Conductive composite requires a well dispersion of conductive filler, which is this difficult to be achieved low content of filler for high density conductive filler. This work investigates the effect of carbon black and graphite on the morphology and conductive properties of conductive epoxy micro-porous. The conductive epoxy micro-porous was prepared by using single emulsion technique. It involved the drop of epoxy-hardener-blowing agent-conductive filler mixture into corn oil at 160 C and followed by the leaching process to remove excess corn oil. Results show the addition of conductive filler in epoxy matrix lead to increases porous structure in epoxy micro-porous. Carbon black filled epoxy micro-porous possessed smaller particles compared to graphite filled epoxy micro-porous. For skeleton density and total pore, both of the value increase with filler loading due to packing sphere effect. However, the skeleton density for carbon black filled epoxy micro-porous is higher compared to graphite filled epoxy micro-porous. For electrical conductivity, graphite filled micro-porous was higher than that of carbon black filled epoxy micro-porous.
