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PublicationFly ash-based geopolymer lightweight concrete using foaming agent( 2012)In this paper, we report the results of our investigation on the possibility of producing foam concrete by using a geopolymer system. Class C fly ash was mixed with an alkaline activator solution (a mixture of sodium silicate and NaOH), and foam was added to the geopolymeric mixture to produce lightweight concrete. The NaOH solution was prepared by dilute NaOH pellets with distilled water. The reactives were mixed to produce a homogeneous mixture, which was placed into a 50 mm mold and cured at two different curing temperatures (60 °C and room temperature), for 24 hours. After the curing process, the strengths of the samples were tested on days 1, 7, and 28. The water absorption, porosity, chemical composition, microstructure, XRD and FTIR analyses were studied. The results showed that the sample which was cured at 60 °C (LW2) produced the maximum compressive strength for all tests, (11.03 MPa, 17.59 MPa, and 18.19 MPa) for days 1, 7, and 28, respectively. Also, the water absorption and porosity of LW2 were reduced by 6.78% and 1.22% after 28 days, respectively. The SEM showed that the LW2 sample had a denser matrix than LW1. This was because LW2 was heat cured, which caused the geopolymerization rate to increase, producing a denser matrix. However for LW1, microcracks were present on the surface, which reduced the compressive strength and increased water absorption and porosity.
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PublicationMechanical properties of Fly Ash-Based geopolymer concrete incorporation Nylon66 Fiber( 2022)This study was carried out to investigate the effect of the diamond-shaped Interlocking Chain Plastic Bead (ICPB) on fiber-reinforced fly ash-based geopolymer concrete. In this study, geopolymer concrete was produced using fly ash, NaOH, silicate, aggregate, and nylon66 fibers. Characterization of fly ash-based geopolymers (FGP) and fly ash-based geopolymer concrete (FRGPC) included chemical composition via XRF, functional group analysis via FTIR, compressive strength determination, flexural strength, density, slump test, and water absorption. The percentage of fiber volume added to FRGPC and FGP varied from 0% to 0.5%, and 1.5% to 2.0%. From the results obtained, it was found that ICBP fiber led to a negative result for FGP at 28 days but showed a better performance in FRGPC reinforced fiber at 28 and 90 days compared to plain geopolymer concrete. Meanwhile, NFRPGC showed that the optimum result was obtained with 0.5% of fiber addition due to the compressive strength performance at 28 days and 90 days, which were 67.7 MPa and 970.13 MPa, respectively. Similar results were observed for flexural strength, where 0.5% fiber addition resulted in the highest strength at 28 and 90 days (4.43 MPa and 4.99 MPa, respectively), and the strength performance began to decline after 0.5% fiber addition. According to the results of the slump test, an increase in fiber addition decreases the workability of geopolymer concrete. Density and water absorption, however, increase proportionally with the amount of fiber added. Therefore, diamond-shaped ICPB fiber in geopolymer concrete exhibits superior compressive and flexural strength.
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PublicationCharacterisation and evaluation of trimesic acid derivatives as disulphide cross-linked polymers for potential colon targeted drug delivery( 2017)Discovery and use of biocompatible polymers offers great promise in the pharmaceutical field, particularly in drug delivery systems. Disulphide bonds, which commonly occur in peptides and proteins and have been used as drug-glutathione conjugates, are reductively cleaved in the colon. The intrinsic stability of a disulphide relative to thiol groups is determined by the redox potential of the environment. The objective of this study was to synthesise a trimesic acid-based disulphide cross-linked polymer that could potentially be used for targeted delivery to the colon. The monomer was synthesised by an amide coupling reaction between trimesic acid and (triphenylmethyl) thioethylamine using a two-step synthesis method. The s-trityl group was removed using a cocktail of trifluoroacetic acid and triethylsilane to expose the thiols in preparation for further polymerisation. The resulting polymers (P10, P15, P21, P25, and P51, generated using different molar ratios) were reduced after 1.5 h of reduction time. Scanning electron microscopy images of the polymers showed spherical, loose, or tight patterns depending on the molar ratio of polymerisation. These polymers also exhibited efficient dissolution under various gastrointestinal conditions. Of the five polymers tested, P10 and P15 appeared to be promising drug delivery vehicles for poorly soluble drugs, due to the hydrophobic nature of the polymers.
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PublicationAnalysis of short time period of operation of horizontal ground heat exchangers( 2015)Ground source heat pump (GSHP) systems have been proven to have higher efficiency compared to conventional air source heat pump systems for space heating and cooling applications. While vertical ground heat exchangers (GHE) are favorable in GSHP installation, this type of configuration requires higher capital costs as opposed to horizontal configuration. Numerical simulation has been used to accurately predict the thermal performance of GHE. In this paper, numerical analysis of thermal performance for slinky horizontal GHE loops in different orientations and operation modes is discussed. It was found that the loop orientation is not so important due to the little effect it has on thermal performance. While the mean heat exchange rate of copper loop increases 48% compared to HDPE loop, the analysis supports the common claim that heat exchange rate is predominantly limited by the thermal conductivity of the ground. With the same amount of circulation work, the mean heat exchange rate increases by 83%–162% when operated in parallel loops operations. The performance in these operations can be further optimized to 10%–14% increase when spacing between adjacent loops was provided. The spacing helps to minimize interference of heat flow that would penalize the overall thermal performance.
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PublicationA proposed aerobic granules size development scheme for aerobic granulation process( 2015-04)Aerobic granulation is increasingly used in wastewater treatment due to its unique physical properties and microbial functionalities. Granule size defines the physical properties of granules based on biomass accumulation. This study aims to determine the profile of size development under two physicochemical conditions. Two identical bioreactors namely Rnp and Rp were operated under non-phototrophic and phototrophic conditions, respectively. An illustrative scheme was developed to comprehend the mechanism of size development that delineates the granular size throughout the granulation. Observations on granules’ size variation have shown that activated sludge revolutionised into the form of aerobic granules through the increase of biomass concentration in bioreactors which also determined the changes of granule size. Both reactors demonstrated that size transformed in a similar trend when tested with and without illumination. Thus, different types of aerobic granules may increase in size in the same way as recommended in the aerobic granule size development scheme.