Mohd. Mustafa Al Bakri Abdullah
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Mohd. Mustafa Al Bakri Abdullah
Official Name
Abdulah, Mohd. Mustafa Al Bakri
Alternative Name
Abdullah, M.M.A.
M.M.A. Abdullah
Mustafa Al Bakri, A. M.
Albakri Abdullah, M. M.
Main Affiliation
CeGeoGTech UniMAP
Scopus Author ID
53164519100

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  • Publication
    Effect of rubber sludge on the physical and mechanical properties of low calcium fly ash-based geopolymer
    (Polish Academy of Sciences, 2025)
    Tee Hoe Woon
    ;
    Heah Cheng Yong
    ;
    Ng Qi Hwa
    ;
    Mohd. Mustafa Al Bakri Abdullah
    ;
    Jia-Ni Lim
    ;
    Ong Shee-Ween
    ;
    O. Wan-En
    ;
    Hang Yong-Jie
    In this research, experimental work has been carried out to check the feasibility of using rubber sludge (RS) to partially replace fly ash (FA) in the production of geopolymer. RS is employed in this study as disposing of RS has led to an issue and is abundant, especially in countries producing rubber products. RS is classified as hazardous waste. Improper awareness on hazardous waste handling can spread a variety of diseases. Therefore, handling of hazardous waste is not easy as competent personnel is required during the collection, transportation, treatment and final disposal. As a result, the cost of disposing the hazardous waste are relatively high. With that, FA incorporated RS geopolymer will able to solve the landfill problems and used it as building materials will save costs, preserve natural resources, and protect the environment from waste impact and hazards. In this study, the physical and mechanical properties were investigated. It was used to replace fly ash at 5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.%. Water absorption, apparent porosity, bulk density, and compressive strength were tested. The test result shows that 5 wt.% of RS incorporation to fly ash-based geopolymer is optimum as it has 1752 kg/m3 of density, 9.5% of water absorption, 19.2% of apparent porosity, and 49.9 MPa of compressive strength.
  • Publication
    Elevated-temperature performance, combustibility and fire propagation index of fly ash-metakaolin blend geopolymers with addition of monoaluminium phosphate (MAP) and aluminum dihydrogen triphosphate (ATP)
    ( 2021-04-02)
    Khairunnisa Zulkifly
    ;
    Heah Cheng Yong
    ;
    Liew Yun Ming
    ;
    Bayuaji R.
    ;
    Mohd. Mustafa Al Bakri Abdullah
    ;
    Ahmad S.B.
    ;
    Stachowiak T.
    ;
    Szmidla J.
    ;
    Gondro J.
    ;
    Jeż B.
    ;
    Khalid M.S.B.
    ;
    Garus S.
    ;
    Ong Shee-Ween
    ;
    Ooi Wan-En
    ;
    Ng Hui-Teng
    Thermal performance, combustibility, and fire propagation of fly ash-metakaolin (FAMK) blended geopolymer with the addition of aluminum triphosphate, ATP (Al(H2PO4)3), and monoaluminium phosphate, MAP (AlPO4) were evaluated in this paper. To prepare the geopolymer mix, fly ash and metakaolin with a ratio of 1:1 were added with ATP and MAP in a range of 0–3% by weight. The fire/heat resistance was evaluated by comparing the residual compressive strengths after the elevated temperature exposure. Besides, combustibility and fire propagation tests were conducted to examine the thermal performance and the applicability of the geopolymers as passive fire protection. Experimental results revealed that the blended geopolymers with 1 wt.% of ATP and MAP exhibited higher compressive strength and denser geopolymer matrix than control geopolymers. The effect of ATP and MAP addition was more obvious in unheated geopolymer and little improvement was observed for geopolymer subjected to elevated temperature. ATP and MAP at 3 wt.% did not help in enhancing the elevated-temperature performance of blended geopolymers. Even so, all blended geopolymers, regardless of the addition of ATP and MAP, were regarded as the noncombustible materials with negligible (0–0.1) fire propagation index.
      2  18
  • Publication
    Elevated-Temperature performance, combustibility and fire propagation index of Fly Ash-Metakaolin blend geopolymers with addition of Monoaluminium Phosphate (MAP) and Aluminum Dihydrogen Triphosphate (ATP)
    ( 2021)
    Khairunnisa Zulkifly
    ;
    Heah Cheng Yong
    ;
    Liew Yun Ming
    ;
    Ridho Bayuaji
    ;
    Mohd. Mustafa Al Bakri Abdullah
    ;
    Shamsul Bin Ahmad
    ;
    Tomasz Stachowiak
    ;
    Janusz Szmidla
    ;
    Joanna Gondro
    ;
    Bartłomiej Jeż
    ;
    Mohd Suhaimi Bin Khalid
    ;
    Sebastian Garus
    ;
    Ong Shee-Ween
    ;
    Ooi Wan-En
    ;
    Ng Hui-Teng
    Thermal performance, combustibility, and fire propagation of fly ash-metakaolin (FA-MK) blended geopolymer with the addition of aluminum triphosphate, ATP (Al(H2PO4)3), and monoaluminium phosphate, MAP (AlPO4) were evaluated in this paper. To prepare the geopolymer mix, fly ash and metakaolin with a ratio of 1:1 were added with ATP and MAP in a range of 0–3% by weight. The fire/heat resistance was evaluated by comparing the residual compressive strengths after the elevated temperature exposure. Besides, combustibility and fire propagation tests were conducted to examine the thermal performance and the applicability of the geopolymers as passive fire protection. Experimental results revealed that the blended geopolymers with 1 wt.% of ATP and MAP exhibited higher compressive strength and denser geopolymer matrix than control geopolymers. The effect of ATP and MAP addition was more obvious in unheated geopolymer and little improvement was observed for geopolymer subjected to elevated temperature. ATP and MAP at 3 wt.% did not help in enhancing the elevated-temperature performance of blended geopolymers. Even so, all blended geopolymers, regardless of the addition of ATP and MAP, were regarded as the noncombustible materials with negligible (0–0.1) fire propagation index.
      1  23
  • Publication
    Cold-pressed fly ash geopolymers: effect of formulation on mechanical and morphological characteristics
    ( 2021)
    Ong Shee-Ween
    ;
    Heah Cheng Yong
    ;
    Lynette Wei Ling Chan
    ;
    Mohd. Mustafa Al Bakri Abdullah
    ;
    Ho Li Ngee
    ;
    Liew Yun Ming
    ;
    Ooi Wan-En
    ;
    Ng Yong-Sing
    ;
    Nur Ain Jaya
    This research uses low alkali activator content and cold pressing technique for fly ash-based geopolymers formation under room temperature condition. The geopolymers were prepared using four different parameters: fly ash/alkali activator ratio, sodium hydroxide concentration, sodium silicate/sodium hydroxide ratio and pressing force. The results indicated that the compressive strength (114.2 MPa) and flexural strength (29.9 MPa) of geopolymers maximised at a fly ash/alkali activator ratio of 5.5, a 14 M sodium hydroxide concentration, a sodium silicate/sodium hydroxide ratio of 1.5 and a pressing force of 5 tons (pressing stress of 100.0 MPa and 155.7 MPa for compressive and flexural samples, respectively). The degree of reaction (40.1%) enhanced the structure compactness with minimum porosity. The improved mechanical properties confirmed that a high strength pressed geopolymer could be formed at low alkali activator content without the aid of temperature.
      1  36
  • Publication
    Evaluation of flexural properties and characterisation of 10-mm thin geopolymer based on fly ash and ladle furnace slag
    ( 2021)
    Ng Yong-Sing
    ;
    Liew Yun Ming
    ;
    Heah Cheng Yong
    ;
    Mohd. Mustafa Al Bakri Abdullah
    ;
    Lynette Wei Ling Chan
    ;
    Ng Hui-Teng
    ;
    Ong Shee-Ween
    ;
    Ooi Wan-En
    ;
    Hang Yong-Jie
    The formulation and flexural properties of thin fly ash geopolymers with thickness of merely 10 mm and replacement of ladle furnace slag to fly ash in thin geopolymer were presented. The formulation was discussed in terms of NaOH molarity, solid aluminosilicates-to-liquid alkali activator (S/L) mass ratio, and alkali activator (Na2SiO3/NaOH) mass ratio. Thin fly ash geopolymers with flexural strength and Young's modulus of 6.2 MPa and 0.14 GPa, respectively, were obtained by using 12 M NaOH, S/L ratio of 2.5 and Na2SiO3/NaOH ratio of 4.0. A high Na2SiO3/NaOH ratio was implemented for thin geopolymer synthesis to produce a more viscous slurry which helped to retain the shape of a thin geopolymer. The incorporation of ladle furnace slag up to 40 wt.% reported an increment of 26% in flexural strength up to 7.8 MPa as compared to pure fly ash geopolymers and the stiffness was increased to 0.19 GPa. Denser microstructure with improved compactness was observed as the ladle furnace slag acted as the filler. New crystalline phases of calcium silicate hydrate (C–S–H) were formed and coexisted with the geopolymer matrix, which consequently enhanced the flexural strength of thin fly ash geopolymer. This proved that the ladle furnace slag has the potential to be utilised in geopolymer synthesis and will enhance the flexural properties of thin geopolymers. The flexural performance of thin geopolymers in this study was considerably good as the thin geopolymers exhibited comparatively similar flexural strengths, but a higher strength/thickness ratio as compared to geopolymers with thickness greater than 40 mm.
      1  18
  • Publication
    Thin fly ash/ ladle furnace slag geopolymer: Effect of elevated temperature exposure on flexural properties and morphological characteristics
    ( 2022-06-15)
    Yong-Sing Ng
    ;
    Liew Yun Ming
    ;
    Heah Cheng Yong
    ;
    Mohd. Mustafa Al Bakri Abdullah
    ;
    Pakawanit P.
    ;
    Chan L.W.L.
    ;
    Ng Hui-Teng
    ;
    Ong Shee-Ween
    ;
    Ooi Wan-En
    ;
    Hang Yong-Jie
    The flexural properties and thermal performance of 10 mm-thin geopolymers made from fly ash and ladle furnace slag were evaluated before and after exposure to elevated temperatures (300 °C, 600 °C, 900 °C, 1100 °C and 1150 °C). Class F fly ash was mixed with liquid sodium silicate (Na2SiO3) and 12 M sodium hydroxide (NaOH) solution using aluminosilicate/activator ratio of 1:2.5 and Na2SiO3/NaOH ratio of 1:4 to synthesise thin fly ash (FA) geopolymers. 40 wt% of ladle furnace slag was partially replacing fly ash to produce fly ash/slag-based (FAS) geopolymers. Thermal treatment enhanced the flexural strength of thin geopolymers. In comparison to the unexposed specimen, the flexural strength of FA geopolymers at 1150 °C and FAS geopolymers 1100 °C was increased by 161.3% to 16.2 MPa and 208.9% to 24.1 MPa, respectively. A more uniform heating was achieved in thin geopolymers which favoured the phase transformation at high temperatures and contributed to the substantial increase in flexural strength. The joint effect of elevated temperature exposure and the incorporation of ladle furnace slag further improved the flexural strength of thin geopolymers. The calcium-rich slag refined the pore structure and increased the crystallinity of thin geopolymers which aided in high strength development.
      1
  • Publication
    Towards greener one-part geopolymers through solid sodium activators modification
    ( 2022-12-10)
    Ooi Wan-En
    ;
    Liew Yun Ming
    ;
    Heah Cheng Yong
    ;
    Ho Li Ngee
    ;
    Mohd. Mustafa Al Bakri Abdullah
    ;
    Bin Khalid M.S.
    ;
    Foo Kai Loong
    ;
    Ong Shee-Ween
    ;
    Pei Seng T.
    ;
    Hang Yong Jie
    ;
    Khairunnisa Zulkifly
    This paper investigates the influence of various solid activators and their mixing parameters on the physical, mechanical and microstructural characteristics of greener one-part geopolymers (OPG) based on high calcium fly ash. The high calcium fly ash that has rarely been explored was utilised to develop OPG in this study. The anhydrous sodium metasilicate (Na2SiO3) with negative environmental impact propelled the partial replacement of Na2SiO3 with sodium hydroxide (NaOH) and sodium carbonate (Na2CO3). Two sets of high calcium fly ash OPGs were developed: (1) the MH-OPG comprised Na2SiO3 and NaOH; (2) the MC-OPG comprised Na2SiO3 and Na2CO3. The optimal MH-OPG (73 MPa) and MC-OPG (75 MPa) exhibited superior compressive strength, higher than the minimal requirement (>28 MPa) of ASTM C150/C150M-18 for construction binder material. Various solid alkali activators triggered different reaction mechanisms, yielding distinctive reaction products that contributed to strength growth. The sodium calcium aluminosilicate hydrate ((N,C)-A-S-H) gel was developed in MH-OPG, whereas the sodium carbonate hydrate, sodium aluminosilicate hydrate (N-A-S-H) and calcium aluminosilicate hydrate (C-A-S-H) binding phases were developed in the MC-OPG. Although Na2CO3 reduced the water demand, improved the fluidity and setting time, the MC-OPG was more sensitive to the alteration of mixing compositions, suggesting a tougher performance control during field application than the MH-OPG. The total embodied carbon (EC) of MC-OPG was lowered by 15.4% compared to that of MH-OPG. The embodied carbon index (ECI) of MH-OPG and MC-OPG were 81.3% and 84.7% less than that of OPC products. This work suggests that substituting Na2SiO3 with NaOH or Na2CO3 effectively produced a greener construction material without compromising mechanical strength.
      1
  • Publication
    Effect of sodium aluminate on the fresh and hardened properties of fly ash-based one-part geopolymer
    ( 2021)
    Ooi Wan-En
    ;
    Liew Yun Ming
    ;
    Heah Cheng Yong
    ;
    Ho Li Ngee
    ;
    Mohd. Mustafa Al Bakri Abdullah
    ;
    Ong Shee-Ween
    ;
    Andrei Victor Sandu
    The one-part geopolymer binder was synthesis from the mixing of aluminosilicate material with solid alkali activators. The properties of one-part geopolymers vary according to the type and amount of solid alkali activators used. This paper presents the effect of various sodium metasilicate-to-sodium aluminate (NaAlO2/Na2SiO3) ratios on fly ash-based one-part geopolymer. The NaAlO2/Na2SiO3 ratios were set at 1.0 to 3.0. Setting time of fresh one-part geopolymer was examined through Vicat needle apparatus. Mechanical and microstructural properties of developed specimens were analysed after 28 days of curing in ambient condition. The study concluded that an increase in NaAlO2 content delayed the setting time of one-part geopolymer paste. The highest compressive strength was achieved at the NaAlO2/Na2SiO3 ratio of 2.5, which was 33.65 MPa. The microstructural analysis revealed a homogeneous structure at the optimum ratio. While the sodium aluminium silicate hydrate (N-A-S-H) and anorthite phases were detected from the XRD analysis.
      7  17
  • Publication
    Comparative mechanical and microstructural properties of high calcium fly ash one-part geopolymers activated with Na2SiO3-anhydrous and NaAlO2
    ( 2021-11-01)
    Ooi Wan-En
    ;
    Liew Yun Ming
    ;
    Heah Cheng Yong
    ;
    Mohd. Mustafa Al Bakri Abdullah
    ;
    Li L.Y.
    ;
    Ho Li Ngee
    ;
    Foo Kai Loong
    ;
    Ong Shee-Ween
    ;
    Ng Hui-Teng
    ;
    Ng Yong-Sing
    ;
    Nur Ain Jaya
    This paper investigates the effect of varying solid alkali activators on the fresh and hardened properties and microstructural changes of one-part geopolymers (OPGs). Single and binary solid alkali activators were used to activate high calcium fly ash. The alkali activators were either solely sodium metasilicate (Na2SiO3) or a combination of sodium aluminate (NaAlO2) and sodium metasilicate (Na2SiO3). The OPG activated with anhydrous Na2SiO3 achieved an excellent 28-day compressive strength of 83.6 MPa while OPG activated with NaAlO2 and Na2SiO3 attained a compressive strength of 45.1 MPa. The Na2SiO3-activated OPG demonstrated better fluidity than the OPG activated with NaAlO2 and Na2SiO3 due to the thixotropic behaviour caused by the NaAlO2. The Na2SiO3-activated OPG consisted of sodium-calcium aluminium silicate hydrate ((N,C)-A-S-H) gel phase, while the OPG activated with NaAlO2 and Na2SiO3 comprised of the coexistence of sodium aluminium silicate hydrate (N-A-S-H) and calcium aluminium silicate hydrate (C-A-S-H) gel phases. Regardless of the distinctive properties, the OPGs are adequate for building materials applications.
      2
  • Publication
    Effect of phosphate addition on room-temperature-cured fly ash-metakaolin blend geopolymers
    ( 2021-02-08)
    Khairunnisa Zulkifly
    ;
    Heah Cheng Yong
    ;
    Liew Yun Ming
    ;
    Mohd. Mustafa Al Bakri Abdullah
    ;
    Ong Shee-Ween
    ;
    Khalid M.S.B.
    This paper details the influence of NaOH concentration, solid-to-liquid (S/L) and sodium silicate-to-sodium hydroxide (Naâ‚‚SiO3/NaOH) ratios, and the role of aluminum phosphate on the compressive strength development of the fly ash-metakaolin (FA-MK) blend geopolymer. The blended geopolymer was prepared with FA: MK at a ratio of 1:1, activated with a sodium-based alkali activator and then cured at room temperature. The optimum FA-MK blend geopolymer was formulated using a 10 M NaOH solution, a S/L ratio of 1.2, and a Naâ‚‚SiO3/NaOH ratio of 2.6. Monoaluminium phosphate (MAP) and aluminum dihydrogen triphosphate (ATP) were added as the source of aluminium phosphate. The FA-MK blend geopolymers have compressive strengths of 63.7 MPa and 55.5 MPa after being cured for 28 days with the addition of 1 wt% of MAP and ATP, respectively. The strength enhancement was assumed to be dictated by the formation of a matrix with a higher cross-linking geopolymer framework. The microstructure of blend geopolymer with MAP and ATP was smoother and compact compared to those without phosphate addition. In comparison, MAP addition in blend geopolymer yielded better physical and mechanical properties.
      1  26