In this study, the electrospray deposition (esD) method was used to deposit carbon nanotubes (cNT) onto the surfaces of carbon fibers (cF) in order to produce hybrid carbon fiber-carbon nanotubes (cF-cNT) which is rarely reported in the past. extreme high-resolution field emission scanning electron microscopy (XHR-FeseM), high-resolution transmission electron microscopy (HRTeM) and x-ray photoelectron spectroscopy (XPs) were used to analyse the hybrid carbon fiber-carbon nanotube (cF-cNT). The results demonstrated that cNT was successfully and homogenously distributed on the cF surface. Hybrid cF-cNT was then prepared and compared with cF without cNT deposition in terms of their tensile properties. statistically, the tensile strength and the tensile modulus of the hybrid cF-cNT were increased by up to 3% and 25%, respectively, as compared to the cF without cNT deposition. The results indicated that the esD method did not cause any reduction of tensile properties of hybrid cF-cNT. based on this finding, it can be prominently identified some new and significant information of interest to researchers and industrialists working on cF based products.