Now showing 1 - 9 of 9
  • Publication
    Fabrication, performance evaluation, and optimisation of adsorptive ammonia removal using hollow fibre ceramic membrane: Response surface methodology approach
    ( 2021-03-01)
    Mohd Ridhwan Adam
    ;
    Mohd Hafiz Dzarfan Othman
    ;
    Siti Hamimah Sheikh Abdul Kadir
    ;
    Mohd Hafiz Puteh
    ;
    ;
    Nik Abdul Hadi Md Nordin
    ;
    Mohd Azri Ab Rani
    ;
    Azeman Mustafa
    ;
    Mukhlis A. Rahman
    ;
    Juhana Jaafar
    This work aims to optimise the factors that affect the adsorptive removal of ammonia by natural zeolite hollow fibre ceramic membrane (HFCM) in a continuous crossflow system using surface response methodology (RSM). The adsorptive HFCM was first characterised using the scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy prior to the adsorption process. A face-centred central composite design (CCD) was used to statistically visualise the interaction of the factors, namely feed pH, feed concentration, and HFCM dosage, with the response of water permeability and ammonia removal of the HFCM. The optimum conditions for the HFCM performance were feed pH of 7.04, feed concentration of 75.00 mg/L, and HFCM dosage of 0.35 g, with a desirability value of 0.953. The excellent ammonia removal performance (96.5%) reveals that the HFCM possesses great potential to be developed as a synergised system that combines the adsorption and filtration of water.
  • Publication
    Effects of temperature on rice husk silica ash additive for fouling mitigation by polysulfone–RHS ash mixed-matrix composite membranes
    ( 2020-08-01)
    Alias S.S.
    ;
    Harun Z.
    ;
    Manoh N.
    ;
    Abstract: It has been found that the preparation of green silica based on agricultural crops preserves environmental sustainability. In this study, rice husk silica (RHS) ash was prepared by burning rice husk (RH) at different temperatures (400 and 1200 Â°C). Both types of green RHS ash additives were blended with polysulfone dope, after which membranes were fabricated via phase inversion. The RHS ash that was synthesised at 400 Â°C (RHS400) had an amorphous structure with strong hydrophilic properties, while the composite membrane containing 3 wt% of RHS400 (A3 membrane) achieved the optimum properties of a dense top, an extended sub-layer of continuous smaller finger-like pores and a bottom layer of macrovoids. A satisfactory mean surface roughness, average pore size (1.90 ± 9.50 × 10−2 µm), porosity (40.66 ± 2.03%) and tensile strength (3.27 ± 0.16 MPa) were also obtained. The contact angle (52.5° ± 3.6°) further proved that this membrane was hydrophilic. The elemental and thermal analyses confirmed the presence of Si and O, which correlated with the 12% residual that was contributed by the silica inside the membrane. The optimum properties of the A3 membrane were an increased PWF (154.04 ± 7.70 L m−2 h−1) with the highest rejection of HA (96.00 ± 4.80%) and a fouling mitigation with the lowest internal resistance (6.79 ± 0.34 × 1012 m−1). Graphic abstract: [Figure not available: see fulltext.]
  • Publication
    Facial synthesis of colloidal stable magnetic nanoparticles coated with high hydrophilic negative charged poly(4-styrenesulfonic acid co-maleic acid) sodium for water remediation
    ( 2023-04-01)
    Lim C.C.
    ;
    ; ; ; ;
    Nasib A.M.
    ;
    Wicaksono S.T.
    ;
    Pramata A.D.
    ;
    Zullaikah S.
    The enhancement of the colloidal stability of magnetite nanoparticles (MNPs) for environmental-related fields has greatly attracted researchers' attention. This study used a high hydrophilic negatively charged polyelectrolyte, poly(4-styrenesulfonic acid co-maleic acid) sodium (PSAAS), to enhance the colloidal stability of MNPs. Coating of the naked MNPs with PSAAS polyelectrolyte is a simple and rapid method to obtain colloidally stable MNPs while sustaining the chemical reactivity of MNPs in water purification. The prepared PSAAS-coated MNPs were characterized by scanning electron microscope, energy dispersive X-ray, Fourier transform infrared, zeta potential analysis, transmission electron microscope and X-ray diffraction. Moreover, the colloidal stability and adsorption performance tests of these naked MNPs and PSAAS-coated MNPs (with different concentrations of PSAAS coated) were investigated and compared. PSAAS-coated MNPs with 0.001 g/ml PSAAS coating possessed the best colloidal stability and the highest methylene blue (MB) dye removal efficiency (94.53 ± 0.69%). The adsorption isotherm and kinetic studies for the adsorption of MB onto PSAAS-coated MNPs were well-described by the Langmuir model and pseudo-second-order kinetic model. These magnetic adsorbents, with high separation efficiency, simple and low production cost and recyclable property, are promising as practicable adsorbents in water treatment.
  • Publication
    A novel bio-ceramic hollow fibre membrane based hydroxyapatite derived from Tilapia fish bone for hybrid arsenic separation/adsorption from water
    ( 2023-01-01)
    Hubadillah S.K.
    ;
    ;
    Othman M.H.D.
    ;
    Adam M.R.
    This paper describes for the first time the synthesis of hydroxyapatite based on bio-ceramic hollow fiber membrane originating from Tilapia fish bones (bio-CHFM/HApT). Prior to the fabrication process, Tilapia fish bones were converted into hydroxyapatite powder by simple calcination method. A well-known method of membrane fabrication; a combination of phase inversion and sintering technique has been used. The study revealed that an exceptional asymmetric structure comprised of desired finger-like and sponge-like structure was induced by the bio-CHFM/HApT. Interestingly, bio-CHFM/HApT sintered at 1100 °C can induced hybrid adsorption/separation for As(III) removal at separation efficiency up to 99.9% and high flux of ∼250 kg/m2h. Additionally, the equilibrium adsorption capacities were obtained within 40 min of contact time. The kinetic information of the removal of As(III) bio-CHFM/HApT is the most suitable for pseudo-first order.
  • Publication
    Parameters adjustments for facile synthesis of high magnetization iron oxide nanoparticles from natural sand
    ( 2024-02-01)
    Wahfiudin A.
    ;
    Pramata A.D.
    ;
    Wicaksono S.T.
    ;
    ; ; ; ;
    This study explores the synthesis of Superparamagnetic Iron Oxide Nanoparticles (SPIONs) by leveraging natural iron sand and steel wool as primary raw materials within the co-precipitation method, which reduces the cost of production compared to the commercial counterparts. The research systematically investigated the influence of the diethylamine percentage, annealing time and annealing temperature on the SPIONs’ synthesis from natural iron sand by the co-precipitation method. Fe3O4 with varying crystallite sizes, ranging from 11.5 to 14.7 nm, were confirmed. SEM highlighted the nanoparticle agglomeration, a concern addressable through surface modification techniques, as further emphasized by TEM, which confirmed the nano-scale dimensions. Magnetic saturation values were confirmed by VSM, ranging from 37 to 51 emu/g. These values established the superparamagnetic behavior, rendering the nanoparticles suitable for versatile applications. The study identifies a potential threshold effect of the diethylamine concentration on the magnetic saturation and suggests an optimum annealing temperature for energy efficiency. This research contributes valuable insights into harnessing natural iron sand for SPION synthesis, advancing cost-effective and sustainable approaches in nanomaterial development, while emphasizing the importance of parameter customization for producing high-quality SPIONs.
  • Publication
    The Route of Hydrothermal Synthesis Zeolite-A from the Low-Grade Perak kaolin, Malaysia
    ( 2022-08-01)
    Sazali N.
    ;
    Harun Z.
    ;
    Abdullahi T.
    ;
    Kamarudin N.H.
    ;
    Sazali N.
    ;
    ;
    Hubadillah S.K.
    ;
    Alias S.S.
    Zeolite A was successfully synthesized using Perak kaolin which acts as the main source of silica and alumina. The process of beneficiation was conducted on raw kaolin to remove the impurities that existed in natural kaolin and also to increase the physical and chemical characteristic of kaolin. The kaolin was continued to be heated in the furnace with the temperature of 6000C for 4 h which described as a metakaolinization process that transformed it into the amorphous stage. The raw kaolin was characterized by XRD, FESEM, FTIR, PSA, TGA, while metakaolin by XRD, FESEM and FTIR. The mixture of zeolite A was achieved by adding the metakaolin into sodium hydroxide (NaOH) solution without adding other sources of silica and alumina. The solution mixture was stirred for 24 h before undergoing the process of hydrothermal synthesis. Two optimum conditions were studied for Zeolite A synthesizing, which were different molarity of sodium hydroxide and crystallizations time during the hydrothermal process. The successful synthesis of Zeolite A was then characterized by XRD, FESEM, FTIR, PSA, and BET surface area. The BET surface area of Zeolite-A is higher, 5.26 m2/g, compared to natural zeolite, 2.9 m2/g. As demonstrated in this work, Perak kaolin which was successfully synthesized into Zeolite-A with 2 M NaOH and 12-h crystallization time, gave a higher crystallinity percentage, 72.97%. The results obtained revealed that formation The of zeolite A has been highly affected by the NaOH molarity and crystallization time used in the combination of reactions.
  • Publication
    Application of natural zeolite clinoptilolite for the removal of ammonia in wastewater
    ( 2023-01-01)
    Adam M.R.
    ;
    Othman M.H.D.
    ;
    Hubadillah S.K.
    ;
    Abd Aziz M.H.
    ;
    This work intends the characterization of the natural zeolite clinoptilolite and its capability in removing the ammonia in wastewater. The natural zeolite clinoptilolite was characterized using transmittance electron microscopy (TEM), X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, X-ray fluorescence (XRF) and zeta potential prior to the adsorption process. The results showed that the natural zeolite clinoptilolite possessed the lamellar and needle-like structure thus giving the highest surface area for effective adsorption. The main constituent of the element consisted of natural zeolite clinoptilolite is known to have a high affinity towards ammonia. Additionally, the zeta potential analysis has shown that natural zeolite clinoptilolite is negatively charged in all media pH with the highest negative potential of −30 mV recorded at pH 7 thus, contributing to the highly effective electrostatic interaction with the contaminants’ cations. Consequently, the excellent performance in removing ammonia of up to 82.97 % has revealed that the natural zeolite clinoptilolite has a great potential to be developed as a synergized adsorptive ceramic membrane that is combining the adsorption and the filtration of water simultaneously.
  • Publication
    Novel hydroxyapatite-based bio-ceramic hollow fiber membrane derived from waste cow bone for textile wastewater treatment
    ( 2020-01-01)
    Hubadillah S.K.
    ;
    Othman M.H.D.
    ;
    Tai Z.S.
    ;
    ;
    Yusuf N.K.
    ;
    Ahmad AA.
    ;
    Rahman M.A.
    ;
    Jaafar J.
    ;
    Kadir S.H.S.A.
    ;
    Harun Z.
    Industrial textile wastewater is toxic due to the presence of recalcitrant color pigments and poisonous heavy metals. In this study, the hydroxyapatite (HAp)-based bio-ceramic hollow fiber membranes (h-bio-CHFM) were developed via the combined phase inversion and sintering technique. It was found that the properties of the developed h-bio-CHFMs were greatly affected by the HAp content of the ceramic suspension, and sintering temperature. The h-bio-CHFM with the sintering temperature of 1200 °C exhibited the long rod-shaped HAp particles and the smallest pore size (0.013 μm). High removals of color (99.9%), COD (80.1%), turbidity (99.4%) and conductivity (30.1%) were achieved using the h-bio-CHFM sintered at 1200 °C with stable high flux of 88.3 L/m2h. Remarkably, the h-bio-CHFM sintered in the temperature range of 1000–1200 °C also demonstrated excellent adsorption ability towards heavy metals with 100% removals. The results of this study show the potential of the h-bio-CHFM for the efficient industrial textile wastewater treatment applications.
  • Publication
    Novel ceramic hollow fibre membranes contactor derived from kaolin and zirconia for ammonia removal and recovery from synthetic ammonia
    ( 2021-11-15)
    Pauzan M.A.B.
    ;
    Hubadillah S.K.
    ;
    Mohamad Kamal S.N.E.A.
    ;
    Othman M.H.D.
    ;
    Puteh M.H.
    ;
    Kurniawan T.A.
    ;
    Abu Bakar S.
    ;
    Abdullah H.
    ;
    ;
    Naim R.
    ;
    Sheikh Abdul Kadir S.H.
    The adverse effects of ammonia found in wastewater streams lead to the development of advanced water treatment technology, i.e. membrane contactor (MC). In this study, single layer hollow fibre membrane (SLZK) and dual layer hollow fibre membrane (DLZK) were prepared from zirconia and kaolin and modified into hydrophobic membrane through simple grafting process via fluoroalkylsilane (FAS) agent. The properties of membranes such as morphology, surface roughness, mechanical strength, wettability and liquid entry pressure were analysed through scanning electron microscopy (SEM), atomic force microscopy (AFM), 3-point bending strength, contact angle and LEPw setup. Finally, the performance of the membranes was also investigated towards ammonia removal via membrane contactor system. Our findings showed that hydrophobicity properties significantly improved for both SLZK and DLZK membranes after grafting modification process as indicated by the increase of contact angle value from 5° and 1° to 132.7° and ~180.0° respectively. Based on the morphological analysis, the surface of DLZK showed more porous structure as compared to the SLZK. In addition, DLZK also displayed the highest mechanical strength and contact angle reading of 125 MPa and ~180° respectively. This suggests that the DLZK showed an excellent membrane contactor performance with highest value of mass transfer coefficient (3.77 x 10-5 ms-1) and almost complete removal of ammonia removal (91%). Overall, these results implied that dual layer ceramic membrane developed from kaolin and zirconia could provide the basis for the development of alternative ceramic membrane with excellent properties for membrane contactor system.