This article presents the results of experimental work on the identification of reactive species produced by plasma discharge in liquid. The analysis was conducted using methylene blue (MB) as chemical probe. There are two objectives, 1) to identify the effect of ground electrode configuration to the presence of reactive species and 2) to observe the ground electrode durability. Results showed that, degradation of MB occurred when using 7 kV input supply and insulated ground electrode for 10 minutes. Meanwhile, the other input supply (7.8 kV and 8.6 kV) were unable to degrade MB solution.