Towards platinum free counter electrode in dye sensitized solar cells, some carbon-based materials like carbon nanotubes and graphene are fully utilized due to their extraordinary properties such as high aspect ratio and conductivity. In this paper, single-walled carbon nanotubes (SWCNT), reduced graphene oxide (rGO) and hybrid structure of rGO-SWCNT spray coated counter electrodes were compared with graphite as the reference material. The morphology of these materials was analyzed with FESEM and FTIR. The DSSC performance was then measured using solar simulator. The current-voltage (I-V) characteristics show that the rGO-SWCNT counter electrode result the excellent performance with efficiency of ~1.86 %, 95.2 % better than graphite. This higher performance was attributed by the complete oxygen-functional group removal during reduction process which offers large active surface area for electro-photocatalytic activity, higher conductivity, better structure and properties compared to the individual forms.
