Nur Syakimah Ismail
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Preferred name
Nur Syakimah Ismail
Official Name
Nur Syakimah, Ismail
Alternative Name
Nur, Syakimah Ismail
Ismail, N. Syakimah
Ismail, Nur Syakimah Binti
Ismail, N. S.
Main Affiliation
Scopus Author ID
56402634600
Researcher ID
HKN-0608-2023

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  • Publication
    Electrochemiluminescence of carbon dots and nitrogen-doped carbon dots from a microwave-assisted method
    ( 2023-10)
    Nurul Izzati Akmal Mohd Azman
    ;
    Muhammad Amirul Afiq Abdul Halim
    ;
    Nur Syakimah Ismail
    ;
    Nur Hamidah Abdul Halim
    ;
    Nurjuliana Juhari
    ;
    Norhayati Sabani
    ;
    Siti Aisyah Shamsudin
    ;
    Eiichi Tamiya
    This research focuses on the use of carbon dots (CDs) and nitrogen-doped carbon dots (NCDs) synthesized using a microwave-assisted method as electrochemiluminescence (ECL) luminophores. CDs have been synthesized using citric acid, while various concentrations of nitrogen-doped CDs have been successfully obtained by varying the amount of urea from 1 to 3 g with citric acid to produce NCD1, NCD,2 and NCD3. The ECL mechanism of CDs and NCDs on screen-printed electrodes has been studied using cyclic voltammetry (CV). ECL emission from as-prepared CDs and NCDs was observed in PBS with potassium persulfate (K2S2O8) as a co-reactant. The addition of potassium chloride (KCl) as a supporting electrolyte displays fast electroreduction of CDs and K2S2O8 to expedite the generation of CDs and peroxydisulfate radicals that simultaneously increase ECL intensity. Furthermore, as the concentration of nitrogen-doped CDs increases, so does the intensity of the ECL. NCD3 shows the highest ECL intensity by an increment of 86.4% in comparison to CDs in PBS with the addition of K2S2O8 and KCl. Finally, optimization of ECL measurement was carried out in terms of CV potential range, concentration of luminophore, supporting electrolyte, and co-reactant using NCD3 luminophore. The CV potential range at 0 to -2 V shows 50 mV of early CV reverse onset potential that resulted in an increase of 52.9% ECL intensity. Meanwhile, 30x dilution of NCD3, 0.1 M of supporting electrolyte KCl, and 0.1 M of co-reactant K2S2O8 show the optimum value to obtain high ECL intensity.
  • Publication
    Electrochemical detection of heavy metal ions using gold nanoparticles on carbon dots extracted from curry leaves
    ( 2024-06)
    Nur Syakimah Ismail
    ;
    Aidil Safiy Kamarul Ariffin
    ;
    Nurul Izzati Akmal Mohd Azman
    ;
    Nur Hamidah Abdul Halim
    ;
    Norhayati Sabani
    ;
    Nurjuliana Juhari
    ;
    Siti Aisyah Shamsudin
    Carbon dots (CDs) have attracted attention due to their versatility in electronic and optical properties based on precursor and type of synthesis process. Recently, many researchers have focused on using natural resources or wastes to form CDs. Four samples of CDs have been synthesized from curry leaves using a microwave-assisted approach at heating powers of 700 and 800 V with durations of 5 and 8 minutes. UV-Vis and FTIR spectra reveal the existence of carbon graphitic elements with carboxyl and hydroxyl functional groups on the surfaces of CDs. CVs of AuNPs/CDs/GS electrodes in ferricyanide disclosed that as-synthesized CDs produced using a lower heating power of 700 W exhibit pronounced electrocatalytic activity with sluggish electron transfer kinetics. Conversely, as-synthesized CDs created with a higher heating power of 800 W demonstrate reduced electrocatalytic activity but rapid electron transfer kinetics. Electrochemical detection of Pb2+ ions was observed through a sharp peak around -0.42 to -0.438 V, while detection of Hg2+ ions was observed through two anodic peaks around +0.334 to +0.408 V during a forward scan in acetate buffer (pH 4.5) on AuNPs/CDs/GS electrodes when tested individually. These distinct peaks also appeared in mixture solutions, with a slight reduction in peak current density that suggests the selectivity of the AuNPs/CDs/GS electrodes towards Pb2+ and Hg2+ ion detection. The optimum AuNPs/CDs/GS electrode for sensitive and selective detection of Pb2+ and Hg2+ was recorded using CDs D as a functional supporting matrix for AuNPs that was synthesized using a heating power of 800 W for 8 minutes.
  • Publication
    Fabrication of Graphene Electrode via Graphene Transfer Method for Bisphenol A (BPA) Detection
    ( 2021-01-01)
    Shukri N.I.B.A.
    ;
    Norhayati Sabani
    ;
    Ruslinda A. Rahim
    ;
    Mohamad Faris Mohamad Fathil
    ;
    Syarifah Norfaezah Sabki
    ;
    Nur Hamidah Abdul Halim
    ;
    Nur Syakimah Ismail
    Exposure of BPA is a concern as BPA can seep into food or beverages from containers and can possibly effects on human health especially endocrine systems. An electrochemical-based aptasensor utilizing graphene was developed in detecting endocrine disrupting compound Bisphenol A (BPA, 4,4'-(propane-2,2-diyl) diphenol). The graphene modified electrode was developed via graphene transfer. Fabrication and characterization of graphene transfer was studied in this paper using Scanning Electron Microscopy (SEM) and High-Power Microscope (HPM). In this research, the investigation of interfacial characteristic modified graphene with aptasensor and recognition of BPA with aptasensor had been done using electrochemical impedance spectroscopy (EIS). The increment of charge transfer resistance (Rct) before and after recognition of BPA denoting the accumulation of charge at the electrode surface in this research.
  • Publication
    Effect of heating power towards synthesis of carbon dots through microwave pyrolysis method for optical-based biosensor
    ( 2020-01-08)
    Nur Syakimah Ismail
    ;
    Husain, Umi Shahirah
    ;
    Selvan S.
    ;
    Mordani, Nor Afnia
    ;
    Nurjuliana Juhari
    ;
    Nur Hamidah Abdul Halim
    This study focuses on the effect of heating power in producing carbon dots (CDs) using microwave-assisted pyrolysis from glucose and PEG-200. Glucose is one type of saccharide that contains carbon atom in their structure while PEG-200 is a polymer that acts as a stabilizer. Synthesis of CDs was carried out by using a domestic microwave at different heating power ranging from 300 to 600 Watts. Produced CDs were subjected to dilution, filtering and dialysis procedure for purification purpose. UV-Vis was carried out using PerkinElmer Lambda 35 Spectrophotometer to prove the present of carbon dots in the sample solution. Photoluminescence intensity was observed using Horiba FluoroLog Spectrophotometer together with Horiba iHR550 Imaging Spectrometer to show the emission wavelength and the emission color of CDs prepared. UV-Vis results show the present of CDs in each sample from absorption peaks in the range between 240 nm until 260 nm. The photoluminescence testing shows the emission wavelength of prepared CDs solution is around 430 nm to 570 nm which represent emission color of green-yellow luminescence. From this experiment, CDs that were prepared using a heating power of 450 Watt in 2 minutes and went through the filtering process produce the best luminescence properties. Prepared CDs display electrochemiluminescence (ECL) properties in the presence of co-reactant potassium peroxydisulfate using cyclic voltammetry to pave the way for optical-based biosensor application.
      13  1
  • Publication
    Optimization of gold nanoparticles electrodeposition duration on screen printed electrode to enhance electrochemiluminescence of nitrogen-doped carbon dots
    ( 2023-12)
    Nurul Izzati Akmal Mohd Azman
    ;
    Nur Syakimah Ismail
    ;
    Nur Hamidah Abdul Halim
    ;
    Nurjuliana Juhari
    ;
    Norhayati Sabani
    ;
    Toibah Abd Rahim
    ;
    Siti Aisyah Shamsudin
    ;
    Eiichi Tamiya
    In this work, the electrodeposition method was utilized to form gold nanoparticles on a carbon screen-printed electrode (SPE) using chronoamperometry at -0.4 V with various durations from 50 to 200 seconds. Scanning Electron Microscopy (SEM) images have proven that the electrodeposition method is capable of uniformly forming AuNPs on SPE (AuNPs- SPE). Apart from that, electrodeposition durations have increased the size of AuNPs by up to 66% based on average size measurements using ImageJ software. It can be observed that long electrodeposition durations permit the agglomeration of AuNPs on the electrode surface. The effect of electrodeposition duration on electrocatalytic performance in potassium ferricyanide and electrochemiluminescence (ECL) intensity of nitrogen-doped carbon dots (NCDs) was evaluated. Cyclic voltammetry (CV) of ferricyanide demonstrates that as the electrodeposition duration increases, AuNPs-SPE shows better electrochemical performance than bare SPE. ECL of NCDs displays that 100 s electrodeposition durations give the highest ECL intensity of 184% compared to bare SPE and have been chosen as the optimum parameter. The ECL mechanisms of bare SPE and AuNPs-SPE reveal that AuNPs- SPE has greater electrochemical and ECL performance than bare SPE, as evidenced by the CV of AuNPs-SPE having a faster reduction current, which rises to 87.2% ECL intensity and 510 mV faster ECL occurrence. These phenomena confirmed that the electrodeposition of AuNPs has improved the conductivity of SPE.
      6  3