Umi Fazara Md Ali
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Preferred name
Umi Fazara Md Ali
Official Name
Umi Fazara, Md Ali
Alternative Name
Ali, Umi Fazara Md
Md. Ali, Umi Fazara
Umi Fazara, M. A.
Main Affiliation
Scopus Author ID
57195513638
Researcher ID
AAU-4840-2020

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  • Publication
    Advancement in recycling waste tire activated carbon to potential adsorbents
    ( 2022-12-01)
    Umi Fazara Md Ali
    ;
    Hussin F.
    ;
    Subash Chandra Bose Gopinath
    ;
    Aroua M.K.
    ;
    Khamidun M.H.
    ;
    Jusoh N.
    ;
    Naimah Ibrahim
    ;
    Ahmad S.F.K.
    Waste tires have been identified as one of the contributors to environmental problems and the issue of inadequate landfill spaces. The lack of consistent and systematic approaches such as specific regulations/laws or mechanisms of waste management to waste tires, limited application of technology for recycling waste tires and lack of awareness on the impacts of waste tires problem, make waste tires a source of environmental pollution. Various researches have been conducted on recycling waste tires into polymer bends, and materials to harden concretes, fuels and adsorbent. Researchers suggested that pyrolysis is the current trend of recycling waste tire to harvest the saleable pyrolysis oil and the recycled carbon black. Therefore, this review attempts to compile relevant knowledge about the potential of adsorbent derived from waste tires to be applied in the removal of various types of pollutants like heavy metals, organic pollutants, dye and air/gaseous pollutant. Studies were carried out on revealing the properties and the characteristics of activated carbon derived from waste tire as effective adsorbent which influence the application performance at liquid or gas phase. In addition, the challenges in the production of activated carbon derived from waste tire were discussed.
  • Publication
    Sulfur dioxide removal by calcium-modified fibrous KCC-1 mesoporous silica: kinetics, thermodynamics, isotherm and mass transfer mechanism
    ( 2022-04-01)
    Hanif M.A.
    ;
    Naimah Ibrahim
    ;
    Khairuddin Md Isa
    ;
    Umi Fazara Md Ali
    ;
    Tuan Abdullah T.A.
    ;
    Jalil A.A.
    The removal of sulfur dioxide from industrial flue gas through dry flue gas desulfurization method commonly involves the use of adsorption process with porous sorbent. The efficiency of this process is highly dependent on the adsorption capacity and the adsorption rate of SO2 onto the sorbent materials. The use of KCC-1 mesoporous silica modified with calcium metal additives (Ca/KCC-1) in SO2 adsorption is examined in a fixed bed reactor system. The adsorption capacity of Ca/KCC-1 is found to be critically governed by the reaction temperature and inlet SO2 concentration where low values of both parameters are favorable to achieve the highest adsorption capacity of 3241.94 mg SO2/g sorbent. SO2 molecules are adsorbed on the surface of Ca/KCC-1 by both physisorption and chemisorption processes as assumed by the Avrami kinetic model. Thermodynamic study shows that the process is exothermic and spontaneous in nature, and changes from an ordered stage on the surface of KCC-1 towards an increasingly random stage. The process is well explained by Freundlich isotherm model indicating a slightly heterogeneous process and moderate adsorption capacity. The adsorption stage is limited by film diffusion at the initial stage and by intraparticle diffusion during the transfer of SO2 into the network of pores before adsorption takes place on the active sites.
  • Publication
    Adsorption of carbon dioxide (CO2) by activated carbon derived from waste coffee grounds
    ( 2021-05-24)
    Lim H.K.
    ;
    Umi Fazara Md Ali
    ;
    Razi Ahmad
    ;
    Aroua M.K.
    Currently, three are several agricultural bio-based materials have been successfully utilized as gas adsorbents. In this study, waste coffee grounds (WCGs) have been selected as a potential precursor of Carbon Dioxide (CO2) adsorbents. The preparation parameters for activated carbon derived from WCGs were optimized using Response Surface Methodology (RSM). The optimized preparation parameters were found to be 1:3.67 impregnation ratio of acid, 533oC of carbonization temperature and 1.13 hours of activation time, which resulted in 23.6 wt% of yield. The physical and chemical characteristics of WCGAC in terms of surface morphology, carbon content, ash content and yield were also investigated. The CO2 breakthrough time using WCGAC were carried out at the temperatures of 30, 40, and 60°C. It was found that WCGAC shows a longer CO2 breakthrough times (5 mins) and a higher adsorption capacity (4.33 mg CO2/g adsorbent) at 30oC.
  • Publication
    Evaluation of phenol formaldehyde resin synthesized from sugarcane bagasse bio-oil under optimized parameters
    ( 2022-04-01)
    Ahmad S.F.K.
    ;
    Umi Fazara Md Ali
    ;
    Khairuddin Md Isa
    ;
    Subash Chandra Bose Gopinath
    Bio-oil from biomass is considered as a potential substitute to partially replace phenol in the preparation of phenol formaldehyde resin as replacement to the commercial phenol which high in cost. However, the percentages of bio-oil substitutions need to be determined to ensure that the performance is good as the commercial ones. The aim of this research is to identify the optimum conditions for synthesizing phenol formaldehyde resin (PF) and determines the percentages of bio-oil substitutions by manipulating the synthesizing variables such as formaldehyde to phenol (F/P) catalyst ratio (NaOH/P), catalyst ratio and duration using one-factor-at-time method. The effect of each manipulated variables on shear strength was compared to the Chinese National Standard for PF resin shear strength. Bio-based phenolic resins are synthesized using the optimum conditions by replacing 10, 20, 30 and 40% of phenol with bio-oil from the pyrolysis of sugarcane bagasse. The results obtained shown that the optimum conditions to synthesize phenol formaldehyde resin is at F/P molar ratio of 2.0, catalyst ratio of 0.6 and duration of 3 hour. The results of bio-based phenolic resins bonding performance shows that substitution percentage of bio-oil up to 20% at most gives good performance compared to the pure PF resin.
  • Publication
    Oil palm waste-derived reduced graphene oxide (rGO) for dynamic adsorption of dye in a fixed-bed system
    ( 2024-01-01)
    Mohd Ali Jinnah S.N.H.
    ;
    Umi Fazara Md Ali
    ;
    Subash Chandra Bose Gopinath
    ;
    Naimah Ibrahim
    ;
    Razi Ahmad
    ;
    Mohamed Zuki F.
    This study focuses on investigating the dynamic adsorption of Rhodamine B (RhB) from reduced graphene oxide (rGO) derived from oil palm waste. The synthesis of rGO from palm kernel shell (PKS) was achieved through double oxidation and carbonization method, resulting in a yield of 73.5 wt%. The reduction of oxygen-containing functionalities process using PKS was confirmed by FTIR spectroscopy, microscopic evaluation, and X-ray diffraction analyses. Laboratory-scale fixed-bed experiments were conducted with various process parameters. Both PKS and rGO were used as adsorbents, and a comparison was made based on breakthrough curve analysis, adsorption capacity and percentage removal of dye. The adsorption kinetics of RhB on PKS and rGO were best described by the non-linear Yoon-Nelson model, with a high adsorption capacity of 88.32 mg/g and 195.24 mg/g respectively. Using both PKS and rGO, the maximum adsorption capacity was observed when using 10 cm bed depth column, inlet dye concentration of 5 mg/L, flow rate of 12 mL/min and pH of 7. PKS exhibited good dye removal with an efficiency of 66.54%. Meanwhile, the exothermic behavior highlighted the potential of utilizing rGO for maximum dye removal, achieving an efficiency of 90.35%. This study justifies rGO as a cost-effective superior dye removal adsorbent, providing new prospect for large-scale dye removal.
  • Publication
    Bio-removal of lead (II) ions under optimal condition by zinc chloride-impregnated activated carbon from brown alga
    ( 2024-01-01)
    Osman N.S.
    ;
    Umi Fazara Md Ali
    ;
    Subash Chandra Bose Gopinath
    ;
    Hussin F.
    ;
    Aroua M.K.
    Sargassum sp., a brown alga in the division of macroalgae was evaluated for its ability to synthesis macroalgal-based activated carbon and remove lead (II) ions from synthetic aqueous solution. The sargassum activated carbon (SAC) was prepared by chemical activation impregnated with zinc chloride followed by carbonization. The surface morphology and functional group of untreated Sargassum sp. powder (SAP) and activated Sargassum sp. carbon (SAC) were scanned and presented with the Scanning Electron Microscope (SEM) and Fourier Transform Infrared spectroscopy (FTIR). Batch studies were conducted to explore maximum removal efficiency in term of pH, initial lead (II) ions concentration, contact time, adsorbent dosage, and temperature for the efficient adsorption. The maximum lead (II) ions uptake capacity for SAC was obtained at pH 5, initial lead (II) ions concentration at 25 mg/L, operation time of 60 min, adsorbent dosage of 0.1 g and temperature of 40 °C. The adsorption data were well-fitted by the Freundlich isotherm model, with an R2 value of 1.000, indicating a good fit. The kinetic study revealed that the adsorption of lead (II) ions followed a pseudo-first-order kinetic model, with an R2 value of 0.9746. This study validates the use of brown algae in the treatment of heavy metal contamination in wastewater.
      12  2
  • Publication
    Non-functionalized oil palm waste-derived reduced graphene oxide for methylene blue removal: Isotherm, kinetics, thermodynamics, and mass transfer mechanism
    ( 2023-01-01)
    Ab Aziz N.A.H.
    ;
    Umi Fazara Md Ali
    ;
    Anis Atikah Ahmad
    ;
    Mohd Irfan Hatim Mohamed Dzahir
    ;
    Khamidun M.H.
    ;
    Muhammad Faiq Abdullah
    The discharge of colored effluents from industries is one of the significant sources of water pollution. Therefore, there is a growing demand for efficient and low-cost treatment methods. An adsorption process with reduced graphene oxide (rGO) synthesized using a novel double carbonization and oxidation method from the natural precursor of oil palm empty fruit bunch (OPEFB) as adsorbent is a promising approach for addressing the problem. In this study, OPEFB biochar was mixed with ferrocene with a ratio of 5:1 (m/m) and oxidized under nitrogen flow at a temperature of 300 °C for 20 min, which resulted in 75.8 wt% of yield. The potential of the synthesized rGO as an effective adsorbent for dye removal from water and wastewater was explored using methylene blue (MB) as a model. Several factors were investigated, including adsorbent dosage, initial concentration, contact time, and pH, to obtain the optimum adsorption condition through batch studies. The physical and chemical characteristics of the rGO in terms of functional groups, surface morphology, elemental composition, and crystallinity phase were determined through characterization. The nonlinear isotherms were appropriated using several error functions to describe the adsorption isotherm with a maximum adsorption capacity of 50.07 mg/g. The kinetic study demonstrates that MB's adsorption fits the PFO kinetic model and agrees with Bangham's interpretation of pore diffusion. The adsorption mechanism was found to be physisorption on the multilayer heterogeneous surface of the rGO involving π-π interaction, hydrophobic association, and electrostatic interaction. The thermodynamics study showed that the process was spontaneous and exothermic. The mass transfer mechanism study shows that the adsorption is controlled by intraparticle diffusion and involves complex pathways. The study found that the novel non- functionalized rGO could remove cationic dyes from water and wastewater.
      2
  • Publication
    Reverse water gas shift reaction over a Cu/ZnO catalyst supported on regenerated spent bleaching earth (RSBE) in a slurry reactor: the effect of the Cu/Zn ratio on the catalytic activity
    ( 2023-01-19)
    Phey Phey M.L.
    ;
    Tuan Abdullah T.A.
    ;
    Umi Fazara Md Ali
    ;
    Mohamud M.Y.
    ;
    Ikram M.
    ;
    Nabgan W.
    The catalytic conversion of CO2via the Reverse Water Gas Shift (RWGS) reaction for CO production is a promising environment-friendly approach. The greenhouse gas emissions from burning fossil fuels can be used to produce valuable fuels or chemicals through CO2 hydrogenation. Therefore, this project was to study the CO2 conversion via RWGS over various Cu/ZnO catalysts supported by regenerated spent bleaching earth (RSBE) prepared by wet impregnation technique with different Cu : Zn ratios (0.5, 1.0, 1.5, 2.0, 3.0). The causes of environmental pollution from the disposal of spent bleaching earth (SBE) from an edible oil refinery can be eliminated by using it as catalyst support after the regeneration process. The synthesized catalysts were characterized by thermogravimetric analysis (TGA), X-ray diffraction (XRD), temperature-programmed reduction of hydrogen (TPR-H2), pyridine-adsorbed Fourier transform infrared (FTIR-pyridine), temperature programmed desorption of carbon dioxide (TPD-CO2), N2 physisorption, and Fourier transform infrared (FTIR) analysis. The RWGS reaction was carried out in a slurry reactor at 200 °C, with a pressure of 3 MPa, a residence time of 4 h, and catalyst loading of 1.0 g with an H2/CO2 ratio of 3. According to experimental data, the Cu/Zn ratio significantly impacts the catalytic structure and performance. The catalytic activity increased until the Cu : Zn ratio reached the maximum value of 1.5, while a further increase in Cu/Zn ratio inhibited the catalytic performance. The CZR3 catalyst (Cu/Zn ratio of 1.5) with a higher catalytic reducibility, high copper dispersion with small crystalline size, lower total pore volume as well as higher basicity showed superior catalytic performance in terms of CO2 conversion (40.67%) and CO yield (39.91%). Findings on the effect of reaction conditions revealed that higher temperature (>240 °C), higher pressure (>3 MPa), higher reaction time (>4 h) and higher catalyst loading (>1.25 g) could improve CO2 conversion to CO yield. A maximum CO2 conversion of 45.8% and multiple recycling stability of the catalyst were achieved, showing no significant decrease in CO2 conversion.
      1  16
  • Publication
    Optimization of Nickel Precipitation and Leaching Process from Simulated Industrial Waste: A Study on pH, Contact Time, and Sulfuric Acid Concentration
    ( 2024-01-01)
    Zulkurnai N.Z.
    ;
    Umi Fazara Md Ali
    ;
    Naimah Ibrahim
    ;
    Mohd Irfan Hatim Mohamed Dzahir
    ;
    Nor Ashikin Ahmad
    ;
    Zuki F.M.
    The presence of nickel in industrial waste has emerged as a significant environmental concern, predominantly attributed to the plating industry. The significant objective of this study is to optimize the precipitation and leaching method to extract valuable nickel from the waste material. The high concentration of nickel found in the waste makes it a potentially valuable resource. To explore its potential extraction, the precipitation and leaching processes were optimized using a simulated Watts bath solution which is widely employed in the industry. This study focuses on examining the influence of pH, contact time, and sulfuric acid concentration on the extraction of nickel concentration during the precipitation and leaching processes. To develop a prediction model for the process, three models were taken into consideration: quadratic, linear, and 2F1. The quadratic model exhibited the greatest adjusted R2 value, suggesting a superior level of fit in comparison with the linear and 2F1 models. The predicted R2 value of 0.8169 exhibits a satisfactory level of concordance with the adjusted R2 value of 0.9737. The recommended optimal conditions proposed by response surface methodology (RSM) consisted of a pH value of 10.56, a contact time of 16.52 h, and a sulfuric acid concentration of 1.80 M in order to achieve a nickel concentration of 28,415 mg/L.
      1
  • Publication
    Sulfur dioxide removal by calcium-modified fibrous KCC-1 mesoporous silica: kinetics, thermodynamics, isotherm and mass transfer mechanism
    ( 2022-04-01)
    Muhammad Adli Hanif
    ;
    Naimah Ibrahim
    ;
    Khairuddin Md Isa
    ;
    Umi Fazara Md Ali
    ;
    Tuan Abdullah T.A.
    ;
    Jalil A.A.
    The removal of sulfur dioxide from industrial flue gas through dry flue gas desulfurization method commonly involves the use of adsorption process with porous sorbent. The efficiency of this process is highly dependent on the adsorption capacity and the adsorption rate of SO2 onto the sorbent materials. The use of KCC-1 mesoporous silica modified with calcium metal additives (Ca/KCC-1) in SO2 adsorption is examined in a fixed bed reactor system. The adsorption capacity of Ca/KCC-1 is found to be critically governed by the reaction temperature and inlet SO2 concentration where low values of both parameters are favorable to achieve the highest adsorption capacity of 3241.94 mg SO2/g sorbent. SO2 molecules are adsorbed on the surface of Ca/KCC-1 by both physisorption and chemisorption processes as assumed by the Avrami kinetic model. Thermodynamic study shows that the process is exothermic and spontaneous in nature, and changes from an ordered stage on the surface of KCC-1 towards an increasingly random stage. The process is well explained by Freundlich isotherm model indicating a slightly heterogeneous process and moderate adsorption capacity. The adsorption stage is limited by film diffusion at the initial stage and by intraparticle diffusion during the transfer of SO2 into the network of pores before adsorption takes place on the active sites.
      2  17