Dye Sensitized Solar Cell (DSSC) is said as a potential solar device which offers easy, cheaper and greener materials and preparation process. However, the efficiency of this device is still an ultimate problem and challenge. In this paper, an organic Remazol orange dye was used as the DSSC dye sensitizer which prepared with different working electrodes. The different working electrodes consist of Titanium Dioxide (TiO2) with Graphene Oxide (GO) and TiO2 with reduced Graphene Oxide (rGO). In order to analyze the adsorption characteristics of GO and rGO, the solution was tested using Ultraviolet-Visible-Near Infrared Spectrophotometry and the surface morphology of all mixed pastes was observed under Atomic Force Microscopy and Scanning Electron Microscope. Then, the device performance was tested under illumination of solar cell simulator. From overall results, the efficiency for all tested devices was quite low from expectation. For this work, the performance of TiO2-rGO DSSC at 0.138% is 84.7% higher compared to the TiO2-GO DSSC which was 0.021%. This result was obtained when the working electrode and dye less exposed to the light during dye preparation process at 24 hours soaking time.