Now showing 1 - 7 of 7
  • Publication
    Hydrogen sulfide removal from fermentative biohydrogen process: Effect of ZSM-5 zeolite loading
    ( 2024-03-01)
    Asman M.K.A.
    ;
    ;
    Wong Y.S.
    ;
    Hanif M.A.
    ;
    ; ; ;
    Hamdzah M.
    The production and consumption of biohydrogen is growing because it is a “green,” renewable energy that can be obtained in a relatively cost-effective manner through anaerobic digestion. Biohydrogen produced from biomass is a viable source of renewable energy; nevertheless, the presence of highly toxic and corrosive hydrogen sulfide (H2S) in the process can hinder the quality of biohydrogen production and limit its application in energy conversion equipment. Consequently, the goal of the research was to assess the feasibility of using ZSM-5 zeolite for H2S adsorption that function as activating agent to enhance biohydrogen quality under thermophilic conditions. The effect of ZMS-5 Zeolite loading (0.2–1.0 g) on biohydrogen production via dark fermentation from mixed fruit waste (MFW) was investigated using anaerobic sludge from a sewage treatment plant. The pH of the broth mixture was adjusted to 6.0, anaerobic conditions were created by purging it with nitrogen gas, and the temperature of the fermentative biohydrogen process was maintained at 60°C. Meanwhile, the H2S adsorption test was run at ambient temperature with flow rates (100 ml/min) and an H2S inlet concentration of 10000 ppm. The results indicate that the Z + H2S exhibit spectral lines corresponding to the S-H asymmetric stretching vibration of H2S at 2345.97 cm−1. The ideal adsorption capacity is at 0.8 g with yet, increasing the dosage amount of adsorbents, increases the time required for the adsorbent to achieve 90% saturation. The non-linear curve fitting demonstrated that the adsorption kinetics of all dosages used followed those of the Avrami kinetic model. This approach of using ZSM-5 zeolite for H2S removal provides an advantage in terms of minimizing environmental pollution and having great potential uses in industrial processes.
  • Publication
    Constructed wetland–microbial fuel cell for azo dyes degradation and energy recovery: Influence of molecular structure, kinetics, mechanisms and degradation pathways
    ( 2020-06-10)
    Oon Y.L.
    ;
    ; ;
    Wong Y.S.
    ;
    ;
    Oon Y.S.
    ;
    Teoh T.P.
    ;
    Lehl H.K.
    ;
    Thung W.E.
    Complete degradation of azo dye has always been a challenge due to the refractory nature of azo dye. An innovative hybrid system, constructed wetland-microbial fuel cell (CW-MFC) was developed for simultaneous azo dye remediation and energy recovery. This study investigated the effect of circuit connection and the influence of azo dye molecular structures on the degradation rate of azo dye and bioelectricity generation. The closed circuit system exhibited higher chemical oxygen demand (COD) removal and decolourisation efficiencies compared to the open circuit system. The wastewater treatment performances of different operating systems were ranked in the decreasing order of CW-MFC (R1 planted-closed circuit) > MFC (R2 plant-free-closed circuit) > CW (R1 planted-open circuit) > bioreactor (R2 plant-free-open circuit). The highest decolourisation rate was achieved by Acid Red 18 (AR18), 96%, followed by Acid Orange 7 (AO7), 67% and Congo Red (CR), 60%. The voltage outputs of the three azo dyes were ranked in the decreasing order of AR18 > AO7 > CR. The results disclosed that the decolourisation performance was significantly influenced by the azo dye structure and the moieties at the proximity of azo bond; the naphthol type azo dye with a lower number of azo bond and more electron-withdrawing groups could cause azo bond to be more electrophilic and more reductive for decolourisation. Moreover, the degradation pathway of AR18, AO7 and CR were elucidated based on the respective dye intermediate products identified through UV–Vis spectrophotometry, high-performance liquid chromatography (HPLC), and gas chromatograph-mass spectrometer (GC–MS) analyses. The CW-MFC system demonstrated high capability of decolouring azo dyes at the anaerobic anodic region and further mineralising dye intermediates at the aerobic cathodic region to less harmful or non-toxic products.
  • Publication
    Wastewater remediation and bioelectricity generation in dual chambered salt bridge microbial fuel cell: A mini-review
    The purpose of this article is to assess the feasibility analysis of microbial fuel cells (MFCs), particularly in the configuration of dual chamber salt bridge microbial fuel cell (DCSB-MFC), as a promising approach for simultaneous bioelectricity generation and wastewater remediation. The application of a salt bridge presents an economically viable alternative to the use of a proton exchange membrane, which is known for its high cost, in the construction of MFCs. This arrangement has been demonstrated to offer significant benefits in terms of enhancing the performance of new elements and evaluating operational parameters. However, it also encounters issues related to the total internal resistance (Rint) of the MFCs as well as power density (P). In addition, it has been found that traditional packing materials such activated carbon and gravel demonstrate poor permeability, internal resistance, and slow biofilm growth. Furthermore, there is a necessity to search for electrodes that possess high resistance to corrosion and are cost-effective to achieve optimal bioelectricity generation. Therefore, this article aims to emphasize the research areas that require attention. By addressing these areas, the actual implementation of this configuration can be brought closer to practical implementation.
  • Publication
    Chemical and biological combined treatment for sugarcane vinasse: selection of parameters and performance studies
    Sugarcane vinasse has been reported as a high strength industrial wastewater that could cause severe environmental pollution due to its complex and bio-refractory compounds. Thus, the combined coagulation and sequencing batch biofilm reactor (SBBR) system was employed for the sugarcane vinasse treatment. This study aims to determine the recommended conditions of various parameters under coagulation and SBBR and investigate the effectiveness of combined processes. First, the approach of the coagulation process could achieve the maximum COD reduction and decolorization efficiencies of 79.0 ± 3.4% and 94.1 ± 1.9%, respectively, under the recommended conditions. Next, SBBR as an integrated biofilm reactor showed excellent synergistic biodegradability, removing 86.6 ± 4.3% COD concentration and 94.6 ± 3.8% color concentration at 3.0 g·COD/L of substrate loading concentration. The kinetic studies of SBBR revealed that the first-order kinetic model was the best fit for COD reduction efficiency. In contrast, the second-order kinetic model was the best fit for decolorization efficiency. The SBBR reaction was further investigated by ultraviolet–visible spectrophotometry (UV–Vis). In the combined processes, SBBR followed by the coagulation process (SBBR–CP) showed greater COD reduction and decolorization efficiencies (97.5 ± 0.3 and 99.4 ± 0.1%) when compared to the coagulation process followed by SBBR (CP–SBBR). This study demonstrated the removal performance and potential application of the combined sequential process to produce effluent that can be reused for bioethanol production and fertigation. This finding provides additional insight for developing effective vinasse treatment using combined chemical and biological processes.
      1
  • Publication
    Role of macrophyte and effect of supplementary aeration in up-flow constructed wetland-microbial fuel cell for simultaneous wastewater treatment and energy recovery
    ( 2017-01-01)
    Oon Yoong Ling
    ;
    ; ; ; ;
    Oon Yoong Sin
    ;
    Harvinder Kaur Lehl
    ;
    Thung Wei Eng
    ;
    Noradiba Nordin
    This study investigates the role of plant (Elodea nuttallii) and effect of supplementary aeration on wastewater treatment and bioelectricity generation in an up-flow constructed wetland-microbial fuel cell (UFCW-MFC). Aeration rates were varied from 1900 to 0 mL/min and a control reactor was operated without supplementary aeration. 600 mL/min was the optimum aeration flow rate to achieve highest energy recovery as the oxygen was sufficient to use as terminal electron acceptor for electrical current generation. The maximum voltage output, power density, normalized energy recovery and Coulombic efficiency were 545.77 ± 25 mV, 184.75 ± 7.50 mW/m3, 204.49 W/kg COD, 1.29 W/m3 and 10.28%, respectively. The variation of aeration flow rates influenced the NO3− and NH4+ removal differently as nitrification and denitrification involved conflicting requirement. In terms of wastewater treatment performance, at 60 mL/min aeration rate, UFCW-MFC achieved 50 and 81% of NO3− and NH4+ removal, respectively. E. nuttallii enhanced nitrification by 17% and significantly contributed to bioelectricity generation.
  • Publication
    Effect of Aeration Rate on Specific Oxygen Uptake Rate (SOUR) in Treating Chemical Oxygen Demand (COD) in Domestic Wastewater
    Specific oxygen uptake rate (SOUR) is significant parameter to determine the microbial activity and examined the effluent quality in biological wastewater treatment. Chemical oxygen demand (COD) is the major indicator in monitoring the effluent quality in relation on its removal mainly depends on the microbial activity in the activated sludge. So, this research is conducted to study the effect of aeration rate on SOUR and determined the best oxygen requirement in removing COD in domestic wastewater. The procedure was carried out by using domestic wastewater as the seed sludge in sequencing batch reactor. The reactor with working volume of 2L was operating 6 cycles in 24 hours with five phases (feeding, aeration, settle, draw and idle). The aeration time is fixed to 2.5 hours. The dissolved oxygen and COD readings were recorded with four types of aeration rate adjusted at 1L, 2L, 3L and 4L / min daily for 7 days. The result indicates that, 3L/min gives the highest SOUR which reflects that the high activity of microbial in this condition. Besides, the effluent also shows the highest COD removal efficiency on 3L/min of aeration rate. So, as a conclusion the best oxygen requirement for the microbial to carry out their activities on aeration rate of 3L/min.
      1
  • Publication
    Biochar: A review of its history, characteristics, factors that influence its yield, methods of production, application in wastewater treatment and recent development
    ( 2022-12-15)
    Nur Salsabila Kamarudin
    ;
    ; ; ; ; ;
    Hamdzah M.
    ;
    Zain N.A.M.
    ;
    Muda K.
    ;
    Wikurendra E.A.
    Biochar can alleviate several issues, and it should also be inexpensive to produce. Most biochars have a high pore structure and diverse functional groups that assist in the adsorption process. Due to the attributed properties of biochar, several studies have demonstrated that biochar is getting more attention for its efficiency in facilitating wastewater treatment. However, to ensure the feasibility of biochar in wastewater treatment, the factors involved in the preparation of biochar that influences its characteristics and adsorption capacity must be understood. This study reviews the history, characteristics, factors that influence its yield, production methods, application, and recent development of biochar in wastewater treatment.
      1