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Liew Yun Ming
Preferred name
Liew Yun Ming
Official Name
Liew Yun Ming
Alternative Name
Yun-Ming, Liew
Liew, Y. M.
Yun Ming, Liew
Ming, Liew Yun
Liew, Yun Ming
Ming, L. Y.
Main Affiliation
Scopus Author ID
57204242778
Researcher ID
S-7164-2019
Now showing
1 - 10 of 18
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PublicationPrimary insights into the effects of organic pollutants and carbon-based cathode materials in a double chambered microbial fuel cell integrated electrocatalytic process( 2021-12-01)
;Yap K.L. ; ; ;Guo K. ; ;Oon Y.S. ;Thor S.H. ;Tan S.M.Teoh T.P.Cathode plays an important role on the oxygen reduction reaction (ORR) reactivity in the microbial fuel cell integrated electrocatalytic process for the effective degradation of organic pollutants. Comparative study of caffeine and phenol as the organic pollutants in the cathodic chamber was investigated in terms of removal efficiency and bioelectricity generation. Results revealed that the highest removal efficiency of phenol (96.89 ± 1.26%) and maximum power density (33.37 ± 4.62 mW m−2) were attained by copper (II) oxide loaded carbon felt (CuO/CF) cathode. Besides, the removal efficiency of phenol was nearly 12-fold higher (24.85 ± 1.36%) using CuO/CF cathode compared with that of caffeine (2.14 ± 0.36%) at the first 24 h. The effect of carbon-based cathode materials on the mineralization of caffeine in the cathodic chamber was evaluated using carbon felt (CF) and carbon plate (CP). Both CuO/CP and bare CP cathodes surpassed CuO/CF and bare CF cathodes in the chemical oxygen demand (COD) removal and bioelectricity generation. Higher crystallinity nature and electrical conductivity (3.57 × 105 Ω−1 m−1) of CP compared with that of amorphous structure and lower electrical conductivity of bare CF (3.33 × 104 Ω−1 m−1) contributed to higher ORR reactivity and efficient transport of electrons for bioelectricity generation. The COD removal efficiency of synthetic wastewater in the anodic chamber and bioelectricity generation of this integrated system were affected by the types of organic pollutants and carbon-based cathode materials in the cathodic chamber.1 -
PublicationCold-pressed fly ash geopolymers: effect of formulation on mechanical and morphological characteristics( 2021)
;Ong Shee-Ween ; ;Lynette Wei Ling Chan ; ; ; ;Ooi Wan-En ;Ng Yong-SingThis research uses low alkali activator content and cold pressing technique for fly ash-based geopolymers formation under room temperature condition. The geopolymers were prepared using four different parameters: fly ash/alkali activator ratio, sodium hydroxide concentration, sodium silicate/sodium hydroxide ratio and pressing force. The results indicated that the compressive strength (114.2 MPa) and flexural strength (29.9 MPa) of geopolymers maximised at a fly ash/alkali activator ratio of 5.5, a 14 M sodium hydroxide concentration, a sodium silicate/sodium hydroxide ratio of 1.5 and a pressing force of 5 tons (pressing stress of 100.0 MPa and 155.7 MPa for compressive and flexural samples, respectively). The degree of reaction (40.1%) enhanced the structure compactness with minimum porosity. The improved mechanical properties confirmed that a high strength pressed geopolymer could be formed at low alkali activator content without the aid of temperature.1 36 -
PublicationComparative study of dihydroxybenzene isomers degradation and bioelectricity generation using CuO as cathodic catalyst in double chambered microbial fuel cell( 2022-10-01)
;Yap Kea Lee ; ; ;Guo K. ; ;Thor Shen Hui ;Tan Sing MeiTeoh Tean PengA double chambered microbial fuel cell (MFC) showed enormous capacity in the simultaneous degradation of synthetic wastewater and dihydroxybenzene isomers (catechol, resorcinol and hydroquinone) and concurrently with bioelectricity generation. Operating parameter such as effect of catalyst on MFC system was evaluated using bare carbon plate and copper (II) oxide (CuO) loaded carbon plate as cathodes, respectively, in terms of chemical oxygen demand (COD) and dihydroxybenzene isomers removal efficiency, maximum voltage output and power density. Results revealed that the application of CuO loaded carbon plate was more effective in the COD removal of synthetic wastewater in the anodic chamber and degradation of dihydroxybenzene isomers in the cathodic chamber. Compared with the bare carbon plate as cathode, the COD removal efficiency of synthetic wastewater, removal rate of dihydroxybenzene isomers and maximum voltage output increased 20, 100 and 31 %, respectively, when CuO was applied as cathodic catalyst. Among the dihydroxybenzene isomers, hydroquinone exhibited the best performance in both absence and presence of catalyst in the MFC. The position of the substituent of hydroxyl groups possessed significant effect on the reaction rate, reactivity and conductivity of dihydroxybenzene isomers. Hydroquinone was more susceptible to be degraded than that of catechol and resorcinol due to its lower dipole moment which eased the bond cleavage. The intermediate products of degradation of catechol, resorcinol and hydroquinone were determined using gas chromatograph-mass spectrometer and the degradation pathways were proposed.1 -
PublicationTowards greener one-part geopolymers through solid sodium activators modification( 2022-12-10)
;Ooi Wan En ; ; ; ; ;Bin Khalid M.S. ; ;Ong Shee Ween ;Pei Seng T. ;Hang Yong JieKhairunnisa ZulkiflyThis paper investigates the influence of various solid activators and their mixing parameters on the physical, mechanical and microstructural characteristics of greener one-part geopolymers (OPG) based on high calcium fly ash. The high calcium fly ash that has rarely been explored was utilised to develop OPG in this study. The anhydrous sodium metasilicate (Na2SiO3) with negative environmental impact propelled the partial replacement of Na2SiO3 with sodium hydroxide (NaOH) and sodium carbonate (Na2CO3). Two sets of high calcium fly ash OPGs were developed: (1) the MH-OPG comprised Na2SiO3 and NaOH; (2) the MC-OPG comprised Na2SiO3 and Na2CO3. The optimal MH-OPG (73 MPa) and MC-OPG (75 MPa) exhibited superior compressive strength, higher than the minimal requirement (>28 MPa) of ASTM C150/C150M-18 for construction binder material. Various solid alkali activators triggered different reaction mechanisms, yielding distinctive reaction products that contributed to strength growth. The sodium calcium aluminosilicate hydrate ((N,C)-A-S-H) gel was developed in MH-OPG, whereas the sodium carbonate hydrate, sodium aluminosilicate hydrate (N-A-S-H) and calcium aluminosilicate hydrate (C-A-S-H) binding phases were developed in the MC-OPG. Although Na2CO3 reduced the water demand, improved the fluidity and setting time, the MC-OPG was more sensitive to the alteration of mixing compositions, suggesting a tougher performance control during field application than the MH-OPG. The total embodied carbon (EC) of MC-OPG was lowered by 15.4% compared to that of MH-OPG. The embodied carbon index (ECI) of MH-OPG and MC-OPG were 81.3% and 84.7% less than that of OPC products. This work suggests that substituting Na2SiO3 with NaOH or Na2CO3 effectively produced a greener construction material without compromising mechanical strength.1 -
PublicationMicrobial fuel cell for simultaneous caffeine removal and bioelectricity generation under various operational conditions in the anodic and cathodic chambers( 2022-02-01)
;Yap Kea L.ee ; ; ;Guo K. ; ;Oon Yoong Sin ;Thor Shen-Hui ;Tan Sing MeiTeoh Tean PengA series of studies of the effects of operational parameters including organic substrate loading concentration, initial caffeine concentration, circuit connection, external resistance and salinity were carried out to evaluate the optimal performance of a double chambered microbial fuel cell for the treatment of caffeine. The increment of organic substrate loading concentration at anode increased the maximum power density from 7.84 ± 0.59 to 14.18 ± 0.87 mW m−2 but deteriorated the removal efficiency of caffeine in which only half of the removal efficiency of caffeine attained at 72 h at 1.500 g L−1 acetate (46.28 ± 3.66 %) than that of 0.375 g L−1 (96.89 ± 0.48 %). Initial caffeine concentration of 20 mg L−1 (95.31 ± 1.83 %) achieved 2.40-fold higher removal efficiency of caffeine than that of 50 mg L−1 (39.58 ± 2.83 %) at 48 h as saturated caffeine molecules hindered the oxygen reduction reaction and thus, fewer hydroxyl radicals were produced for the decomposition of caffeine. An optimal external resistance of 1000 Ω exhibited the best performance in terms of pollutants removal efficiency and power generation than that of 500 and 5000 Ω. Sodium chloride concentration of 0.580 g L−1 produced the highest maximum power density of 11.78 ± 0.68 but reduced to 8.26 ± 0.41 mW m−2 at 0.696 g L−1 as high concentration of sodium ions caused dehydration of anodophilic cells which decreased the electron transfer ability of electrochemically active bacteria.1 -
PublicationTowards greener one-part geopolymers through solid sodium activators modification( 2022-12-10)
;Ooi Wan-En ; ; ; ; ;Bin Khalid M.S. ; ;Ong Shee-Ween ;Pei Seng T. ;Hang Yong JieKhairunnisa ZulkiflyThis paper investigates the influence of various solid activators and their mixing parameters on the physical, mechanical and microstructural characteristics of greener one-part geopolymers (OPG) based on high calcium fly ash. The high calcium fly ash that has rarely been explored was utilised to develop OPG in this study. The anhydrous sodium metasilicate (Na2SiO3) with negative environmental impact propelled the partial replacement of Na2SiO3 with sodium hydroxide (NaOH) and sodium carbonate (Na2CO3). Two sets of high calcium fly ash OPGs were developed: (1) the MH-OPG comprised Na2SiO3 and NaOH; (2) the MC-OPG comprised Na2SiO3 and Na2CO3. The optimal MH-OPG (73 MPa) and MC-OPG (75 MPa) exhibited superior compressive strength, higher than the minimal requirement (>28 MPa) of ASTM C150/C150M-18 for construction binder material. Various solid alkali activators triggered different reaction mechanisms, yielding distinctive reaction products that contributed to strength growth. The sodium calcium aluminosilicate hydrate ((N,C)-A-S-H) gel was developed in MH-OPG, whereas the sodium carbonate hydrate, sodium aluminosilicate hydrate (N-A-S-H) and calcium aluminosilicate hydrate (C-A-S-H) binding phases were developed in the MC-OPG. Although Na2CO3 reduced the water demand, improved the fluidity and setting time, the MC-OPG was more sensitive to the alteration of mixing compositions, suggesting a tougher performance control during field application than the MH-OPG. The total embodied carbon (EC) of MC-OPG was lowered by 15.4% compared to that of MH-OPG. The embodied carbon index (ECI) of MH-OPG and MC-OPG were 81.3% and 84.7% less than that of OPC products. This work suggests that substituting Na2SiO3 with NaOH or Na2CO3 effectively produced a greener construction material without compromising mechanical strength.1 -
PublicationEffect of sodium aluminate on the fresh and hardened properties of fly ash-based one-part geopolymer( 2021)
;Ooi Wan-En ; ; ; ; ;Ong Shee-WeenAndrei Victor SanduThe one-part geopolymer binder was synthesis from the mixing of aluminosilicate material with solid alkali activators. The properties of one-part geopolymers vary according to the type and amount of solid alkali activators used. This paper presents the effect of various sodium metasilicate-to-sodium aluminate (NaAlO2/Na2SiO3) ratios on fly ash-based one-part geopolymer. The NaAlO2/Na2SiO3 ratios were set at 1.0 to 3.0. Setting time of fresh one-part geopolymer was examined through Vicat needle apparatus. Mechanical and microstructural properties of developed specimens were analysed after 28 days of curing in ambient condition. The study concluded that an increase in NaAlO2 content delayed the setting time of one-part geopolymer paste. The highest compressive strength was achieved at the NaAlO2/Na2SiO3 ratio of 2.5, which was 33.65 MPa. The microstructural analysis revealed a homogeneous structure at the optimum ratio. While the sodium aluminium silicate hydrate (N-A-S-H) and anorthite phases were detected from the XRD analysis.7 17 -
PublicationComparative mechanical and microstructural properties of high calcium fly ash one-part geopolymers activated with Na2SiO3-anhydrous and NaAlO2( 2021-11-01)
;Ooi Wan-En ; ; ; ;Li L.Y. ; ; ;Ong Shee-Ween ;Ng Hui-Teng ;Ng Yong-SingNur Ain JayaThis paper investigates the effect of varying solid alkali activators on the fresh and hardened properties and microstructural changes of one-part geopolymers (OPGs). Single and binary solid alkali activators were used to activate high calcium fly ash. The alkali activators were either solely sodium metasilicate (Na2SiO3) or a combination of sodium aluminate (NaAlO2) and sodium metasilicate (Na2SiO3). The OPG activated with anhydrous Na2SiO3 achieved an excellent 28-day compressive strength of 83.6 MPa while OPG activated with NaAlO2 and Na2SiO3 attained a compressive strength of 45.1 MPa. The Na2SiO3-activated OPG demonstrated better fluidity than the OPG activated with NaAlO2 and Na2SiO3 due to the thixotropic behaviour caused by the NaAlO2. The Na2SiO3-activated OPG consisted of sodium-calcium aluminium silicate hydrate ((N,C)-A-S-H) gel phase, while the OPG activated with NaAlO2 and Na2SiO3 comprised of the coexistence of sodium aluminium silicate hydrate (N-A-S-H) and calcium aluminium silicate hydrate (C-A-S-H) gel phases. Regardless of the distinctive properties, the OPGs are adequate for building materials applications.2 -
PublicationRole of tin (IV) oxide as cathodic catalyst on wastewater treatment and bioelectricity generation in a baffled microbial fuel cell( 2023-01-01)
;Yap K.L. ; ;Guo K. ; ; ;Microbial fuel cell (MFC) has attracted extensive attentions over the past decade because it able to treat wastewater and generate bioelectricity concurrently. However, the development of cost-effective cathodic catalysts to enhance the oxygen reduction reaction was vital for practical implementation. The effect of cathodic catalyst of tin (IV) oxide (SnO2) on the removal of synthetic wastewater and power generation in a baffled MFC was explored. SnO2 was synthesized using tin (IV) pentahydrate and sodium hydroxide through a hydrothermal method. SnO2 was characterized using X-ray diffractometer before applied on the carbon plate (CP) to identify the phase composition and crystal structure, respectively. Results indicated that the chemical oxygen demand removal of synthetic wastewater was increased up to 18 % under the presence of SnO2. The application of SnO2 on CP has significantly increased the oxygen reduction reaction reactivity in the cathodic chamber.1 -
PublicationEffect of Sodium Aluminate on the Fresh and Hardened Properties of Fly Ash-Based One-Part Geopolymer( 2022-01-01)
;Ooi Wan En ; ; ; ; ;Ong Shee WeenSandu A.V.The one-part geopolymer binder was synthesis from the mixing of aluminosilicate material with solid alkali activators. The properties of one-part geopolymers vary according to the type and amount of solid alkali activators used. This paper presents the effect of various sodium metasilicate-to-sodium aluminate (NaAlO2/Na2SiO3) ratios on fly ash-based one-part geopolymer. The NaAlO2/Na2SiO3 ratios were set at 1.0 to 3.0. Setting time of fresh one-part geopolymer was examined through Vicat needle apparatus. Mechanical and microstructural properties of developed specimens were analysed after 28 days of curing in ambient condition. The study concluded that an increase in NaAlO2 content delayed the setting time of one-part geopolymer paste. The highest compressive strength was achieved at the NaAlO2/Na2SiO3 ratio of 2.5, which was 33.65 MPa. The microstructural analysis revealed a homogeneous structure at the optimum ratio. While the sodium aluminium silicate hydrate (N-A-S-H) and anorthite phases were detected from the XRD analysis.4 28