In the present work, the effect of different sodium hydroxide (NaOH) molarity (6M, 8M, 10M, 12M and 14M) on the physical, mechanical and thermal conductivity of metakaolin geopolymers (MkGPs) was investigated. Geopolymers were prepared by activating the metakaolin with a mixture of NaOH with sodium silicate (Na2SiO3). The products obtained were characterized after 28 days of curing. The density, porosity, compressive strength and thermal conductivity (TC) were determined. In general, the NaOH molarity has a significant effect on the compressive strength of the MkGPs. The highest compressive strength was 14.6 MPa achieved with 10M of NaOH solution. The thermal conductivity of MkGPs measured in this work was low in the range between 0.71-0.97 W/mK. NaOH molarity had a significant effect on compressive strength but a marginal effect on thermal conductivity of MkGPs. The thermal conductivity was mainly affected by the bulk density and thus the total porosity. The
results showed that the geopolymer can be considered to be used as the thermal insulating material.