Dye-sensitized solar cell (DSSC) has been studied widely due to its efficiency and the simplicity of manufacturing technology. Much research has been performed to improve the photovoltaic output parameters in DSSC by modifying the photoanode layers. The efforts to investigate DSSC mainly focus on how to increase light absorption, speed electron transport in circuits, and reduce charge recombination. This review discusses the process of charge recombination and the paths of occurrence in a DSSC. Recombination occurs when the electrons in the conduction band fall into the valance band holes and is considered an unnecessary process in DSSC. Due to the recombination process, the photocurrent and the photovoltage are reduced, leading to lower power conversion efficiency. Hence, the ways to overcome the charge recombination process were also discussed.