Now showing 1 - 3 of 3
  • Publication
    Bio-Char And Bio-Oil Production From Pyrolysis of Palm Kernel Shell And Polyethylene
    In recent years, palm kernel shell (PKS) has become a viable feedstock for making biofuels and value-added commodities using a variety of thermal conversion routes. Therefore, significant conservation is required for PKS as a resource for fuel production in biofuel facilities. Thus, this research was intended to elucidate the effects on PKS as a solid fuel through torrefaction and the production of bio-char and bio-oil by single and co-pyrolysis of PKS and polyethylene (PE). The PKS was treated through torrefaction at different temperatures and holding times. The optimum parameters for torrefaction were a temperature of 250 oC and a holding time of 60 min. Then the PKS and PE were pyrolyzed in a fixed-bed reactor at different temperatures and ratios. The product yield was analysed for single and co-pyrolysis of PKS and PE for pyrolysis. The properties of the product composition for single and co-pyrolysis of the PKS and PE were determined by proximate analysis, Fourier transform infrared (FTIR) analysis, and gas chromatography-mass spectrometry (GC-MS). The optimum parameter obtained for biochar and bio-oil production from co-pyrolysis of PKS and PE was at temperature of 500 oC at a ratio of 1:2 (PKS: PE). The ester and phenol compounds were increased around 19.02 to 23.18% and 32.51 to 34.80 %, respectively, while amide and amine decreased around 4.94 to 18.87% and 0.63 to 32.39 %, respectively, compared to the single pyrolysis of PKS. Therefore, the PKS and PE co-pyrolysis significantly increased the amount of phenol and ester compounds while slightly reducing the amount of amide and amine compounds in the bio-oil product. As a conclusion, biomass conservation enables the manufacturing of value-added chemicals.
  • Publication
    Compatibilizers Effect on Recycled Acrylonitrile Butadiene Rubber with Polypropylene and Sugarcane Bagasse Composite for Mechanical Properties
    Compatibilizers effect on recycled acrylonitrile butadiene rubber (NBRr) with polypropylene (PP) and sugarcane bagasse (SCB) composite for mechanical properties is evaluated. Trans-Polyoctylene Rubber (TOR) and Bisphenol a Diglycidyl Ether (DGEBA) are used as compatibilizers in this study. Three (3) different composites (80/20/15, 60/40/15, and 40/60/15), with fixed filler (15 phr) and compatibilizers (10 phr) content, were carried out. These composites were arranged via melt mixing technique utilizing a heated two-roll mill at a temperature of 180 C for 9 minutes employing a 15-rpm rotor speed. Tensile and morphological properties were evaluated. The result shown average tensile strength dropped by 48.50% as the recycle NBR content rises 20 phr. Nevertheless, subsequent compatibilization reveals that the compositesâ tensile properties were all greater than control composites. The morphology discovered validates the tensile properties, indicating a stronger interaction between the PP/SCB and recycle NBR composites with the addition of compatibilizer DGEBA.
  • Publication
    Influence of pretreated coconut shell on gasification product yield
    Gasification of untreated and pretreated coconut shell (CS) was carried out in a fixed-bed reactor to assess the effect of temperature (600, 650, 700, 750, and 800 C) and holding time (30 and 40 min) on gases composition. The untreated CS was first torrefied in a fixed-bed reactor at different temperatures (200 â 300 C) and holding times (30 min, 60 min and 90 min). Pretreated CS at the optimal torrefaction temperature (275 C and 60 min) was used for gasification. Under optimal conditions of 750 C and 30 min holding time, gasification contributed the most gas production. At this optimum condition, the gas composition of pretreated CS was 35.03 % of CH4, 24.43 % of CO2, and 40.54 % of H2 + CO. Untreated CS contains 37.63 % of CH4, 24.03 % of CO2, and 38.34 % of H2 + CO gases. The production of CH4 gas was higher when untreated CS was used for gasification rather than pretreated CS. Moreover, when untreated CS was used for gasification, the amount of CO2, H2, and CO produced was minimal. Therefore, for high H2 production, pretreatment prior to gasification is appropriate.