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Khor Shing Fhan
Preferred name
Khor Shing Fhan
Official Name
Shing Fhan, Khor
Alternative Name
Khor, S. F.
Fhan, Khor Shing
Shing, Fhan Khor
Khor, Shing F.
Shing Fhan, Khor
Main Affiliation
Scopus Author ID
35242874900
Researcher ID
W-7216-2019
Now showing
1 - 10 of 35
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PublicationFormation of bio-based derived dicalcium silicate ceramics via mechanochemical treatment: physical, XRD, SEM and FTIR analyses( 2023-07)
;Siti Nur Hazwani Yunus ; ; ; ;Nur Hazlinda Jakfar ; ;Emma Ziezie Mohd TarmiziZainal Abidin TalibBeta-dicalcium silicate plays an important role in modern technology, but its tendency for polymorphic transformation results in the dusting phenomenon, is a major challenge. Therefore, mechanochemical treatment is used to reduce the particle size to retain the stability of the polymorph. In this study, pure dicalcium silicate ceramics of β-monoclinic structure with P 121/c1 space group were synthesized using calcium oxide and silicate powders derived from calcined eggshells and rice husks, respectively. The powders were mixed in a 2:1 molar ratio by mechanochemical treatment and heat-treated in the air at temperatures ranging from 900°C to 1100°C for 2 h. The results reveal that pure betadicalcium silicate formed at 1100°C without adding stabilizers. The properties of the pristine and sintered bodies were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM). SEM revealed that the grain and pore sizes increase with rising sintering temperatures. FTIR spectra indicate the existence of Si-O bonds in -4 4 SiO tetrahedrons on all the samples. The sample sintered at 1000°C attains the lowest bulk density (1.2463 g/cm3), whereas the apparent porosity is the highest (62.5%). The reason for this trend is due to the decomposition of carbonate into CO2 gas. The densification onset for the sample sintered at 1100°C as the bulk density rises and grain size achieves 6.06 μm. This study further explains the effect of sintering temperatures on the physical, structural, and morphological properties of Ca2SiO4 which would also be useful for further optimization of its use. -
PublicationDielectric spectroscopy technique for carbohydrate characterization of fragrant rice, brown rice and white rice( 2017-11-20)
; ;Kok Yeow You ;Lee KimYee ;Abbas Z. ; ; ;Lee Y.S.This study was conducted to investigate the feasibility of microwave dielectric spectroscopic technique in characterizing commercial rice due to different level of moisture content. There are some unethical rice industry runner mixes good qualities of rice which can be sold at high price with low cost and quality of rice to maximize profit. It causes fraudulency in business and great lost in term of money to nation who take rice as staple food. It happens frequently in Asian country which is active in agricultural activities. This technique is implemented using Keysight E8362B network analyzer in conjunction with an Keysight 85070E dielectric probe ranging from 200 MHz to 10 GHz. The samples of study are commercially available at market, namely fragrant rice, white rice, and brown rice, respectively. These are the popular and favorite rice for Malaysian due its delicacy and affordable price. Nutrient level for fragrant rice, white rice, and brown rice in terms of protein, moisture, carbohydrate and fat are different and unique. It leads to various electromagnetic responses toward frequency. Dielectric and reflection measurement were conducted to characterize these rice. The presence of polar and non-polar molecules in nutrient of rice causes variation of dielectric and reflection behavior over the operating frequency range. -
PublicationThe effect of pressing load on 8 mol% Yttria stabilized Zirconia grade 204NS-GThe aim of this study is to understand the compaction characteristics of as received granulated 8 mol% yttria-stabilized zirconia (8YSZ). The samples were compacted at different loads and sintered at 1550 °C with the heating rate of 5°C/min for 5 hours. The densification, morphology analysis and crystal structure of the sintered were compared. The densification of granulated 8YSZ achieved 67% as increasing pressing load (0.1 tonne to 0.4 tonne). Rietveld quantitative phase analysis demonstrates that the tetragonal-ZrO2 phase reduces in granulated 8YSZ. The amount of cubic-ZrO2 phase dramatically dropped for both granulated as the pressing load increased. From the morphology analysis, granulated sample found to be porous observed on the surface as compaction load applied. Compaction load has no significant effect on the densification of granule sintered 8YSZ in the current study. The maximum densification was only reached 67% by using granulated 8YSZ powder with 0.4 tonne pressing load.
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PublicationThe thermal behavior of cordierite-based ceramic with the substitution of treated flue gas desulfurization sludge in the non-stoichiometric cordierite composition(Springer, 2023)
;Fatin Fatini Othman ; ; ;Nik Akmar RejabSuffi Irni AliasThe substitution of FGD sludge that is rich with a glass-forming agent in non-stoichiometric cordierite composition is able to crystallize α-cordierite at the low sintering temperature, 1250 °C via solid-state reaction methods. Even though the substitution of MgO with FGD sludge can reduce the sintering temperature, the physical and mechanical properties of cordierite-based ceramic with FGD sludge are depleted due to the decomposition of SO3 took place during the sintering process and thus lead to the formation of voids in the ceramic. Thus, this paper is focusing on the thermal properties of cordierite-based ceramic when subjected to a high sintering temperature, 1000 °C using a dilatometric test. Different wt% of treated FGD sludge substitution gave a different type of CTE value, but 3.0 wt% of FGD sludge is able to obtain the lowest CTE value, 2.26 × 10–6/°C, compared to other samples as this sample obtains a single phase of α-cordierite phases. -
PublicationThe mechanochemical process and Hâ‚‚SOâ‚„ treatment on the rehydration of Anhydrite from FGD sludge into Gypsum and Hemihydrate(Springer, 2023)
;Fatin Fatini Othman ; ; ;Nik Akmar RejabSuffi Irni AliasThe rehydration of anhydrite (CaSO₄) leads to the crystallization of gypsum (CaSO₄⋅2H₂O) has been widely studied. Different process parameter had been conducted on anhydrite from the flue gas desulphurization (fgd) sludge to identify its ability to be reused as synthetic gypsum. A mechanochemical process using a high-energy planetary mill would break down the particle size and enhance the reaction of Ca²+ and SO₄ ²− with water while additives modify the number of ions present in the sample during the hydration. Difference hydrothermal temperatures (80 and 130 °C) for 30 min were conducted to dehydrate the synthetic gypsum from fgd sludge to hemihydrate (CaSO₄⋅0.5H₂O) to identify its potential to replace natural gypsum during the plaster of Paris production. The sample without a mechanochemical process wasn’t able to crystallize a high amount of gypsum while sample with 5 × 10–4 mol−1 of H₂SO₄ additive was able to crystallize a high amount of gypsum from the fgd sludge. After undergoing the hydrothermal process, all of the samples were able to crystallize hemihydrate at low-intensity peak due to the favourable of hemihydrate crystal’s growth at plane [31-3] only, which leads to the preferred orientation of hemihydrate crystal. -
PublicationComplex Impedance and Modulus Analysis on Porous and Non-Porous Scaffold Composites Due to Effect of Hydroxyapatite/Starch Proportion( 2023-01-01)
;Beh C.Y. ; ;Tan X.J. ;Mohd Nasir N.F. ; ; ; ;Lee K.Y.This study aims to investigate the electric responses (complex modulus and complex impedance analysis) of hydroxyapatite/starch bone scaffold as a function of hydroxyapatite/starch proportion and the microstructural features. Hence, the non-porous and porous hydroxyapatite/starch composites were fabricated with various hydroxyapatite/starch proportions (70/30, 60/40, 50/50, 40/60, 30/70, 20/80, and 10/90 wt/wt%). Microstructural analysis of the porous hydroxyapatite/starch composites was carried out by using scanning electron microscopy. It shows that the formation of hierarchical porous microstructures with high porosity is more significant at a high starch proportion. The complex modulus and complex impedance analysis were conducted to investigate the electrical conduction mechanism of the hydroxyapatite/starch composites via dielectric spectroscopy within a frequency range from 5 MHz to 12 GHz. The electrical responses of the hydroxyapatite/starch composites are highly dependent on the frequency, material proportion, and microstructures. High starch proportion and highly porous hierarchical microstructures enhance the electrical responses of the hydroxyapatite/starch composite. The material proportion and microstructure features of the hydroxyapatite/starch composites can be indirectly reflected by the simulated electrical parameters of the equivalent electrical circuit models.4 -
PublicationMorphological and optical properties of porous hydroxyapatite/cornstarch (HAp/Cs) composites( 2020-01-01)
;Beh C.Y. ; ; ;Mohd Tarmizi E.Z. ;Eng S.K. ; ; ;Ahmad Saad F.S.This paper presents the correlation between the morphological characteristics and the diffuse reflectance (optical properties) of the porous hydroxyapatite/cornstarch (HAp/Cs) composites with various starch proportions (30, 40, 50, 60, 70, 80 and 90 wt%). The porous composites were measured via SEM and enhanced by image processing to find the average pore size, strut width, and average surface roughness. The average porosity of the porous composites was measured using liquid displacement method. The diffuse reflectance spectroscopy was implemented to investigate the diffuse reflectance and the corresponding optical band gap energy of the porous composites in the 500e900 nm range. A relationship between morphological characteristics and diffuse reflectance properties were established using Pearson's correlation coefficient. The findings of the study depict that a strong correlation can be noticed between optical band gap energy with porosity, pore sizes and surface roughness of the porous composites. Meanwhile, the strong correlations between the diffuse reflectance spectral gradient with surface roughness can be observed. The moderate correlations can be observed between the diffuse reflectance spectral gradient with pore sizes and strut width of the porous composites.2 -
PublicationA Comprehensive Review of Midrange Wireless Power Transfer Using Dielectric Resonators( 2021-01-01)
; ; ;Faiz Wan Ali W.F. ; ;Kamarudin M.R. ; ; ; ; ;Nurulazlina RamliMagnetic resonant coupling (MRC) is one of the techniques that are widely used in wireless power transfer (WPT) systems. The technique is commonly used for enhancing distance while maintaining power transfer efficiency (PTE). Many studies have investigated new technologies to extend the distance of MRC while maintaining high PTE values. The most promising technique to date in MRC is the addition of a resonator between the transmitter and the receiver coil. The implementation of the resonator varies based on different designs, sizes, and material types, although the outcomes remain unsatisfactory. By introducing dielectric material resonators, PTE can be improved by lowering the ohmic loss which becomes a problem on conventional resonators. This study presents a general overview on the use of dielectric material as a resonator in MRC WPT technology and its technological development. The basic operation of MRC WPT is summarized with up-to-date technical improvements related to dielectric material as a resonator in the field of WPT. An overview of the current limitations and challenges of this technique is also highlighted in this study.1 -
PublicationLow frequency dielectric and optical behavior on physicochemical properties of hydroxyapatite/cornstarch composite( 2021-10-15)
;Beh C.Y. ; ; ; ;Eng S.K. ; ;Lee K.Y.An investigation on relationship among the physicochemical, optical and dielectric properties of the hydroxyapatite/cornstarch (HA/Cs) composites with the starch proportion of 30, 40, 50, 60, 70, 80 and 90 wt% is presented in this work. The HA/Cs composites have been characterized via FTIR, XRD, DRS and impedance analyzer. This work depicts that the strong interaction is exhibited between the hydroxyapatite nanoparticles and starch as the starch proportion increases. This increment trend results in the higher crystallinity of the HA/Cs composites. The highly crystallized HA/Cs with hydroxyapatite nucleation center presents low optical properties (diffuse reflectance and optical band gap energy). The HA/Cs composite with 80 wt% starch proportion (H2C8) show higher dielectric properties (dielectric constant, loss factor and conductivity) due to the stronger interfacial interaction and close-packed HA/Cs crystalline structure. The relationship among the physicochemical, optical and dielectric properties of the HA/Cs composite is studied in this work for potential of instrumentation design.2 1 -
PublicationMineral composition, crystallinity and dielectric evaluation of Bamboo Salt, Himalaya Salt, and Ba’kelalan salt content( 2024)
; ; ; ; ;Ong Hong Liang ;Tan Xiao Jian ;Lee Kim Yee ;You Kok Yeow ;Emma Ziezie Mohd Tarmizi ;Mohd Riza Mohd RoslanSiti Aishah Baharuddin32 1