This study aims to determine the effect of the amylose/amylopectin contents of starch on the porosity and dielectric properties of porous hydroxyapatite/starch composites. The porous hydroxyapatite/starch composites were prepared by utilizing the starches (rice, corn and potato starch) via gelatinization and retrogradation process. The complex permittivity of the porous hydroxyapatite/starch composites were evaluated in the frequency range of 12.4-18.0 GHz. The porous composites were exhibited the higher average porosity by using the starch with higher amylopectin content. The highly porous hydroxyapatite/starch composites with higher amylopectin content show the significant fluctuation peaks (at 13.8 and 16.6 GHz) and the higher imaginary part of the complex permittivity (ϵ′′) at higher frequency in the dielectric spectrum, respectively. The real (ϵ′) and imaginary part (ϵ′′) of the complex permittivity of the porous composites could be enhanced by increasing the average porosity and the amylopectin contents.
