Now showing 1 - 2 of 2
  • Publication
    Microbial fuel cell operation using monoazo and diazo dyes as terminal electron acceptor for simultaneous decolourisation and bioelectricity generation
    ( 2017-03-05)
    Oon Yoong Sin
    ;
    ; ; ;
    Oon Yoong Ling
    ;
    Harvinder Kaur Lehl
    ;
    Thung Wei Eng
    ;
    Noradiba Nordin
    Monoazo and diazo dyes [New coccine (NC), Acid orange 7 (AO7), Reactive red 120 (RR120) and Reactive green 19 (RG19)] were employed as electron acceptors in the abiotic cathode of microbial fuel cell. The electrons and protons generated from microbial organic oxidation at the anode which were utilized for electrochemical azo dye reduction at the cathodic chamber was successfully demonstrated. When NC was employed as the electron acceptor, the chemical oxygen demand (COD) removal and dye decolourisation efficiencies obtained at the anodic and cathodic chamber were 73 Â± 3% and 95.1 Â± 1.1%, respectively. This study demonstrated that the decolourisation rates of monoazo dyes were ∼50% higher than diazo dyes. The maximum power density in relation to NC decolourisation was 20.64 mW/m 2 , corresponding to current density of 120.24 mA/m 2 . The decolourisation rate and power output of different azo dyes were in the order of NC > AO7 > RR120 > RG19. The findings revealed that the structure of dye influenced the decolourisation and power performance of MFC. Azo dye with electron-withdrawing group at para substituent to azo bond would draw electrons from azo bond; hence the azo dye became more electrophilic and more favourable for dye reduction.
  • Publication
    Role of macrophyte and effect of supplementary aeration in up-flow constructed wetland-microbial fuel cell for simultaneous wastewater treatment and energy recovery
    ( 2017-01-01)
    Oon Yoong Ling
    ;
    ; ; ; ;
    Oon Yoong Sin
    ;
    Harvinder Kaur Lehl
    ;
    Thung Wei Eng
    ;
    Noradiba Nordin
    This study investigates the role of plant (Elodea nuttallii) and effect of supplementary aeration on wastewater treatment and bioelectricity generation in an up-flow constructed wetland-microbial fuel cell (UFCW-MFC). Aeration rates were varied from 1900 to 0 mL/min and a control reactor was operated without supplementary aeration. 600 mL/min was the optimum aeration flow rate to achieve highest energy recovery as the oxygen was sufficient to use as terminal electron acceptor for electrical current generation. The maximum voltage output, power density, normalized energy recovery and Coulombic efficiency were 545.77 ± 25 mV, 184.75 ± 7.50 mW/m3, 204.49 W/kg COD, 1.29 W/m3 and 10.28%, respectively. The variation of aeration flow rates influenced the NO3− and NH4+ removal differently as nitrification and denitrification involved conflicting requirement. In terms of wastewater treatment performance, at 60 mL/min aeration rate, UFCW-MFC achieved 50 and 81% of NO3− and NH4+ removal, respectively. E. nuttallii enhanced nitrification by 17% and significantly contributed to bioelectricity generation.
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