and Dielectric Properties of the Porous Hydroxyapatite/Starch Composites
    ( 2020-07-09)
    Chong You B.
    ;
    Cheng Ee Meng
    ;
    Abu Bakar S.
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Eng Swee Kheng
    ;
    Mohd Shukry Abdul Majid
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Khor Shing Fhan
    This study aims to determine the effect of the amylose/amylopectin contents of starch on the porosity and dielectric properties of porous hydroxyapatite/starch composites. The porous hydroxyapatite/starch composites were prepared by utilizing the starches (rice, corn and potato starch) via gelatinization and retrogradation process. The complex permittivity of the porous hydroxyapatite/starch composites were evaluated in the frequency range of 12.4-18.0 GHz. The porous composites were exhibited the higher average porosity by using the starch with higher amylopectin content. The highly porous hydroxyapatite/starch composites with higher amylopectin content show the significant fluctuation peaks (at 13.8 and 16.6 GHz) and the higher imaginary part of the complex permittivity (ϵ′′) at higher frequency in the dielectric spectrum, respectively. The real (ϵ′) and imaginary part (ϵ′′) of the complex permittivity of the porous composites could be enhanced by increasing the average porosity and the amylopectin contents.
      27  1
  • Publication
    Dielectric Properties of Hydrothermally Modified Potato, Corn, and Rice Starch
    ( 2022-06-01)
    Beh C.Y.
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Tarmizi E.Z.
    ;
    Khor Shing Fhan
    ;
    Mohd Shukry Abdul Majid
    ;
    Lee K.Y.
    ;
    Mohd Ridzuan Mohd Jamir
    The effect of starch granule sizes, shapes, composition, and frequency on the dielectric properties (dielectric constant, loss factor, and conductivity) of native and hydrothermally modified starches (potato, corn, and rice starch) are investigated in this work. Dielectric properties are determined from 5 Hz to 5 GHz. The modified starches exhibit lower dielectric properties than the native starches from 5 Hz to 5 GHz due to the disruption of the native polysaccharide’s molecular arrangement. The modified potato starch shows the highest loss factor (208.12 at 50 Hz and 19.95 at 500 Hz) and stable conductivity (~5.33 × 10−7 S/m at 50 Hz and 500 Hz) due to the larger continuous network structure after hydrothermal modification. The rice starch shows the largest difference in dielectric constant (47.30%) and loss factor (71.42%) between the modified form and native form in the frequency range of 5 MHz–5 GHz. This is due to the restriction of dipole motions in the closely packed structure after hydrothermal modification. The findings indicate that the quality of starch modification can be characterized by dielectric properties for assisting starch-based plastic production’s design.
      2
  • Publication
    Effect of sintering temperature on dielectric and electrical properties of bio-waste derived beta-dicalcium silicate
    ( 2023-11-01)
    Mohd Yunus S.N.H.
    ;
    Khor Shing Fhan
    ;
    Banjuraizah Johar
    ;
    Nur Maizatul Shima Adzali
    ;
    Jakfar N.H.
    ;
    Cheng Ee Meng
    ;
    Mohd Tarmizi E.Z.
    ;
    Talib Z.A.
    Beta-dicalcium silicate ceramics were synthesized by mechanochemical-assisted solid-state reaction route using rice husks and chicken eggshells as silica and calcium oxide sources. The ceramics were sintered at 900, 1000, and 1100 °C for 2 h in air. The effect of sintering temperature on these ceramics' morphological, breakdown strength, dielectric, and electrical properties was investigated. It was found that the ceramic sintered at the optimized temperature of 1100 °C formed the pure β-dicalcium silicate (β-Ca2SiO4). Scanning electron micrographs showed that with the increase in sintering temperature, the average grain size and pore size of the sintered ceramics increased while the grain boundary density decreased, which promoted the breakdown path and resulted in a decrease in breakdown strength. The dielectric behavior examined from 25 to 300 °C and in a frequency range of 4–5 MHz found that the dielectric constant and loss tangent decreased with increasing frequency. Nyquist plot of impedance confirmed a non-Debye type relaxation, and grain and grain boundary contributions were revealed from equivalent circuit fitting. Variations of impedance spectroscopy reflect the positive and negative temperature coefficient of resistance behavior for these ceramics. Electric modulus spectra revealed that with the sintering temperature increase, the samples' conductivity activation energies increased from 0.35 to 0.46 eV. All the sintered samples attained low dielectric loss (0.004 < tanδ < 0.1) above 103 Hz, which makes them suitable materials for capacitor application.
      1  31