Che Zulzikrami Azner Abidin
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Che Zulzikrami Azner Abidin
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Abidin, Che Zulzikrami Azner
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  • Publication
    Reactive Green 19 degradation using O3/S2 O8(2-) process: Intermediates and proposed degradation pathway
    ( 2022-01-01)
    Mohd Razali N.A.
    ;
    Che Zulzikrami Azner Abidin
    ;
    Ong Soon An
    ;
    Fahmi Muhammad Ridwan
    ;
    Abdul Haqi Ibrahim
    ;
    Siti Nasuha Sabri
    ;
    Kow Su Huan
    ;
    Safya Abdul Malik
    The massive drawbacks of conventional wastewater treatment have led to a demand investigation about new advanced wastewater treatment technology. The issue can be addressed via advanced oxidation processes (AOPs) as witnessed recently. Therefore, the objective of this study was to investigate the performance of ozone/persulfate ((Formula presented.)) process to assess its use as potential degradation of diazo dye which is Reactive Green 19 (RG19). In this work, efficiency, color, and COD removal were investigated over a range of initial pH, persulfate concentration and initial concentration of RG19. The amount of sodium persulfate ((Formula presented.)) was varied at different levels (20–100 mM) relative to precursor radical to assess the optimum usage of persulfate concentration for RG19 degradation. Evidence that RG19 could degrade efficiently had occurred at 100 mg/L, initial pH 9, 60 mM persulfate concentration was identified by FTIR and GC/MS analysis. The results revealed that RG19 could achieve complete decolorization easily as compared to mineralization. In addition, RG19 degradation pathway gave the best representation of level degradation. The GC/MS and FTIR results exhibited the proposed RG19 degradation pathway that involved the characteristic of sulfonic group, (Formula presented.) accompanied with (Formula presented.) became as an indicator of their structure broken down one by one. The degradation products such as oxalic acid, formic acids and others were analyzed and finally converted to carbon dioxide and water. The diazo dye structure itself aided with (Formula presented.) has its superior characteristic as an aid for the efficient degradation process.
      1
  • Publication
    Influence of leachate matrix on oxidation performance of ozonation and aops
    ( 2022-12-15)
    Kow Su Huan
    ;
    Fahmi Muhammad Ridwan
    ;
    Che Zulzikrami Azner Abidin
    ;
    Najihah Abdul Rashid
    ;
    Naimah Ibrahim
    ;
    Abdul Haqi Ibrahim
    ;
    Ong Soon An
    ;
    Wikurendra E.A.
    ;
    Handayani D.
    Landfill leachate is a critical environmental issue that should be adequately treated to prevent it from spreading to the environment. This study explored the influence of raw leachate matrix and treated leachate matrix on O3, O3/H2O2, and O3/PS performance. O3 and AOPs were conducted in a laboratory-scale batch reactor. The findings showed the degradation of p-cresol, COD, and humic substances was much slower in treated leachate matrix than in raw leachate matrix. However, color was found easier to remove in treated leachate. The results revealed a synergic effect between molecular O3 and dissolved organic matter in the raw leachate as the O3 performance was enhanced in the presence of raw leachate matrix, except for color removal. The highest degradation of more than 90% was achieved in O3 /H2 O2 to remove COD, p-cresol, and humic substances, although it is the most affected by the leachate matrix. This study provides vital insight into the notable performance of O3 /PS in color removal regardless of the influence of leachate matrix, suggesting that the sulfate radical-induced oxidation outperformed O3 and O3 /H2 O2 in reducing nitrogen-containing compounds.
      1  39
  • Publication
    The effect of iron doping on ZnO catalyst on dye removal efficiency
    ( 2020-06-10)
    Tzewei T.
    ;
    Abdul Haqi Ibrahim
    ;
    Che Zulzikrami Azner Abidin
    ;
    Fahmi Muhammad Ridwan
    Dyes often being use in many manufacturing processes. Hence, the wastewater resulted from the manufacturing process contain colour which need to be removed before being emitted into any water bodies. Photocatalysis is a method which effectively treating wastewater using photocatalyst. ZnO is an example of semiconductor material which is use as a photocatalyst in the treatment method. Doping with transition metals can improve its properties to maximize its photocatalytic efficiency. In this study, the effect of zinc oxide (ZnO) and zinc oxide doped Fe (ZnO/Fe) photocatalyst for dye removal efficiency were investigated. The photocatalysts were successfully synthesized through sol-gel method and characterized by SEM, FTIR and EDX. The photocatalytic efficiency of ZnO and ZnO/Fe was studied by degrading methylene blue (MB) under the exposure of 3 hours of sunlight with varies operational condition. Optimal photocatalytic efficiency operating parameters were performed by Design Expert 10 using the Response Surface Method (RSM). ZnO appeared as regular shape compared to ZnO/Fe which most of the particles had clumped together. The removal efficiency of MB was increase when the dosage of catalyst increased. However, once the optimum dosage of catalyst exceeded, the removal efficiency of MB reduced. During the experiment, 30 mg of ZnO was capable to remove 90% of MB from the solution. When while, ZnO/Fe exhibited better result as it could remove up to 95% of MB using only 10 mg of ZnO/Fe during the treatment. It can be concluded that doping the ZnO with Fe could improve the catalytic ability of ZnO to degrade MB in wastewater.
      29  2
  • Publication
    Preliminary screening oxidative degradation methyl orange using ozone/ persulfate
    ( 2018)
    Nur Aqilah Razali
    ;
    Che Zulzikrami Azner Abidin
    ;
    Ong Soon An
    ;
    Fahmi Muhammad Ridwan
    ;
    Abdul Haqi Ibrahim
    ;
    Siti Nasuha Sabri
    ;
    Su Huan Kow
    The present study focusing on the performances of advanced oxidation process by using ozonation method towards Methyl Orange based on the efficiency of colour removal and Chemical Oxygen Demand (COD) removal. Factorial design with response surface methodology (RSM) was used to evaluate the interaction between operational conditions, such as pH, initial concentration, contact time and persulfate dosage to obtain the optimum range conditions using a semi-batch reactor. The range of independent variables investigated were pH (3-11), initial concentration (100-500mg/L), contact time (10-50min) and persulfate dosage (20-100mM) while the response variables were colour removal and COD removal of Methyl Orange. The experimental results and statistical analysis showed all the parameters were significant. Thus, from this findings, optimization of operational conditions that had been suggested from the ozone/persulfate RSM analysis were (pH 3, 100 mg/L, 50min, 60mM) that would be produced 99% Colour Removal and 80% COD Removal and help in promoting an efficient ozonation process. The effect list data that showed the most contributed effects to increase the percentages of colour removal were pH and persulfate dosage whereas the contact time and initial concentration had the highest positive effects on the COD removal. Other than that, the interaction between pH, contact time and persulfate dosage were found to be the most influencing interaction. Therefore the least influencing interaction was interaction between persulfate dosage and pH. In this study, the correlation coefficient value R2 for colour removal and COD removal of Methyl Orange were R2= 0.9976 and R2= 0.9924 which suggested a good fit of the first-order regression model with the experimental data.
      6  23
  • Publication
    Influence of leachate matrix on oxidation performance of ozonation and aops
    ( 2022-12-15)
    Kow S.H.
    ;
    Fahmi Muhammad Ridwan
    ;
    Che Zulzikrami Azner Abidin
    ;
    Najihah Abdul Rashid
    ;
    Naimah Ibrahim
    ;
    Abdul Haqi Ibrahim
    ;
    Ong Soon An
    ;
    Wikurendra E.A.
    ;
    Handayani D.
    Landfill leachate is a critical environmental issue that should be adequately treated to prevent it from spreading to the environment. This study explored the influence of raw leachate matrix and treated leachate matrix on O3, O3/H2O2, and O3/PS performance. O3 and AOPs were conducted in a laboratory-scale batch reactor. The findings showed the degradation of p-cresol, COD, and humic substances was much slower in treated leachate matrix than in raw leachate matrix. However, color was found easier to remove in treated leachate. The results revealed a synergic effect between molecular O3 and dissolved organic matter in the raw leachate as the O3 performance was enhanced in the presence of raw leachate matrix, except for color removal. The highest degradation of more than 90% was achieved in O3 /H2 O2 to remove COD, p-cresol, and humic substances, although it is the most affected by the leachate matrix. This study provides vital insight into the notable performance of O3 /PS in color removal regardless of the influence of leachate matrix, suggesting that the sulfate radical-induced oxidation outperformed O3 and O3 /H2 O2 in reducing nitrogen-containing compounds.
      2  47
  • Publication
    Treatment of O3 with Na2S2O8 by ANOVA Interpretation towards degradation of azo dye
    ( 2018-12)
    Noor Ashikin Mohd Razali
    ;
    Che Zulzikrami Azner Abidin
    ;
    Ong Soon An
    ;
    Fahmi Muhammad Ridwan
    ;
    Abdul Haqi Ibrahim
    ;
    S. N. Sabri
    ;
    S.H. Kow
    ;
    S.A. Malik
    Advanced oxidation processes (AOPs) especially ozonation method is widely studied in the wastewater treatmentfield. In this study, it highlighted about threemainenvironmental issues in the world such as1) proposing a method to overcome uncontrollable effluents from textile industriesby using syntheticdyes; 2)creating an improvementof previous conventional method; 3) reduced process time by using statistical approach.To address with this issue, analysis of variance (ANOVA)from Response Surface Methodology (RSM)to study the performance of O3with the help of persulfate (Na2S2O8) for treating one of azo dyes which is Reactive Green 19.This is due to there isvery limited work done by statistical analysis on this study. Hence, ANOVA data would proposestatistical models tailored to the data in 2D and 3D contour plots by knowing the three influenced parameterswhich is pH(6 to 10),persulfate concentration (30to 70mM) and contact time (4 to 20 min). Through the analysis, the result can be concluded that improvement of ozonation process with persulfate (Na2S2O8) werestatistically significant after allinteractive effectsgave a positive feedback towards responses.The obtained optimum conditions included a persulfate concentration (49mM), initial pH (8.89) and contact time (18 min) with fixed initial concentration 100mg/L. The experimental results were corresponded well with predicted models colour removal rates which is 99%.
      1  19
  • Publication
    Effect of ozonation on COD fractionation of wastewater from poultry processing industry
    ( 2020-06-10)
    Fahmi Muhammad Ridwan
    ;
    Che Zulzikrami Azner Abidin
    ;
    Abdul Haqi Ibrahim
    ;
    Kan S.L.E.
    ;
    Loong J.E.
    ;
    Roshasmawi Abdul Wahab
    The objectives of this study were to evaluate the effect of ozonation on the solubility and biodegradability of wastewater from poultry processing industry. In addition, the wastewater also characterized based on the COD fractionation. The wastewater sample used was collected from Advance Chicken Processing (M) Sdn. Bhd., Perlis, Malaysia. Ozonation process was carried out in a semi-batch glass reactor which has a 2 L volume. The COD fractionation of poultry wastewater indicated that non-biodegradable COD is predominant compare to other fractions. However, the wastewater is containing higher percentage biodegradable COD comprehensively. It is expected that ozonation treatment would transform both particulate and soluble non-biodegradable COD towards biodegradable constituent that easily remove by biodegradation. The removal of COD was significant at ozonation duration up to 5 min. However, COD removal efficiency was only increased slightly with the increased of the ozonation duration after 5 min. This may be due to the fact that ozonation for long time would possibly producing constituent that inhibit ozone dissociation.
      3  29
  • Publication
    Removal of palm oil mill effluent by using electro-oxidation process
    ( 2020-06-10)
    Che Zulzikrami Azner Abidin
    ;
    Sabri S.N.
    ;
    Fahmi Muhammad Ridwan
    ;
    Bashir Mohammed J.K.
    ;
    Abdul Haqi Ibrahim
    ;
    Nazerry Rosmady Rahmat
    ;
    Mohamed Hussein N.F.
    ;
    Mahiran N.Q.
    Wastewater includes the Palm Oil Mill Effluent (POME) that gives adverse impacts to the environment especially for water pollution when it is not treated properly. POME are known to have various types of liquids, residual oil and suspended solid as it has very high strength waste in its untreated form. Although conventional biological processes are normally efficient for the degradation of pollutants occurring in wastewater, most of these compounds are not effectively removed. As a result, further treatment is needed to meet more stringent discharge standards of Department of Environment (DOE). This research focused on treatment of POME by using electro-oxidation process (EO). It was done to identify the performance of EO process for colour, chemical oxygen demand (COD), suspended solids (SS), ammoniacal-nitrogen (NH3-N), and turbidity removal as well as the relative effects of different operational parameters such as pH, type of electrodes and contact time. The pH was varied from 3 to 11, the electrodes were aluminium and iron and the contact time was from 0 to 120 min. The most suitable pH, contact time and type of electrode were pH 3, 120 min and Al electrode.
      1  35
  • Publication
    Recovery of nano-lignin from anaerobic treated palm oil mill effluent (AT-POME)
    ( 2020-06-10)
    Ismail H.S.
    ;
    Abdul Haqi Ibrahim
    ;
    Che Zulzikrami Azner Abidin
    ;
    Fahmi Muhammad Ridwan
    Lignin is the main polymers in woody biomass aside cellulose and hemicelluloses Recently, nano-lignin is gaining importance due to the increasing demand for bio-based and bio-active nanomaterial fillers for many applications such as in composite and textile industries. Palm oil mill effluent (POME) is the main wastewater produce by palm oil mills. Anaerobically treated (AT-POME) contains high soluble lignin due to the anaerobic digestion of cellulosic material in POME. Nano-lignin was precipitated by adjusting the initial pH of AT-POME during the sonication process. Sulfuric acid (H2SO4), nitric acid (HNO3), hydrochloric acid (HCl) and phosphoric acid (H3PO4) were used to adjust the initial pH of AT-POME. Result shows that sulfuric acid was the most suitable acid to be used as it could recovered 96% of the soluble lignin in AT-POME. The presence of ultrasonic during the precipitation process had reduced the size to 383.4 nm. The optimum operating parameter for lignin recovery is at pH 4 using sulfuric acid and sonicated at 80 watts for 15 minutes. This study shows that sonication could reduce the size of precipitated lignin from AT-POME. In addition, removal of lignin from AT-POME also reduced the COD content of AT-POME.
      2  33
  • Publication
    Study of O3/S2O82- Advanced Oxidation Processes (AOPs) for removal of dye industrial effluents
    ( 2019)
    Che Zulzikrami Azner Abidin
    ;
    Fahmi Muhammad Ridwan
    ;
    Ong Soon An
    ;
    Abdul Haqi Ibrahim
    ;
    Sabri Siti Nasuha
    ;
    Razali Nur Aqilah
    This research was carried out to study the efficiency of O3/S2O82- system in removal of Reactive Red 120 (RR120) dye sample. Different operating parameter such as pH, initial dye concentration and persulfate dosage were studied to evaluate the performance on removing colour and COD. The removal of colour and COD achieved higher efficiency at pH 7, 100 mg/L of initial dye concentration and persulfate dosage of 5 g S2O82-/1 g RR120. O3/S2O82- with the most effective conditions experienced effective decolourization and degradation of organic pollutants than O3 only. Furthermore, it achieved faster breakdown of azo bond and aromatic groups than O3 after treatment as observed with UV-Vis absorption spectra. The FT-IR analysis obtained new absorption peak that represents alkenes after 20 min of O3 treatment whereas mostly of the absorption bands of O3/S2O82- flattened.
      1  6