The moisture distribution in the silos depends upon various seeds parameters such as type and size of seeds, amount of storage, external weather, and storage period as well as structural and environmental factors. It is very difficult to predict moisture distribution in silos effectively while taking all the above aspects into consideration. This study aims to investigate the efficiency and accuracy of localization of moisture distributions sensing in agricultural silo. The work is mainly focussed on three major elements: Radio Frequency (RF), tomographic imaging and classification process using machine learning. In particular, RF-based signal and volume tomographic images are used to predict the moisture distribution. Furthermore, computational intelligence techniques such as artificial neural network (ANN) is applied to develop models based on previous data. The generalization of these models towards new set of data is discussed in making sure a successful application of a model. A detailed study of the relative performance of computational intelligence techniques has been carried out based on different statistical performance criteria.