Now showing 1 - 10 of 92
  • Publication
    Microstructural Analysis of Fly Ash-based Geopolymers with various Alkali Concentration
    ( 2019-08-14)
    Hui-Teng N.
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    ;
    Yun-Ming L.
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    ;
    Yong-Sing N.
    In the present work, a comparative study on the effect of different concentration of sodium hydroxide (NaOH) on fly ash-based geopolymer was investigated. The geopolymer synthesis by mixing fly ash with alkali activator (a mixture of NaOH and sodium silicate) at solid/liquid ratio of 2.5. The NaOH were used 6M, 8M, 10M, 12M and 14M with constant sodium silicate/NaOH ratio of 2.5. The geopolymers were cured at room temperature (29°C) for 24 hours and 60°C in oven for another 24 hours. The testing and analysis of the fly ash-based geopolymers were performed after 28 days. The adequate Na+ ions and densified microstructure were observed at optimum 8M-NaOH-activated fly ash-based geopolymers.
  • Publication
    Mechanical Properties and Thermal Conductivity of Lightweight Foamed Geopolymer Concretes
    ( 2019-08-14)
    Fatimah Azzahran Abdullah S.
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    Yun-Ming L.
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    ; ;
    Zulkifly K.
    Foamed geopolymer concretes have a better performance in the thermal insulation properties compared to normal geopolymer concretes. In this research, lightweight aggregate geopolymer concretes was incorporated with different percentage of foaming agents (hydrogen peroxide). Compressive strength and thermal conductivity were measured. From results obtained, increased H2O2 contents will decrease the strength of lightweight foamed geopolymer concretes. Lightweight aggregate foamed geopolymer concretes (LWAFGC) with foaming agent content of 0.2wt.% obtained the highest strength of 19.601 MPa. Furthermore, Increased of H2O2 contents also will decrease the thermal conductivity of lightweight foamed geopolymer concretes. Lightweight foamed geopolymer concretes with 2wt.% H2O2 gave the good thermal insulating behavior when the thermal conductivity value recorded the lowest value compare to other wt.% of H2O2 content. The thermal conductivity value of lightweight foamed geopolymer concretes with 2wt.% of H2O2 was 0.072 W/m. K while, the thermal conductivity of other mixtures ranged between 0.077 W/m. K to 0.087 W/m. K., respectively.
  • Publication
    The important characteristic and properties of dolomite minerals and potential uses as bioceramics: an overview
    (Trans Tech Publications Ltd, 2025)
    Nur Hasnidah Ahmad Shukeri
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    ;
    Mohamad Hasmaliza
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    ;
    Dolomite is a raw carbonate mineral rich in contents with calcium, magnesium and oxide compounds also including other minor impurities from other compounds. It could be easily found in sedimentary rock which is most likely known as dolostone associated with limestone and chalk carbonates. This mineral has been used in a variety of industries including agricultural, metallurgy, constructions, biomass and others. Currently, there are abundant sources of local dolomite minerals but have very limited applications when compared to other types of carbonate minerals. This was contributed by the lack of basic technical information on dolomite properties and no extensive research has been done to evaluate the new potential of this mineral. Therefore, this paper made a brief review on the important characteristics, properties and thermal behavior of dolomite and based on these findings discussed the dolomite's suitability and potential to be used as bioceramics and in biomedical applications.<
  • Publication
    Effect of rubber sludge on the physical and mechanical properties of low calcium fly ash-based geopolymer
    (Polish Academy of Sciences, 2025)
    Tee Hoe Woon
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    ; ; ;
    Jia-Ni Lim
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    Ong Shee-Ween
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    O. Wan-En
    ;
    Hang Yong-Jie
    In this research, experimental work has been carried out to check the feasibility of using rubber sludge (RS) to partially replace fly ash (FA) in the production of geopolymer. RS is employed in this study as disposing of RS has led to an issue and is abundant, especially in countries producing rubber products. RS is classified as hazardous waste. Improper awareness on hazardous waste handling can spread a variety of diseases. Therefore, handling of hazardous waste is not easy as competent personnel is required during the collection, transportation, treatment and final disposal. As a result, the cost of disposing the hazardous waste are relatively high. With that, FA incorporated RS geopolymer will able to solve the landfill problems and used it as building materials will save costs, preserve natural resources, and protect the environment from waste impact and hazards. In this study, the physical and mechanical properties were investigated. It was used to replace fly ash at 5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.%. Water absorption, apparent porosity, bulk density, and compressive strength were tested. The test result shows that 5 wt.% of RS incorporation to fly ash-based geopolymer is optimum as it has 1752 kg/m3 of density, 9.5% of water absorption, 19.2% of apparent porosity, and 49.9 MPa of compressive strength.
  • Publication
    Improvements of flexural properties and thermal performance in thin geopolymer based on fly ash and ladle furnace slag using borax decahydrates
    ( 2022)
    Ng Yong-Sing
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    ; ; ;
    Phakkhananan Pakawanit
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    Petrica Vizureanu
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    Mohd Suhaimi Khalid
    ;
    Ng Hui-Teng
    ;
    Hang Yong-Jie
    ;
    Marcin Nabiałek
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    Paweł Pietrusiewicz
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    Sebastian Garus
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    Wojciech Sochacki
    ;
    Agata Śliwa
    This paper elucidates the influence of borax decahydrate addition on the flexural and thermal properties of 10 mm thin fly ash/ladle furnace slag (FAS) geopolymers. The borax decahydrate (2, 4, 6, and 8 wt.%) was incorporated to produce FAB geopolymers. Heat treatment was applied with temperature ranges of 300 °C, 600 °C, 900 °C, 1000 °C and 1100 °C. Unexposed FAB geopolymers experienced a drop in strength due to a looser matrix with higher porosity. However, borax decahydrate inclusion significantly enhanced the flexural performance of thin geopolymers after heating. FAB2 and FAB8 geopolymers reported higher flexural strength of 26.5 MPa and 47.8 MPa, respectively, at 1000 °C as compared to FAS geopolymers (24.1 MPa at 1100 °C). The molten B2O3 provided an adhesive medium to assemble the aluminosilicates, improving the interparticle connectivity which led to a drastic strength increment. Moreover, the borax addition reduced the glass transition temperature, forming more refractory crystalline phases at lower temperatures. This induced a significant strength increment in FAB geopolymers with a factor of 3.6 for FAB8 at 900 °C, and 4.0 factor for FAB2 at 1000 °C, respectively. Comparatively, FAS geopolymers only achieved 3.1 factor in strength increment at 1100 °C. This proved that borax decahydrate could be utilized in the high strength development of thin geopolymers.
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  • Publication
    Preparation of Fly Ash-Ladle Furnace Slag Blended Geopolymer Foam via Pre-Foaming Method with Polyoxyethylene Alkyether Sulphate Incorporation
    ( 2022-06-01)
    Ng Hui Teng
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    ; ; ;
    Rojviriya C.
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    Razi H.M.
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    Garus S.
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    Nabiałek M.
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    Sochacki W.
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    Abidin I.M.Z.
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    Ng Yong Sing
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    Śliwa A.
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    Sandu A.V.
    This paper uses polyoxyethylene alkyether sulphate (PAS) to form foam via pre-foaming method, which is then incorporated into geopolymer based on fly ash and ladle furnace slag. In the literature, only PAS-geopolymer foams made with single precursor were studied. Therefore, the performance of fly ash-slag blended geopolymer with and without PAS foam was investigated at 29–1000 °C. Unfoamed geopolymer (G-0) was prepared by a combination of sodium alkali, fly ash and slag. The PAS foam-to-paste ratio was set at 1.0 and 2.0 to prepare geopolymer foam (G-1 and G-2). Foamed geopolymer showed decreased compressive strength (25.1–32.0 MPa for G-1 and 21.5–36.2 MPa for G-2) compared to G-0 (36.9–43.1 MPa) at 29–1000 °C. Nevertheless, when compared to unheated samples, heated G-0 lost compressive strength by 8.7% up to 1000 °C, while the foamed geopolymer gained compressive strength by 68.5% up to 1000 °C. The thermal stability of foamed geopolymer was greatly improved due to the increased porosity, lower thermal conductivity, and incompact microstructure, which helped to reduce pressure during moisture evaporation and resulted in lessened deterioration.
      1
  • Publication
    Effect of anisotropic pores on the material properties of metakaolin geopolymer composites incorporated with corrugated fiberboard and rubber
    ( 2021-09-01)
    Nur Ain Jaya
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    ; ;
    Foo Wah L.
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    ;
    Zainal Abidin I.M.
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    Azaman N.
    ;
    Ooi Wan-En
    This paper compares the compressive strength and thermal conductivity of metakaolin geopolymer (MKG) incorporated with anisotropic and isotropic pores. MKG was prepared by activation with sodium hydroxide and sodium silicate. Corrugated fiberboard and rubber were included to create anisotropy of pores, and they were added in 3, 5, and 7 layers. Hydrogen peroxide and surfactant were added to generate isotropic pores. For geopolymer with corrugated fiberboard (MKG-C) and rubber (MKG-R), compressive test and thermal conductivity measurement were performed in perpendicular and parallel direction to the flat surface of fiberboard and rubber. The result showed that MKG-C and MKG-R exhibited mechanical and insulation anisotropically. The highest compressive strength was achieved in the parallel loading direction while the lowest thermal conductivity was attained in the perpendicular direction. MKG-C possessed better compressive strength of 26.9 MPa loaded in the parallel direction. The compressive strength performance of MKG-C was greater than MKG-R because of the fibrous-like structure, which further contributes to the strength. The thermal conductivity was low (0.15–0.20 W/mK) for both MKG-C and MKG-R. The anisotropy of pores led to high strength retention and improvement of thermal insulating properties. These properties were contrary to geopolymer with isotropic pores (MKG-F), which have excellent thermal insulating properties but low compressive strength to be eligible for structural applications.
      1
  • Publication
    Interaction of Geopolymer Filler and Alkali Molarity Concentration towards the Fire Properties of Glass-Reinforced Epoxy Composites Fabricated Using Filament Winding Technique
    This paper aims to find out the effect of different weight percentages of geopolymer filler in glass-reinforced epoxy pipe, and which can achieve the best mechanical properties and adhesion between high calcium pozzolanic-based geopolymer matrices. Different weight percentages and molarities of epoxy hardener resin and high calcium pozzolanic-based geopolymer were injected into the glass fiber. By manually winding filaments, composite samples were produced, and they were then allowed to cure at room temperature. To determine how well the geopolymer matrices adhere to the fiber reinforcement, the microstructure of the composites’ surfaces and perpendicular sections were examined. Maximum values of compressive strength and compressive modulus were 94.64 MPa and 2373.58 MPa, respectively, for the sample with a weight percentage of filler loading of 30 wt% for an alkali concentration of 12 M. This is a relatively wide range of geopolymer weight percentage of filler loading from 10 wt% to 40 wt%, at which we can obtain high compressive properties. By referring to microstructural analysis, adhesion, and interaction of the geopolymer matrix to glass fiber, it shows that the filler is well-dispersed and embedded at the fiber glass, and it was difficult to determine the differences within the range of optimal geopolymer filler content. By determining the optimum weight percent of 30 wt% of geopolymer filler and microstructural analysis, the maximum parameter has been achieved via analysis of high calcium pozzolanic-based geopolymer filler. Fire or elevated temperature represents one of the extreme ambient conditions that any structure may be exposed to during its service life. The heat resistance or thermal analysis between glass-reinforced epoxy (GRE) pipe and glass-reinforced epoxy pipe filled with high calcium pozzolanic-based geopolymer filler was studied by investigating burning tests on the samples, which shows that the addition of high calcium pozzolanic-based geopolymer filler results in a significant reduction of the melted epoxy.
      1
  • Publication
    The physical and mechanical properties of fly ash geopolymers with various S/L ratios
    In the present work, a study of the effect of different solid/liquid (S/L) ratio on fly ash geopolymer was investigated. The geopolymer were prepared by mixing fly ash with alkali activator (a mixture of sodium hydroxide and sodium silicate). The S/L ratios were used 1.0, 1.5, 2.0, 2.5, 3.0 and 3.5 with fixed sodium silicate/sodium hydroxide ratio of 2.5 and 8M of sodium hydroxide. The geopolymers were cured at room temperature (29°C) for 24 hours and at 60°C for another 24 hours. The testing and analysis of the fly ash geopolymers were performed after 28 days. The geopolymer showed highest compressive strength (37.6MPa) with 3.0 of S/L ratio, further decreased in compressive strength (2.7MPa) was observed at 3.5.
      1
  • Publication
    Effect of Sodium Aluminate on the Fresh and Hardened Properties of Fly Ash-Based One-Part Geopolymer
    ( 2022-01-01)
    Wan-En O.
    ;
    Yun-Ming L.
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    ; ; ;
    Shee-Ween O.
    ;
    Sandu A.V.
    The one-part geopolymer binder was synthesis from the mixing of aluminosilicate material with solid alkali activators. The properties of one-part geopolymers vary according to the type and amount of solid alkali activators used. This paper presents the effect of various sodium metasilicate-to-sodium aluminate (NaAlO2/Na2SiO3) ratios on fly ash-based one-part geopolymer. The NaAlO2/Na2SiO3 ratios were set at 1.0 to 3.0. Setting time of fresh one-part geopolymer was examined through Vicat needle apparatus. Mechanical and microstructural properties of developed specimens were analysed after 28 days of curing in ambient condition. The study concluded that an increase in NaAlO2 content delayed the setting time of one-part geopolymer paste. The highest compressive strength was achieved at the NaAlO2/Na2SiO3 ratio of 2.5, which was 33.65 MPa. The microstructural analysis revealed a homogeneous structure at the optimum ratio. While the sodium aluminium silicate hydrate (N-A-S-H) and anorthite phases were detected from the XRD analysis.
      20  8