Now showing 1 - 10 of 15
  • Publication
    Improving flexural and dielectric properties of carbon fiber epoxy composite laminates reinforced with carbon nanotubes interlayer using electrospray deposition
    ( 2020)
    Muhammad Razlan Zakaria
    ;
    Hazizan Md Akil
    ;
    ; ;
    Aslina Anjang Ab Rahman
    ;
    Muhammad Bisyrul Hafi Othman
    The electrospray deposition method was used to deposit carbon nanotubes (CNT) onto the surfaces of woven carbon fiber (CF) to produce woven hybrid carbon fiber–carbon nanotubes (CF–CNT). Extreme high-resolution field emission scanning electron microscopy (XHR-FESEM), X-ray diffraction (XRD), Raman spectroscopy and Fourier transform infrared spectroscopy (FT-IR) were used to analyze the woven hybrid CF–CNT. The results demonstrated that CNT was successfully and homogenously distributed on the woven CF surface. Woven hybrid CF–CNT epoxy composite laminates were then prepared and compared with woven CF epoxy composite laminates in terms of their flexural and dielectric properties. The results indicated that the flexural strength, flexural modulus and dielectric constant of the woven hybrid CF–CNT epoxy composite laminates were improved up to 19, 27 and 25%, respectively, compared with the woven CF epoxy composite laminates.
  • Publication
    Enhancement of tensile properties of glass fibre epoxy laminated composites reinforced with carbon nanotubes interlayer using electrospray deposition
    ( 2021)
    Muhammad Razlan Zakaria
    ;
    ;
    Hazizan Md Akil
    ;
    Muhammad Bisyrul Hafi Othman
    ;
    The introduction of carbon nanotubes (CNTs) onto glass fibre (GF) to create a hierarchical structure of epoxy laminated composites has attracted considerable interest due to their merits in improving performance and multifunctionality. Field emission scanning electron microscopy (FESEM) was used to analyze the woven hybrid GF-CNT. The results demonstrated that CNT was successfully deposited on the woven GF surface. Woven hybrid GF-CNT epoxy laminated composites were then prepared and compared with woven GF epoxy laminated composites in terms of their tensile properties. The results indicated that the tensile strength and tensile modulus of the woven hybrid GF-CNT epoxy laminated composites were improved by up to 9% and 8%, respectively compared to the woven hybrid GF epoxy laminated composites.
  • Publication
    The effect of synthesis parameter On HKUST-1 nanocomposites studied by FTIR characterisation and mechanical testing
    ( 2024-12)
    Syazwana Ahmad
    ;
    ; ; ; ;
    E. M. Mahdi
    ;
    Hazizan Md Akil
    ;
    Muhammad Hafiz Hassan
    ;
    Norlin Nosbi
    ;
    Nurfina Yudasari
    In the present work, Hong Kong University of Science and Technology (HKUST-1) has been synthesised at room temperature with 1:0, 1:1 and 0:1 ratio of ethanol and water and reinforced into polyurethane. In order to understand the impact of synthesis parameters on HKUST-1 nanocomposites, an investigation was conducted using FTIR characterisation and mechanical testing. The objective was to examine the potential improvement of the reinforced polymer. The mechanical testing results were shown to be significantly influenced by the presence of HKUST-1 with 1:0 ratio of ethanol and water (sample A) into polyurethane (PU). The samples underwent Fourier Transform Infrared Spectroscopy (FTIR) analysis to determine the types of bonds within the polymer-MOF nanocomposites. It was observed that the reinforced nanoparticles did not undergo any chemical changes, as indicated by the recorded spectra, which can be related to the overlapping characteristics of HKUST-1 and PU. The findings indicate that the A/PU exhibited a notable impact in comparison to other materials, as evidenced by the results of the tensile test and nanoindentation study.
      1  24
  • Publication
    Improving flexural and dielectric properties of carbon fiber epoxy composite laminates reinforced with carbon nanotubes interlayer using electrospray deposition
    ( 2020-01-01)
    Muhammad Razlan Zakaria
    ;
    Hazizan Md Akil
    ;
    ; ;
    Rahman, Aslina Anjang Ab
    ;
    Othman, Muhammad Bisyrul Hafi
    The electrospray deposition method was used to deposit carbon nanotubes (CNT) onto the surfaces of woven carbon fiber (CF) to produce woven hybrid carbon fiber-carbon nanotubes (CF-CNT). Extreme high-resolution field emission scanning electron microscopy (XHR-FESEM), X-ray diffraction (XRD), Raman spectroscopy and Fourier transform infrared spectroscopy (FT-IR) were used to analyze the woven hybrid CF-CNT. The results demonstrated that CNT was successfully and homogenously distributed on the woven CF surface. Woven hybrid CF-CNT epoxy composite laminates were then prepared and compared with woven CF epoxy composite laminates in terms of their flexural and dielectric properties. The results indicated that the flexural strength, flexural modulus and dielectric constant of the woven hybrid CF-CNT epoxy composite laminates were improved up to 19, 27 and 25%, respectively, compared with the woven CF epoxy composite laminates.
      2  1
  • Publication
    Influence of filler surface modification on static and dynamic mechanical responses of rice husk reinforced linear low-density polyethylene composites
    Filler surface modification has become an essential approach to improve the compatibility problem between natural fillers and polymer matrices. However, there is limited work that concerns on this particular effect under dynamic loading conditions. Therefore, in this study, both untreated and treated low linear density polyethylene/rice husk composites were tested under static (0.001 s–1, 0.01 s–1 and 0.1 s–1) and dynamic loading rates (650 s–1, 900 s–1 and 1100 s–1) using universal testing machine and split Hopkinson pressure bar equipment, respectively. Rice husk filler was modified using silane coupling agents at four different concentrations (1, 3, 5 and 7% weight percentage of silane) at room temperature. This surface modification was experimentally proven by Fourier transform infrared and Field emission scanning electron microscopy. Results show that strength properties, stiffness properties and yield behaviour of treated composites were higher than untreated composites. Among the treated composites, the 5% silane weight percentage composite shows the optimum mechanical properties. Besides, the rate of sensitivity of both untreated and treated composites also shows great dependency on strain rate sensitivity with increasing strain rate. On the other hand, the thermal activation volume shows contrary trend. For fracture surface analysis, the results show that the treated LLDPE/RH composites experienced less permanent deformation as compared to untreated LLDPE/RH composites. Besides, at dynamic loading, the fracture surface analysis of the treated composites showed good attachment between RH and LLDPE.
      1  16
  • Publication
    Nonisothermal kinetic degradation of Hybrid CNT/Alumina Epoxy Nanocomposites
    ( 2021)
    Muhammad Helmi Abdul Kudus
    ;
    Muhammad Razlan Zakaria
    ;
    ;
    Muhammad Bisyrul Hafi Othman
    ;
    Hazizan Md. Akil
    ;
    Marcin Nabiałek
    ;
    Bartłomiej Jeż
    ;
    Due to the synergistic effect that occurs between CNTs and alumina, CNT/alumina hybrid-filled epoxy nanocomposites show significant enhancements in tensile properties, flexural properties, and thermal conductivity. This study is an extension of previously reported investigations into CNT/alumina epoxy nanocomposites. A series of epoxy composites with different CNT/alumina loadings were investigated with regard to their thermal-degradation kinetics and lifetime prediction. The thermal-degradation parameters were acquired via thermogravimetric analysis (TGA) in a nitrogen atmosphere. The degradation activation energy was determined using the Flynn–Wall–Ozawa (F-W-O) method for the chosen apparent activation energy. The Ea showed significant differences at α > 0.6, which indicate the role played by the CNT/alumina hybrid filler loading in the degradation behavior. From the calculations, the lifetime prediction at 5% mass loss decreased with an increase in the temperature service of nitrogen. The increase in the CNT/alumina hybrid loading revealed its contribution towards thermal degradation and stability. On average, a higher Ea was attributed to greater loadings of the CNT/alumina hybrid in the composites.
      2  16
  • Publication
    Enhancement of mechanical and thermal properties of carbon fiber epoxy composite laminates reinforced with carbon nanotubes interlayer using electrospray deposition
    ( 2020)
    Muhammad Razlan Zakaria
    ;
    Hazizan Md Akil
    ;
    ;
    Muhammad Helmi Abdul Kudus
    ;
    Fatin Nur Amirah Mohd Sabri
    ;
    Carbon nanotubes (CNTs) was successfully deposited onto the surface of woven carbon fiber (CF) using the electrospray deposition method to produce a woven hybrid CF-CNT. The effect of voltage and spray times on the morphology of the woven hybrid CF-CNT have been studied. The voltage and spray time is crucial towards achieving a homogeneous CNT coating on the woven CF surface. The epoxy composite laminated with optimized woven hybrid CF-CNT and woven CF without the deposited CNTs were then prepared, and its tensile and thermal properties subsequently determined. The results showed that the woven hybrid CF-CNT epoxy composite laminates tensile strength increased by ~21%, its tensile modulus increased by ~37%, its interlaminar shear strength increased by ~25%, and its thermal conductivity increased by ~35% relative to that of the woven CF epoxy composite laminates.
      3  26
  • Publication
    Effect of aluminium powder on kaolin-based geopolymer characteristic and removal of Cu²⁺
    ( 2021)
    Nurliyana Ariffin
    ;
    ;
    Przemysław Postawa
    ;
    ;
    Mohd Remy Rozainy Mohd Arif Zainol
    ;
    Ramadhansyah Putra Jaya
    ;
    Agata Śliwa
    ;
    ;
    Jerzy J. Wysłocki
    ;
    Katarzyna Błoch
    ;
    Marcin Nabiałek
    This current work focuses on the synthesis of geopolymer-based adsorbent which uses kaolin as a source material, mixed with alkali solution consisting of 10 M NaOH and Na2SiO3 as well as aluminium powder as a foaming agent. The experimental range for the aluminium powder was between 0.6, 0.8, 1.0 and 1.2wt%. The structure, properties and characterization of the geopolymer were examined using X-Ray Diffraction (XRD), Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). Adsorption capacity and porosity were analysed based on various percentages of aluminium powder added. The results indicate that the use of aluminium powder exhibited a better pore size distribution and higher porosity, suggesting a better heavy metal removal. The maximum adsorption capacity of Cu2+ approached approximately 98%. The findings indicate that 0.8% aluminium powder was the optimal aluminium powder content for geopolymer adsorbent. The removal efficiency was affected by pH, adsorbent dosage and contact time. The optimum removal capacity of Cu2+ was obtained at pH 6 with 1.5 g geopolymer adsorbent and 4 h contact time. Therefore, it can be concluded that the increase in porosity increases the adsorption of Cu2+.
      4  17
  • Publication
    Enhancement of tensile properties of glass fibre epoxy laminated composites reinforced with carbon nanotubes interlayer using electrospray deposition
    ( 2022-01-01)
    Muhammad Razlan Zakaria
    ;
    ;
    Hazizan Md Akil
    ;
    Muhammad Bisyrul Hafi Othman
    ;
    The introduction of carbon nanotubes (CNTs) onto glass fibre (GF) to create a hierarchical structure of epoxy laminated composites has attracted considerable interest due to their merits in improving performance and multifunctionality. Field emission scanning electron microscopy (FESEM) was used to analyze the woven hybrid GF-CNT. The results demonstrated that CNT was successfully deposited on the woven GF surface. Woven hybrid GF-CNT epoxy laminated composites were then prepared and compared with woven GF epoxy laminated composites in terms of their tensile properties. The results indicated that the tensile strength and tensile modulus of the woven hybrid GF-CNT epoxy laminated composites were improved by up to 9% and 8%, respectively compared to the woven hybrid GF epoxy laminated composites.
      3  3
  • Publication
    Study of carbon nanotubes stability in different types of solvents for electrospray deposition method
    ( 2020-12-01)
    Zakaria, Muhammad Razlan
    ;
    ;
    Akil H.M.
    ;
    Electrospray deposition (ESD) required a dispersing agent that could form a stable suspension of solution for carbon nanotubes (CNT) deposition on the carbon fiber (CF). The N-methyl-2-pyrrolodone (NMP), dimethylformamide (DMF) and tetrahydrofuran (THF) solvents were investigated for dispersion of CNT. Based on the optical observation, zeta potential and UV-Vis spectroscopy, all findings indicate that the CNT dispersed in NMP has better dispersion and higher stability. Analysis by extreme high-resolution field emission scanning electron microscope (XHR-FESEM) shows the CNT was homogeneously distributed and covered the entire surface of the CF.
      2  16