The concept of zero charge potential (Epzc) is manipulated to eliminates the effect of the electric double layer in order to mitigate the corrosion reactions through the zero-charge corrosion protection (ZCCP) method. The efficiency of the ZCCP method was examined by planned intervals test on pure Mg metal in 3.5% NaCl solution. The test results showed that the tendency of both liquid corrosiveness and metal corrodibility are decreased from -1562.7mm/yr (Eocp) to -98.2mm/yr (Epzc). ZCCP technique was succeeded by corrosion protection efficiency of pure Mg which was recorded between 93 to 96% in 3.5%) NaCl solution.