Research Output
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PublicationInfluence of Amaranth dye concentration on the efficiency of hybrid system of photocatalytic fuel cell and Fenton process( 2017-10-01)A novel sustainable hybrid system of photocatalytic fuel cell (PFC) and Fenton process is an alternative wastewater treatment technology for energy-saving and efficient treatment of organic pollutants. The electrons generated from PFC photoanode are used to produce H2O2 in the Fenton reactor and react with the in situ generation of Fe2+ from sacrificial iron for hydroxyl radical formation. In this study, the effect of different initial Amaranth dye concentrations on degradation and electricity generation were investigated. ZnO/Zn photoanode was prepared by anodizing method and characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). Results revealed that the maximum power density (9.53 mW/m2) and current density (0.0178 mA/m2) were achieved at 10 mg/L of Amaranth. The correlation between dye degradation, voltage output, and kinetic photocatalytic degradation were also investigated and discussed.
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PublicationIntermolecular mechanistic treatment of recalcitrant environmental pollutants: Azo, benzene, naphthalene and vinyl sulfone( 2017-07-01)A new class of coagulant, from natural resource namely laterite soil has demonstrated efficiency in degrading a wide range of industrial organic pollutants into simple hydrocarbon structures or less toxic compounds. The composition study revealed the relative Si/Al/Fe: 0.57/0.33/0.10 ratios in laterite soil and surface morphology of laterite soil were investigated to analyze the fundamental degradation that drive the decolorization of Reactive Black 5 (RB 5). The interfacial and colloid aspects of laterite soil colloidosomes and dye particles were distinguished with the corresponding mechanism of coagulation–flocculation process. RB5 structure was destabilized by activation of laterite soil colloidosomes through charge neutralization and subsequent siloxane polymerization through enhancement of siloxanes monomers. This research also evaluated the rate laws and reaction mechanism for each of the main chemical network strands of RB 5. The result implied that all the chemical network strands followed the pseudo first order of reactions. Research approach has utilized Fourier Transform Infrared Spectroscopy, Gas Chromatography Mass Spectrometry and Ultraviolet–visible Spectrophotometry (FTIR, GCMS and UV–vis) to study the degradation intermediates structure, chemical derivatives and final products after coagulation–flocculation process.