Now showing 1 - 8 of 8
  • Publication
    Geopolymer-based artificial aggregates: a review on methods of producing, properties, and improving techniques
    ( 2022)
    Mohammad Almadani
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    ; ;
    Rosnita Mohamed
    The depletion of aggregate-related natural resources is the primary concern of all researchers globally. Recent studies emphasize the significance of recycling and reusing various types of natural or by-product material waste from industry as a result of the building industry’s rising demand for aggregate as the primary component in concrete production. It has been demonstrated that the geopolymer system has exceptional features, such as high strength, superior durability, and greater resistance to fire exposure, making it a viable alternative to ordinary Portland Cement (OPC) concrete. This study will examine the present method utilized to generate artificial aggregate-based geopolymers, including their physical and mechanical properties, as well as their characterization. The production process of geopolymer derived from synthetic aggregates will be highlighted. In conjunction with the bonding of aggregates and the cement matrix, the interfacial transition zone (ITZ) is highlighted in this work as an additional important property to be researched in the future. It will be discussed how to improve the properties of geopolymers based on artificial aggregates. It has been demonstrated that cold bonding provides superior qualities for artificial aggregate while conserving energy during production. The creation of ITZ has a significant impact on the bonding strength between artificial aggregates and the cement matrix. Additionally, improvement strategies demonstrate viable methods for enhancing the quality of manufactured aggregates. In addition, other recommendations are discussed in this study for future work.
  • Publication
    Artificial lightweight aggregates made from pozzolanic material: A review on the method, physical and mechanical properties, thermal and microstructure
    ( 2022)
    Dickson Ling Chuan Hao
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    ;
    Marwan Kheimi
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    ; ;
    Dumitru Doru Burduhos Nergis
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    Hamzah Fansuri
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    Ratna Ediati
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    Rosnita Mohamed
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    As the demand for nonrenewable natural resources, such as aggregate, is increasing worldwide, new production of artificial aggregate should be developed. Artificial lightweight aggregate can bring advantages to the construction field due to its lower density, thus reducing the dead load applied to the structural elements. In addition, application of artificial lightweight aggregate in lightweight concrete will produce lower thermal conductivity. However, the production of artificial lightweight aggregate is still limited. Production of artificial lightweight aggregate incorporating waste materials or pozzolanic materials is advantageous and beneficial in terms of being environmentally friendly, as well as lowering carbon dioxide emissions. Moreover, additives, such as geopolymer, have been introduced as one of the alternative construction materials that have been proven to have excellent properties. Thus, this paper will review the production of artificial lightweight aggregate through various methods, including sintering, cold bonding, and autoclaving. The significant properties of artificial lightweight aggregate, including physical and mechanical properties, such as water absorption, crushing strength, and impact value, are reviewed. The properties of concrete, including thermal properties, that utilized artificial lightweight aggregate were also briefly reviewed to highlight the advantages of artificial lightweight aggregate.
  • Publication
    Waste material via geopolymerization for heavy-duty application: a review
    ( 2022)
    Marwan Kheimi
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    Ikmal Hakem Aziz
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    ;
    Mohammad Almadani
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    Due to the extraordinary properties for heavy-duty applications, there has been a great deal of interest in the utilization of waste material via geopolymerization technology. There are various advantages offered by this geopolymer-based material, such as excellent stability, exceptional impermeability, self-refluxing ability, resistant thermal energy from explosive detonation, and excellent mechanical performance. An overview of the work with the details of key factors affecting the heavy-duty performance of geopolymer-based material such as type of binder, alkali agent dosage, mixing design, and curing condition are reviewed in this paper. Interestingly, the review exhibited that different types of waste material containing a large number of chemical elements had an impact on mechanical performance in military, civil engineering, and road application. Finally, this work suggests some future research directions for the the remarkable of waste material through geopolymerization to be employed in heavy-duty application.
  • Publication
    Properties and morphology of fly ash based Alkali Activated Material (AAM) paste under steam curing condition
    ( 2022) ;
    Sh. Nur Syamimi Sy. Izman
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    ; ; ;
    Rosnita Mohamed
    This paper details the properties, microstructures, and morphologies of the fly ash-based alkali-activated material (AAM), also known as geopolymers, under various steam curing temperatures. The steam curing temperature result in subsequent high strengths relative to average curing temperatures. However, detailed studies involving the use of steam curing for AAM remain scarce. The AAM paste was prepared by mixing fly ash with an alkali activator consisting of sodium silicate (Na2SiO3) and sodium hydroxide (NaOH). The sample was steam cured at 50°C, 60°C, 70°C, and 80°C, and the fresh paste was tested for its setting time. The sample also prepared for compressive strength, density, and water absorption testings. It was observed that the fastest time for the fly ash geopolymer to start hardening was at 80°C at only 10 minutes due to the elevated temperature quickening the hydration of the paste. The compressive strength of the AAM increased with increasing curing time from 3 days to 28 days. The AAM’s highest compressive strength was 61 MPa when the sample was steam cured at 50°C for 28 days. The density of AAM was determined to be ~2122 2187 kg/m3 , while its water absorption was ~6.72-8.82%. The phase analyses showed the presence of quartz, srebrodolskite, fayalite, and hematite, which indirectly confirms Fe and Ca’s role in the hydration of AAM. The morphology of AAM steam-cured at 50°C showed small amounts of unreacted fly ash and a denser matrix, which resulted in high compressive strength.
  • Publication
    Optimization of NaOH Molarity, LUSI Mud/Alkaline Activator, and Na2SiO3/NaOH Ratio to produce lightweight aggregate-based geopolymer
    This paper presents the mechanical function and characterization of an artificial lightweight geopolymer aggregate (ALGA) using LUSI (Sidoarjo mud) and alkaline activator as source materials. LUSI stands for LU-Lumpur and SI-Sidoarjo, meaning mud from Sidoarjo which erupted near the Banjarpanji-1 exploration well in Sidoarjo, East Java, Indonesia on 27 May 2006. The effect of NaOH molarity, LUSI mud/Alkaline activator (LM/AA) ratio, and Na2SiO3/NaOH ratio to the ALGA are investigated at a sintering temperature of 950 °C. The results show that the optimum NaOH molarity found in this study is 12 M due to the highest strength (lowest AIV value) of 15.79% with lower water absorption and specific gravity. The optimum LUSI mud/Alkaline activator (LM/AA) ratio of 1.7 and the Na2SiO3/NaOH ratio of 0.4 gives the highest strength with AIV value of 15.42% with specific gravity of 1.10 g/cm3 and water absorption of 4.7%. The major synthesized crystalline phases were identified as sodalite, quartz and albite. Scanning Electron Microscope (SEM) image showed more complete geopolymer matrix which contributes to highest strength of ALGA produced.
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  • Publication
    Optimization of NaOH molarity, LUSI mud/alkaline activator, and Na₂SiO₃/NaOH ratio to produce lightweight aggregate-based geopolymer
    This paper presents the mechanical function and characterization of an artificial lightweight geopolymer aggregate (ALGA) using LUSI (Sidoarjo mud) and alkaline activator as source materials. LUSI stands for LU-Lumpur and SI-Sidoarjo, meaning mud from Sidoarjo which erupted near the Banjarpanji-1 exploration well in Sidoarjo, East Java, Indonesia on 27 May 2006. The effect of NaOH molarity, LUSI mud/Alkaline activator (LM/AA) ratio, and Na₂SiO₃/NaOH ratio to the ALGA are investigated at a sintering temperature of 950 °C. The results show that the optimum NaOH molarity found in this study is 12 M due to the highest strength (lowest AIV value) of 15.79% with lower water absorption and specific gravity. The optimum LUSI mud/Alkaline activator (LM/AA) ratio of 1.7 and the Na2SiO3/NaOH ratio of 0.4 gives the highest strength with AIV value of 15.42% with specific gravity of 1.10 g/cm3 and water absorption of 4.7%. The major synthesized crystalline phases were identified as sodalite, quartz and albite. Scanning Electron Microscope (SEM) image showed more complete geopolymer matrix which contributes to highest strength of ALGA produced.
      1  15
  • Publication
    Characterisation at the bonding zone between fly ash based Geopolymer Repair Materials (GRM) and Ordinary Portland Cement Concrete (OPCC)
    ( 2020)
    Warid Wazien Ahmad Zailani
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    Mohd Fadzil Arshad
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    Remy Rozainy Mohd Arif Zainol
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    Marcin Nabialek
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    Andrei Victor Sandu
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    Jerzy J. Wysłocki
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    Katarzyna BÅ‚och
    In recent years, research and development of geopolymers has gained significant interest in the fields of repairs and restoration. This paper investigates the application of a geopolymer as a repair material by implementation of high-calcium fly ash (FA) as a main precursor, activated by a sodium hydroxide and sodium silicate solution. Three methods of concrete substrate surface preparation were cast and patched: as-cast against ordinary Portland cement concrete (OPCC), with drilled holes, wire-brushed, and left as-cast against the OPCC grade 30. This study indicated that FA-based geopolymer repair materials (GRMs) possessed very high bonding strength at early stages and that the behavior was not affected significantly by high surface treatment roughness. In addition, the investigations using scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX) spectroscopy have revealed that the geopolymer repair material became chemically bonded to the OPC concrete substrate, due to the formation of a C–A–S–H gel. Fundamentally, the geopolymer network is composed of tetrahedral anions (SiO4)4− and (AlO4)5− sharing the oxygen, which requires positive ions such as Na+, K+, Li+, Ca2+, Na+, Ba2+, NH4+, and H3O+. The availability of calcium hydroxide (Ca(OH)2) at the surface of the OPCC substrate, which was rich in calcium ions (Ca2+), reacted with the geopolymer; this compensated the electron vacancies of the framework cavities at the bonding zone between the GRM and the OPCC substrate.
      8  14
  • Publication
    Metakaolin/sludge based geopolymer adsorbent on high removal efficiency of Cu2+
    ( 2022)
    Pilomeena Arokiasamy
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    ; ;
    Mohd Remy Rozainy Mohd Arif Zainol
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    ;
    Marwan Kheimi
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    Jitrin Chaiprapa
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    Andrei Victor Sandu
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    Petrica Vizureanu
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    ;
    Activated carbon (AC) has received a lot of interest from researchers for the removal of heavy metals from wastewater due to its abundant porous structure. However, it was found unable to meet the required adsorption capacity due to its amorphous structure which restricts the fundamental studies and structural optimization for improved removal performance. In addition, AC is not applicable in large scale wastewater treatment due its expensive synthesis and difficulty in regeneration. Thus, the researchers are paying more attention in synthesis of low cost geopolymer based adsorbent for heavy metal removal due its excellent immobilization effect. However, limited studies have focused on the synthesis of geopolymer based adsorbent for heavy metal adsorption by utilizing industrial sludge. Thus, the aim of this research was to develop metakaolin (MK) based geopolymer adsorbent with incorporation of two types of industrial sludge (S1 and S3) that could be employed as an adsorbent for removing copper (Cu2+) from aqueous solution through the adsorption process. The effects of varied solid to liquid ratio (S/L) on the synthesis of metakaolin/sludge based geopolymer adsorbent and the removal efficiency of Cu2+ by the synthesis adsorbent were studied. The raw materials and synthesized geopolymer were characterized by using x-ray fluorescence (XRF), x-ray diffraction (XRD), scanning electron microscope (SEM), fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET) and micro XRF. The concentration of Cu2+ before and after adsorption was determined by atomic absorption spectroscopy (AAS) and the removal efficiency was calculated. The experimental data indicated that the synthesized geopolymer at low S/L ratio has achieved the highest removal efficiency of Cu2+ about 99.62 % and 99.37 % at 25 %:75 % of MK/S1 and 25 %:75 % of MK/S3 respectively compared to pure MK based geopolymer with 98.56 %. The best S/
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