Now showing 1 - 3 of 3
  • Publication
    Revealing the influences of functional groups in azo dyes on the degradation efficiency and power output in solar photocatalytic fuel cell
    ( 2020-12-01)
    Khalik, Wan Fadhilah
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    ; ;
    Yusoff N.A.
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    ;
    Lee, Sin-Li
    In this study, the degradation efficiency and electricity generation of the azo dyes affected by the functional groups and molecular structure in a solar photocatalytic fuel cell (PFC) system were investigated and discussed in detail. Four different azo dyes such as, Acid Orange 7 (AO7), Acid Red 18 (AR18), Reactive Black 5 (RB5), Reactive Red 120 (RR120) with different molecular structure were evaluated. The degradation efficiency of AO7, AR18, RB5 and RR120 achieved 5.6 ± 0.3%, 11.1 ± 0.6%, 41.9 ± 0.9% and 52.1 ± 1.3%, respectively, after 6 h irradiated under solar light. In addition, the maximum power density, Pmax for AO7, AR18, RB5 and RR120 was 0.0269 ± 0.01, 0.111 ± 0.03, 1.665 ± 0.67 and 4.806 ± 1.79 mW cm−2, respectively. Meanwhile, the concentration of COD for AO7, AR18, RB5 and RR120 reduced to 16 ± 0.1, 10 ± 0.3, 7 ± 0.6 and 3 ± 0.9 mg L−1, respectively. The concentration ratio of benzene / naphthalene, benzene / azo bond and naphthalene / azo bond, respectively, was analyzed to investigate the impact of the functional groups over photodegradation of the azo dyes in PFC. Electron releasing groups (-OH and –NH2) and electron withdrawing groups (-SO3Na) which attached to the naphthalene or benzene ring also played a pivotal role in the degradation mechanism.
      2  25
  • Publication
    Discovering the roles of electrode distance and configuration in dye degradation and electricity generation in photocatalytic fuel cell integrated electro-Fenton process
    ( 2022-01-01)
    Thor S.H.
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    ; ; ; ;
    Nordin N.
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    Ong Yong Por
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    Yap Kea Lee
    Photocatalytic fuel cell (PFC) integrated electro-Fenton (EF) system (PFC-EF system) was considered as an eco-friendly approach for dye degradation and electricity generation simultaneously. The modification on configuration of PFC-EF system was aimed to improve the dye degradation and power output. Effect of electrode distance on the efficiency of PFC-EF system was investigated as it was a crucial factor in the mass transfer of ions in PFC-EF system. Closer electrode distance reduced the resistance flow of ions and enhanced the mass transfer of ions between the electrodes in both PFC and EF, eventually yielded higher concentration of reactive species for removal of dye. Four different electrode configurations by varying the number of cathodes in PFC and EF were investigated to discover the most efficient operating configuration for this PFC-EF system. The dye decolourization rate was evaluated and compared by using pseudo-first order and second order in both PFC and EF system, respectively. Results revealed that single cathode PFC-EF system was the most effective configuration in dye degradation while double cathodes PFC-EF system was the optimal configuration to be used for power output.
      2  22
  • Publication
    Influence of Amaranth dye concentration on the efficiency of hybrid system of photocatalytic fuel cell and Fenton process
    ( 2017-10-01)
    Noradiba Nordin
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    ; ; ; ;
    Sin Li Lee
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    Oon Yoong Sin
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    Oon Yoong Ling
    A novel sustainable hybrid system of photocatalytic fuel cell (PFC) and Fenton process is an alternative wastewater treatment technology for energy-saving and efficient treatment of organic pollutants. The electrons generated from PFC photoanode are used to produce H2O2 in the Fenton reactor and react with the in situ generation of Fe2+ from sacrificial iron for hydroxyl radical formation. In this study, the effect of different initial Amaranth dye concentrations on degradation and electricity generation were investigated. ZnO/Zn photoanode was prepared by anodizing method and characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). Results revealed that the maximum power density (9.53 mW/m2) and current density (0.0178 mA/m2) were achieved at 10 mg/L of Amaranth. The correlation between dye degradation, voltage output, and kinetic photocatalytic degradation were also investigated and discussed.
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