Khor Shing Fhan
Thumbnail Image
Preferred name
Khor Shing Fhan
Official Name
Shing Fhan, Khor
Alternative Name
Khor, S. F.
Fhan, Khor Shing
Shing, Fhan Khor
Khor, Shing F.
Shing Fhan, Khor
Main Affiliation
Scopus Author ID
35242874900
Researcher ID
W-7216-2019

Research Output

Filters

12 1
26
Reset filters

Settings
Now showing 1 - 10 of 26
  • Publication
    Lumped-element circuit modeling for composite Scaffold with Nano-Hydroxyapatite and Wangi Rice Starch
    ( 2023)
    Xiao Jian Tan
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Shukry Abdul Majid
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Khor Shing Fhan
    ;
    Kim Yee Lee
    ;
    Kok Yeow You
    ;
    Che Wan Sharifah Robiah Mohamad
    Mechanistic studies of the interaction of electromagnetic (EM) fields with biomaterials has motivated a growing need for accurate models to describe the EM behavior of biomaterials exposed to these fields. In this paper, biodegradable bone scaffolds were fabricated using Wangi rice starch and nano-hydroxyapatite (nHA). The effects of porosity and composition on the fabricated scaffold were discussed via electrical impedance spectroscopy analysis. The fabricated scaffold was subjected to an electromagnetic field within the X-band and Ku-band (microwave spectrum) during impedance/dielectric measurement. The impedance spectra were analyzed with lumped-element models. The impedance spectra of the scaffold can be embodied in equivalent circuit models composed of passive components of the circuit, i.e., resistors, inductors and capacitors. It represents the morphological, structural and chemical characteristics of the bone scaffold. The developed models describe the impedance characteristics of plant tissue. In this study, it was found that the ε′ and ε″ of scaffold composites exhibited up and down trends over frequencies for both X-band and Ku-band. The circuit models presented the lowest mean percentage errors of Z′ and Z″, i.e., 3.60% and 13.80%, respectively.
  • Publication
    Lumped-element circuit modeling for composite scaffold with nano-hydroxyapatite and wangi rice starch
    ( 2023)
    Xiao Jian Tan
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Shukry Abdul Majid
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Khor Shing Fhan
    ;
    Kim Yee Lee
    ;
    Kok Yeow You
    ;
    Che Wan Sharifah Robiah Mohamad
    Mechanistic studies of the interaction of electromagnetic (EM) fields with biomaterials has motivated a growing need for accurate models to describe the EM behavior of biomaterials exposed to these fields. In this paper, biodegradable bone scaffolds were fabricated using Wangi rice starch and nano-hydroxyapatite (nHA). The effects of porosity and composition on the fabricated scaffold were discussed via electrical impedance spectroscopy analysis. The fabricated scaffold was subjected to an electromagnetic field within the X-band and Ku-band (microwave spectrum) during impedance/dielectric measurement. The impedance spectra were analyzed with lumped-element models. The impedance spectra of the scaffold can be embodied in equivalent circuit models composed of passive components of the circuit, i.e., resistors, inductors and capacitors. It represents the morphological, structural and chemical characteristics of the bone scaffold. The developed models describe the impedance characteristics of plant tissue. In this study, it was found that the ε′ and ε″ of scaffold composites exhibited up and down trends over frequencies for both X-band and Ku-band. The circuit models presented the lowest mean percentage errors of Z′ and Z″, i.e., 3.60% and 13.80%, respectively.
  • Publication
    Dielectric properties of hydrothermally modified potato, corn, and rice starch
    ( 2022)
    Chong You Beh
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Shukry Abdul Majid
    ;
    Khor Shing Fhan
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Emma Ziezie Mohd Tarmizi
    ;
    Kim Yee Lee
    The effect of starch granule sizes, shapes, composition, and frequency on the dielectric properties (dielectric constant, loss factor, and conductivity) of native and hydrothermally modified starches (potato, corn, and rice starch) are investigated in this work. Dielectric properties are determined from 5 Hz to 5 GHz. The modified starches exhibit lower dielectric properties than the native starches from 5 Hz to 5 GHz due to the disruption of the native polysaccharide’s molecular arrangement. The modified potato starch shows the highest loss factor (208.12 at 50 Hz and 19.95 at 500 Hz) and stable conductivity (~5.33 × 10−7 S/m at 50 Hz and 500 Hz) due to the larger continuous network structure after hydrothermal modification. The rice starch shows the largest difference in dielectric constant (47.30%) and loss factor (71.42%) between the modified form and native form in the frequency range of 5 MHz–5 GHz. This is due to the restriction of dipole motions in the closely packed structure after hydrothermal modification. The findings indicate that the quality of starch modification can be characterized by dielectric properties for assisting starch-based plastic production’s design.
  • Publication
    Complex impedance and modulus analysis on porous and non-porous scaffold composites due to effect of Hydroxyapatite/starch proportion
    ( 2023)
    Chong You Beh
    ;
    Cheng Ee Meng
    ;
    Xiao Jian Tan
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Shukry Abdul Majid
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Khor Shing Fhan
    ;
    Kim Yee Lee
    ;
    Che Wan Sharifah Robiah Mohamad
    This study aims to investigate the electric responses (complex modulus and complex impedance analysis) of hydroxyapatite/starch bone scaffold as a function of hydroxyapatite/starch proportion and the microstructural features. Hence, the non-porous and porous hydroxyapatite/starch composites were fabricated with various hydroxyapatite/starch proportions (70/30, 60/40, 50/50, 40/60, 30/70, 20/80, and 10/90 wt/wt%). Microstructural analysis of the porous hydroxyapatite/starch composites was carried out by using scanning electron microscopy. It shows that the formation of hierarchical porous microstructures with high porosity is more significant at a high starch proportion. The complex modulus and complex impedance analysis were conducted to investigate the electrical conduction mechanism of the hydroxyapatite/starch composites via dielectric spectroscopy within a frequency range from 5 MHz to 12 GHz. The electrical responses of the hydroxyapatite/starch composites are highly dependent on the frequency, material proportion, and microstructures. High starch proportion and highly porous hierarchical microstructures enhance the electrical responses of the hydroxyapatite/starch composite. The material proportion and microstructure features of the hydroxyapatite/starch composites can be indirectly reflected by the simulated electrical parameters of the equivalent electrical circuit models.
  • Publication
    Regression analysis of the dielectric and morphological properties for porous Nanohydroxyapatite/Starch composites: a correlative study
    ( 2022)
    Chong You Beh
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Shukry Abdul Majid
    ;
    Khor Shing Fhan
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Emma Ziezie Mohd Tarmizi
    ;
    Kim Yee Lee
    This paper aims to investigate the dielectric properties, i.e., dielectric constant (ε′), dielectric loss factor (ε″), dielectric tangent loss (tan δ), electrical conductivity (σ), and penetration depth (Dp), of the porous nanohydroxyapatite/starch composites in the function of starch proportion, pore size, and porosity over a broad band frequency range of 5 MHz–12 GHz. The porous nanohydroxyapatite/starch composites were fabricated using different starch proportions ranging from 30 to 90 wt%. The results reveal that the dielectric properties and the microstructural features of the porous nanohydroxyapatite/starch composites can be enhanced by the increment in the starch proportion. Nevertheless, the composite with 80 wt% of starch proportion exhibit low dielectric properties (ε′, ε″, tan δ, and σ) and a high penetration depth because of its highly interconnected porous microstructures. The dielectric properties of the porous nanohydroxyapatite/starch composites are highly dependent on starch proportion, average pore size, and porosity. The regression models are developed to express the dielectric properties of the porous nanohydroxyapatite/starch composites (R2 > 0.96) in the function of starch proportion, pore size, and porosity from 1 to 11 GHz. This dielectric study can facilitate the assessment of bone scaffold design in bone tissue engineering applications.
  • Publication
    Regression analysis of the dielectric and morphological properties for Porous Nanohydroxyapatite/Starch composites: a correlative study
    ( 2022)
    Chong You Beh
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Shukry Abdul Majid
    ;
    Khor Shing Fhan
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Emma Ziezie Mohd Tarmizi
    ;
    Kim Yee Lee
    This paper aims to investigate the dielectric properties, i.e., dielectric constant (ε′), dielectric loss factor (ε″), dielectric tangent loss (tan δ), electrical conductivity (σ), and penetration depth (Dp), of the porous nanohydroxyapatite/starch composites in the function of starch proportion, pore size, and porosity over a broad band frequency range of 5 MHz–12 GHz. The porous nanohydroxyapatite/starch composites were fabricated using different starch proportions ranging from 30 to 90 wt%. The results reveal that the dielectric properties and the microstructural features of the porous nanohydroxyapatite/starch composites can be enhanced by the increment in the starch proportion. Nevertheless, the composite with 80 wt% of starch proportion exhibit low dielectric properties (ε′, ε″, tan δ, and σ) and a high penetration depth because of its highly interconnected porous microstructures. The dielectric properties of the porous nanohydroxyapatite/starch composites are highly dependent on starch proportion, average pore size, and porosity. The regression models are developed to express the dielectric properties of the porous nanohydroxyapatite/starch composites (R2 > 0.96) in the function of starch proportion, pore size, and porosity from 1 to 11 GHz. This dielectric study can facilitate the assessment of bone scaffold design in bone tissue engineering applications.
  • Publication
    Dielectric and biodegradation properties of biodegradable nano-hydroxyapatite/starch bone scaffold
    ( 2022)
    Beh Chong You
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Emma Ziezie Mohd Tarmizi
    ;
    Khor Shing Fhan
    ;
    Eng Swee Kheng
    ;
    Mohd Shukry Abdul Majid
    ;
    Mohd Ridzuan Mohd Jamir
    This study is aim to investigate the dielectric properties (dielectric constant, ε′ and loss factor, ε′′) and the biodegradation properties of the nano-hydroxyapatite/starch bone scaffold with various starch proportion in simulated body fluid. The nano-hydroxyapatite/starch bone scaffolds with starch proportions 30, 40, 50, 60, 70, 80, and 90 wt.% were fabricated. The ε′ and ε′′ of nano-hydroxyapatite/starch composite decrease when frequency increases. However, it increases when starch proportion and temperature increase. The biodegradation properties of the nano-hydroxyapatite/starch bone scaffold can be improved when the dielectric properties and porosity are enhanced. The enhancement of dielectric properties and porosity is due to the increment of starch proportion. The nano-hydroxyapatite/starch bone scaffold with the high starch proportion exhibits nano-hydroxyapatite/starch interfaces with strong intermolecular interactions that can stabilize biodegradation and biomineralization. The dielectric properties of the simulated body solutions are highly sensitive to the variation of the ion concentrations (calcium and phosphate). The nano-hydroxyapatite/starch bone scaffold with 80 wt.% starch proportion exhibits significant dielectric and biodegradation properties. It has potential to be a biodegradable inorganic/organic bone scaffold.
  • Publication
    Lumped-element circuit modeling for composite scaffold with Nano-Hydroxyapatite and wangi rice starch
    ( 2023)
    Xiao Jian Tan
    ;
    Cheng Ee Meng
    ;
    Nashrul Fazli Mohd Nasir
    ;
    Mohd Shukry Abdul Majid
    ;
    Mohd Ridzuan Mohd Jamir
    ;
    Khor Shing Fhan
    ;
    Kim Yee Lee
    ;
    Kok Yeow You
    ;
    Che Wan Sharifah Robiah Mohamad
    Mechanistic studies of the interaction of electromagnetic (EM) fields with biomaterials has motivated a growing need for accurate models to describe the EM behavior of biomaterials exposed to these fields. In this paper, biodegradable bone scaffolds were fabricated using Wangi rice starch and nano-hydroxyapatite (nHA). The effects of porosity and composition on the fabricated scaffold were discussed via electrical impedance spectroscopy analysis. The fabricated scaffold was subjected to an electromagnetic field within the X-band and Ku-band (microwave spectrum) during impedance/dielectric measurement. The impedance spectra were analyzed with lumped-element models. The impedance spectra of the scaffold can be embodied in equivalent circuit models composed of passive components of the circuit, i.e., resistors, inductors and capacitors. It represents the morphological, structural and chemical characteristics of the bone scaffold. The developed models describe the impedance characteristics of plant tissue. In this study, it was found that the ε′ and ε″ of scaffold composites exhibited up and down trends over frequencies for both X-band and Ku-band. The circuit models presented the lowest mean percentage errors of Z′ and Z″, i.e., 3.60% and 13.80%, respectively.
  • Publication
    Formation of bio-based derived dicalcium silicate ceramics via mechanochemical treatment: physical, XRD, SEM and FTIR analyses
    ( 2023-07)
    Siti Nur Hazwani Yunus
    ;
    Khor Shing Fhan
    ;
    Banjuraizah Johar
    ;
    Nur Maizatul Shima Adzali
    ;
    Nur Hazlinda Jakfar
    ;
    Cheng Ee Meng
    ;
    Emma Ziezie Mohd Tarmizi
    ;
    Zainal Abidin Talib
    Beta-dicalcium silicate plays an important role in modern technology, but its tendency for polymorphic transformation results in the dusting phenomenon, is a major challenge. Therefore, mechanochemical treatment is used to reduce the particle size to retain the stability of the polymorph. In this study, pure dicalcium silicate ceramics of β-monoclinic structure with P 121/c1 space group were synthesized using calcium oxide and silicate powders derived from calcined eggshells and rice husks, respectively. The powders were mixed in a 2:1 molar ratio by mechanochemical treatment and heat-treated in the air at temperatures ranging from 900°C to 1100°C for 2 h. The results reveal that pure betadicalcium silicate formed at 1100°C without adding stabilizers. The properties of the pristine and sintered bodies were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM). SEM revealed that the grain and pore sizes increase with rising sintering temperatures. FTIR spectra indicate the existence of Si-O bonds in -4 4 SiO tetrahedrons on all the samples. The sample sintered at 1000°C attains the lowest bulk density (1.2463 g/cm3), whereas the apparent porosity is the highest (62.5%). The reason for this trend is due to the decomposition of carbonate into CO2 gas. The densification onset for the sample sintered at 1100°C as the bulk density rises and grain size achieves 6.06 μm. This study further explains the effect of sintering temperatures on the physical, structural, and morphological properties of Ca2SiO4 which would also be useful for further optimization of its use.
  • Publication
    Nonlinear optical characterization of phosphate glasses based on ZnO using the Z-scan technique
    ( 2013-06-07)
    Masoumeh Shokati Mojdehi
    ;
    Wan Mahmood Mat Yunus
    ;
    Khor Shing Fhan
    ;
    Zainal Abidin Talib
    ;
    N. Tamchek
    The nonlinear optical properties of a phosphate vitreous system [(ZnO)x −(MgO)30−x −(P2O5)70], where x = 8, 10, 15, 18, and 20 mol% synthesized through the melt-quenching technique have been investigated by using the Z-scan technique. In the experiment, a continuous-wave laser with a wavelength of 405 nm was utilized to determine the sign and value of the nonlinear refractive (NLR) index and the absorption coefficient with closed and opened apertures of the Z-scan setup. The NLR index was found to increase with the ZnO concentration in the glass samples by an order of 10−10 cm2 ·W−1. The real and imaginary parts of the third-order nonlinear susceptibility were calculated by referring tothe NLR index (n2) and absorption coefficient (β) of the samples. The value of the third-order nonlinear susceptibility was presented by nonlinear refractive or absorptive behavior of phosphate glasses for proper utilization in nonlinear optical devices. Based on the measurement, the positive sign of the NLR index shows a self-focusing phenomenon. The figures of merit for each sample were calculated to judge the potential of phosphate glasses for application in optical switching.