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PublicationMetakaolin/sludge based geopolymer adsorbent on high removal efficiency of Cu2+( 2022)Activated carbon (AC) has received a lot of interest from researchers for the removal of heavy metals from wastewater due to its abundant porous structure. However, it was found unable to meet the required adsorption capacity due to its amorphous structure which restricts the fundamental studies and structural optimization for improved removal performance. In addition, AC is not applicable in large scale wastewater treatment due its expensive synthesis and difficulty in regeneration. Thus, the researchers are paying more attention in synthesis of low cost geopolymer based adsorbent for heavy metal removal due its excellent immobilization effect. However, limited studies have focused on the synthesis of geopolymer based adsorbent for heavy metal adsorption by utilizing industrial sludge. Thus, the aim of this research was to develop metakaolin (MK) based geopolymer adsorbent with incorporation of two types of industrial sludge (S1 and S3) that could be employed as an adsorbent for removing copper (Cu2+) from aqueous solution through the adsorption process. The effects of varied solid to liquid ratio (S/L) on the synthesis of metakaolin/sludge based geopolymer adsorbent and the removal efficiency of Cu2+ by the synthesis adsorbent were studied. The raw materials and synthesized geopolymer were characterized by using x-ray fluorescence (XRF), x-ray diffraction (XRD), scanning electron microscope (SEM), fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET) and micro XRF. The concentration of Cu2+ before and after adsorption was determined by atomic absorption spectroscopy (AAS) and the removal efficiency was calculated. The experimental data indicated that the synthesized geopolymer at low S/L ratio has achieved the highest removal efficiency of Cu2+ about 99.62 % and 99.37 % at 25 %:75 % of MK/S1 and 25 %:75 % of MK/S3 respectively compared to pure MK based geopolymer with 98.56 %. The best S/
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PublicationSolidification/Stabilization technology for radioactive wastes using cement: An appraisal( 2023)Across the world, any activity associated with the nuclear fuel cycle such as nuclear facility operation and decommissioning that produces radioactive materials generates ultramodern civilian radioactive waste, which is quite hazardous to human health and the ecosystem. Therefore, the development of effectual and commanding management is the need of the hour to make certain the sustainability of the nuclear industries. During the management process of waste, its immobilization is one of the key activities conducted with a view to producing a durable waste form which can perform with sustainability for longer time frames. The cementation of radioactive waste is a widespread move towards its encapsulation, solidification, and finally disposal. Conventionally, Portland cement (PC) is expansively employed as an encapsulant material for storage, transportation and, more significantly, as a radiation safeguard to vigorous several radioactive waste streams. Cement solidification/stabilization (S/S) is the most widely employed treatment technique for radioactive wastes due to its superb structural strength and shielding effects. On the other hand, the eye-catching pros of cement such as the higher mechanical strength of the resulting solidified waste form, trouble-free operation and cost-effectiveness have attracted researchers to employ it most commonly for the immobilization of radionuclides. In the interest to boost the solidified waste performances, such as their mechanical properties, durability, and reduction in the leaching of radionuclides, vast attempts have been made in the past to enhance the cementation technology. Additionally, special types of cement were developed based on Portland cement to solidify these perilous radioactive wastes. The present paper reviews not only the solidification/stabilization technology of radioactive wastes using cement but also addresses the challenges that stand in the path of the design of durable cementitious waste forms for these problematical functioning wastes. In addition, the manuscript presents a review of modern cement technologies for the S/S of radioactive waste, taking into consideration the engineering attributes and chemistry of pure cement, cement incorporated with SCM, calcium sulpho–aluminate-based cement, magnesium-based cement, along with their applications in the S/S of hazardous radioactive wastes.
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PublicationPrediction of pressuremeter modulus (E M) using GMDH neural network: a case study of Kenny Hill Formation( 2020-05-01)Soil investigation (SI) work is a process of collecting subsurface ground profile information in evaluating soil engineering properties for a construction project. The standard penetration method (SPT) is widely accepted worldwide as a feasible and relatively inexpensive method over other field tests. Pressuremeter test (PMT), on the other hand, is costly and more popular in situ method in interpreting soil deformation behavior. Considering SPT is available in almost site investigation works for all sizes of project, it was tempting to establish the correlation between SPT and PMT results, specifically in local geologic setting. The study was conducted in Kenny Hill Formation, Kuala Lumpur, Malaysia. The correlation established in this study is between pressuremeter modulus (EM) and SPT blow count (N60). In addition to in situ methods, the physical properties of soil extruded from boreholes were tested in geotechnical laboratories to determine soil properties, such as particle size distribution, liquid limit, and plastic limit. These parameters need to be considered during prediction of EM. Group method of data handling (GMDH) neural network has been used to achieve this objective. The mean absolute error (MAE) results show that the GMDH neural networks produce values of 8.04 and 8.59 for training and testing. The root mean square error (RMSE) yields 10.61 and 10.84 for training and testing, respectively. Further, the results of the coefficients of determination (R2) are 0.794 and 0.726 for training and testing demonstrates a good correlation exists between predicted and measured values. Based on the GMDH results, N60, sand, and clay are required input variables for determination of EM.
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PublicationPromoting a well-dispersion of MoO3 nanoparticles on fibrous silica catalyst via one-pot synthesis for enhanced photoredox environmental pollutants efficiency( 2022-12-01)The coexistence of pharmaceutical compounds and heavy metals in the aquatic environment has resulted in complications in the treatment process and thus, causing uproar among the citizens. The radical-based photocatalysis technology has aroused as an excellent method to eliminate both heavy metal and pharmaceutical compounds in the water. Herein, reported the utilization of the microemulsion technique for the preparation of nanoporous fibrous silica-molybdenum oxide (FSMo) towards simultaneous photocatalytic abatement of hexavalent chromium (Cr(VI)) and tetracycline (TC). The FESEM analysis showed the spherical morphology of the FSMo catalyst with dendrimeric silica fiber. The synthesized FSMo catalyst exhibited narrowed bandgap, high crystallinity, and well Mo element dispersion for enhanced photo-redox of Cr(VI) and TC. Remarkably, simultaneous remediation of the Cr(VI) and TC over FSMo demonstrated superior photocatalytic efficiency, 69% and 75%, respectively, than in the individual system, possibly due to the effective separation of photoinduced charges. The introduction of the Mo element to the silica framework via microemulsion technique demonstrated better dispersion of Mo compared to the incipient wetness impregnation method and thus, yielded higher photocatalytic activity towards simultaneous removal of TC and Cr(VI). Besides, quenching experiments revealed the electrons and holes as the active species that play a dominant role in the simultaneous photo-redox of Cr(VI) and TC. Lastly, the FSMo catalyst demonstrated high stability after four continuous cycles of simultaneous photocatalysis reactions, implying its potential as a suitable material for practical wastewater treatments.
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PublicationSulfur dioxide removal by calcium-modified fibrous KCC-1 mesoporous silica: kinetics, thermodynamics, isotherm and mass transfer mechanism( 2022-04-01)The removal of sulfur dioxide from industrial flue gas through dry flue gas desulfurization method commonly involves the use of adsorption process with porous sorbent. The efficiency of this process is highly dependent on the adsorption capacity and the adsorption rate of SO2 onto the sorbent materials. The use of KCC-1 mesoporous silica modified with calcium metal additives (Ca/KCC-1) in SO2 adsorption is examined in a fixed bed reactor system. The adsorption capacity of Ca/KCC-1 is found to be critically governed by the reaction temperature and inlet SO2 concentration where low values of both parameters are favorable to achieve the highest adsorption capacity of 3241.94 mg SO2/g sorbent. SO2 molecules are adsorbed on the surface of Ca/KCC-1 by both physisorption and chemisorption processes as assumed by the Avrami kinetic model. Thermodynamic study shows that the process is exothermic and spontaneous in nature, and changes from an ordered stage on the surface of KCC-1 towards an increasingly random stage. The process is well explained by Freundlich isotherm model indicating a slightly heterogeneous process and moderate adsorption capacity. The adsorption stage is limited by film diffusion at the initial stage and by intraparticle diffusion during the transfer of SO2 into the network of pores before adsorption takes place on the active sites.
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