In this work, the reflection measurement on animal and vegetable oils due to different heating temperature was conducted using Agilent E8362B slim probe in conjunction with Agilent E8362B PNA Network Analyzer. The effect of thermal degradation on measured reflection efficient (Γ) is investigated. Many chemical processes are occurred when edible oils are heated during frying process. The thermal degradation products, i.e., volatile and non-volatile chemical compounds are generated. The generated volatile chemical compounds are dangerous to human health. Products of thermal degradation of animal and vegetable oils can be carcinogenic. On the other hand, it may cause diabetes, atherosclerosis, Alzheimer’s and Parkinson’s diseases, coronary heart disease, sudden cardiac death, and systemic vasculitis. Slim probe and open ended coaxial sensor are implemented to measure the reflection coefficient of the cooking oils. The fresh animal fats and vegetable oils are commercially available in local market. Five types of cooking oil (i.e. corn oil, olive oil, palm oil, sunflower oil and walnut oil) were measured at the temperature of 60ºC, 80ºC and 100 ºC for the frequency range of 3 GHz to 8GHz. When the oil is subjected to thermal degradation during heating, the chemical chain of oil will be altered and resulting in physical and internal properties change. It is the key element that led to the variation of Γ. Γ is function of physical-chemical properties of cooking oil that implying the oil quality. In reflection measurement, there are different noticeable results which indicates the used and fresh cooking oil and the effect of heating period
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