Now showing 1 - 7 of 7
  • Publication
    Interaction of geopolymer filler and alkali molarity concentration towards the fire properties of glass-reinforced epoxy composites fabricated using filament winding technique
    This paper aims to find out the effect of different weight percentages of geopolymer filler in glass-reinforced epoxy pipe, and which can achieve the best mechanical properties and adhesion between high calcium pozzolanic-based geopolymer matrices. Different weight percentages and molarities of epoxy hardener resin and high calcium pozzolanic-based geopolymer were injected into the glass fiber. By manually winding filaments, composite samples were produced, and they were then allowed to cure at room temperature. To determine how well the geopolymer matrices adhere to the fiber reinforcement, the microstructure of the composites’ surfaces and perpendicular sections were examined. Maximum values of compressive strength and compressive modulus were 94.64 MPa and 2373.58 MPa, respectively, for the sample with a weight percentage of filler loading of 30 wt% for an alkali concentration of 12 M. This is a relatively wide range of geopolymer weight percentage of filler loading from 10 wt% to 40 wt%, at which we can obtain high compressive properties. By referring to microstructural analysis, adhesion, and interaction of the geopolymer matrix to glass fiber, it shows that the filler is well-dispersed and embedded at the fiber glass, and it was difficult to determine the differences within the range of optimal geopolymer filler content. By determining the optimum weight percent of 30 wt% of geopolymer filler and microstructural analysis, the maximum parameter has been achieved via analysis of high calcium pozzolanic-based geopolymer filler. Fire or elevated temperature represents one of the extreme ambient conditions that any structure may be exposed to during its service life. The heat resistance or thermal analysis between glass-reinforced epoxy (GRE) pipe and glass-reinforced epoxy pipe filled with high calcium pozzolanic-based geopolymer filler was studied by investigating burning tests on the samples, which shows that the addition of high calcium pozzolanic-based geopolymer filler results in a significant reduction of the melted epoxy.
  • Publication
    Mechanical effects on different solid to liquid ratio of geopolymer filler in epoxy resin
    Geopolymer is formed from the alkali activation of materials rich in Si and Al content with the addition of a silicate solution to enhance the properties of the materials. This paper presents research on the mechanical properties of fly ash-based geopolymer filler in epoxy resin by varying different solid to liquid ratios using sodium hydroxide and sodium silicate as the alkaline activator. However, the common problem observed from the solid to liquid ratio is the influence of curing time and compressive strength of geopolymer to have the best mechanical property. The mix design for geopolymers of solid to liquid ratio is essential in developing the geopolymer’s mechanical strength. A series of epoxy filled with fly ash-based geopolymer materials with different solid to liquid ratio, which is prepared from 0.5 to 2.5 solid to liquid ratio of alkaline activator. The tensile strength and flexural strength of the epoxy filled with fly ash-based geopolymer materials is determined using Universal Testing Machine under tensile and flexural mode. It was found that the optimum solid to liquid ratio is 2.0, with the optimum tensile and flexural strength value. However, both the tensile and flexural properties of epoxy filled with fly ash-based geopolymer suddenly decrease at a 2.5 solid to liquid ratio. The strength is increasing with the increasing solid to liquid ratio sample of geopolymer filler content.
  • Publication
    Durability of inorganic fiber-reinforced alkali-activated composites
    Durability and sustainability are essential serviceability concerns for alkali-activated composites used in construction. Incorporating inorganic fibers both metal and nonmetal one in alkali-activated materials is beneficial, considering their availability, are more resistant, more rigid, have an higher melting point, and are more heat resistant than traditional fibers. The durability of natural fiber-reinforced alkali-activated composites is influenced by several factors, including type and content of fiber, dispersion and size of fiber, fiber modification, fiber moisture content, fiber alkaline degradation, and fiber mineralization. Besides, this chapter indicates the durability of inorganic fiber-reinforced alkali-activated composites in terms of crack resistance and toughness, high-temperature resistance, wet/dry cycles, freeze-thaw cycles, chemical resistance, and carbonation resistance.
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  • Publication
    EFFECT OF COMPOSITION ON MELT FLOW AND DENSITY OF POLYPROPYLENE COPOLYMER/KAOLIN GEO-FILLER COMPOSITES
    ( 2023-01-01)
    Zulkifli Z.
    ;
    ; ; ;
    Aygörmez Y.
    This study examined the effects rheological properties of different composition kaolin and kaolin geo-filler in polypropylene composites. Polypropylene composites with varying composition of kaolin geo-filler 0 wt%, 2 wt%, 4 wt%, 6 wt%, 8 wt%, and 10 wt% was prepared and compared with polypropylene composite with raw kaolin. Kaolin is an aluminosilicate based mineral filler was used to prepare geopolymer paste by combining with alkaline activator solution. The polypropylene composite was compounded using a twin-screw extruder and the melt flow index was determined by a constant weight pressure of 2.16 kg at 230°C in 10 min. Knowing the melt flow index is necessary to predict and control the process, the study has demonstrated that the composition of kaolin filler and kaolin geo-filler affects the melt flow, melt density and surface morphology at varies composition. Composites with kaolin geo-filler have demonstrated high melt flow index process and having better distribution and flow.
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  • Publication
    Interaction of Geopolymer Filler and Alkali Molarity Concentration towards the Fire Properties of Glass-Reinforced Epoxy Composites Fabricated Using Filament Winding Technique
    This paper aims to find out the effect of different weight percentages of geopolymer filler in glass-reinforced epoxy pipe, and which can achieve the best mechanical properties and adhesion between high calcium pozzolanic-based geopolymer matrices. Different weight percentages and molarities of epoxy hardener resin and high calcium pozzolanic-based geopolymer were injected into the glass fiber. By manually winding filaments, composite samples were produced, and they were then allowed to cure at room temperature. To determine how well the geopolymer matrices adhere to the fiber reinforcement, the microstructure of the composites’ surfaces and perpendicular sections were examined. Maximum values of compressive strength and compressive modulus were 94.64 MPa and 2373.58 MPa, respectively, for the sample with a weight percentage of filler loading of 30 wt% for an alkali concentration of 12 M. This is a relatively wide range of geopolymer weight percentage of filler loading from 10 wt% to 40 wt%, at which we can obtain high compressive properties. By referring to microstructural analysis, adhesion, and interaction of the geopolymer matrix to glass fiber, it shows that the filler is well-dispersed and embedded at the fiber glass, and it was difficult to determine the differences within the range of optimal geopolymer filler content. By determining the optimum weight percent of 30 wt% of geopolymer filler and microstructural analysis, the maximum parameter has been achieved via analysis of high calcium pozzolanic-based geopolymer filler. Fire or elevated temperature represents one of the extreme ambient conditions that any structure may be exposed to during its service life. The heat resistance or thermal analysis between glass-reinforced epoxy (GRE) pipe and glass-reinforced epoxy pipe filled with high calcium pozzolanic-based geopolymer filler was studied by investigating burning tests on the samples, which shows that the addition of high calcium pozzolanic-based geopolymer filler results in a significant reduction of the melted epoxy.
      1
  • Publication
    Effects of Different Fiber Sizes in PLA/Carbon Fiber Composites on Mechanical Properties
    This study assessed the morphology and chemical composition of coir coconut husk carbon fiber, as well as the impact of fiber diameters on the physical and mechanical properties of polylactic acid composites. Researchers are studying polylactide acid, a biodegradable material. This eco-friendly material’s excellent features, generated from sustainable and renewable sources, have drawn many people. Malaysia’s high coconut fiber output made coir husk a popular commodity. Coconut fibers are lignin, cellulose, and hemicellulose. Alkaline treatment eliminates hemicellulose, oil, wax, and other contaminants from coir fibers and removes lignin. Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy were used to examine the treated coconut fibers’ chemical modification analysis and morphology. Coconut coir husk was carbonized to produce carbon fiber using a furnace operated at 300°C for 2 hours. Fiber and polylactic acid were mixed in different fiber sizes (0, 53 µm, 75 µm, and 212 µm) via extrusion and injection processing techniques. The results showed that the alkali treatment reduced the hydroxyl (-OH) group and separated the area from the carbonyl (C=O) group of coconut coir husk, which changed the filler’s hydrophilicity. The fiber size of 212 µm was discovered to have the highest tensile and flexural strength values. According to testing, the modified material structure had a better surface fill-matrix bond. Thus, generalized fiber sizing and characterization methods were developed. Regardless of the matrix, this method can characterize natural fiber strength and interfacial shear strength of varied diameters and solid contents.
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  • Publication
    Mechanical Effect on Different Geopolymer Filler in Glass Reinforced Epoxy Composite
    Glass reinforced epoxy are widely known in oil and gas industry as glass reinforced epoxy pipe. However, glass reinforced epoxy has limitation such as demanding careful handling due fabrication, installation and transportation because of brittle nature itself and low compressive strength. The aim of this research is to characterize and study the effect of different geopolymer filler in the glass reinforced epoxy pipe composites. Filament winding method will be used in producing glass reinforced epoxy composite. Samples will be prepared with different weight percentage of geopolymer filler loading and different types of geopolymer filler which is fly ash-based geopolymer and kaolin-based geopolymer with 10wt% - 40wt% of geopolymer filler loading. Microstructure was obtained by using Scanning Electron Microscopy showed spherical shaped of fly ash raw material and plate-like structure for kaolin raw material. After undergoes the mechanical testing involved compressive test, pipe sample of glass reinforced epoxy filled with 20 wt% of fly ash-based geopolymer filler showed the best performances above them all. The compressive strength value was 43.05 MPa. Glass reinforced epoxy composite pipe filled with different geopolymer are not widely used in this research area. Therefore, by using geopolymer as a filler can improve the properties of glass reinforced epoxy composite pipe. Hence, a waste material like geopolymer can reduce the cost of material and improve the environment.
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