Now showing 1 - 2 of 2
  • Publication
    Sulfur dioxide removal using deep eutectic solvent–functionalized palm kernel shell–activated carbon
    (Springer, 2025-02)
    Wan Nur Amanna Wan Nuzi
    ;
    Muhammad Adli Hanif
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    ; ; ; ;
    Raja Nazrul Hakim Raja Nazri
    ;
    The release of SOâ‚‚ into the atmosphere is concerning due to its role in acidification, which threatens living organisms and the environment. Adsorption processes using materials like chemically modified activated carbon (AC) have demonstrated strong potential for removing SOâ‚‚ before its release. This study evaluates the performance of AC derived from palm kernel shells, and AC functionalized with choline chloride-glycerol, a deep eutectic solvent (DES) (AC-DES), in removing SOâ‚‚ through breakthrough experiments conducted in a fixed bed reactor. AC and AC-DES achieved SOâ‚‚ adsorption capacities of 0.522 and 2.763 mg SOâ‚‚/g adsorbent, respectively. Characterization of the adsorbents indicated that DES functionalization significantly increased the number of active sites for SOâ‚‚ adsorption, leading to superior adsorption performance of AC-DES. The optimization of process parameters identified 40 Â°C and 1500 ppm inlet SOâ‚‚ concentration as the ideal conditions for optimal SOâ‚‚ adsorption. Experimental data fitted with three adsorption kinetic and isotherm models indicated that SOâ‚‚ adsorption onto AC-DES is best described by the Avrami kinetic model and the Sips isotherm model. Thermodynamics studies revealed that the process is exothermic, thermodynamically non-spontaneous, and goes from a random state to an ordered one. The findings suggest that SOâ‚‚ adsorption onto AC-DES follows a complex mixed mechanism involving both physisorption and chemisorption, with surface heterogeneity and adsorbate-adsorbent interactions playing a critical role in controlling the adsorption process.
  • Publication
    Comparative Performance of Catalytic and Non-Catalytic Pyrolysis of Sugarcane Bagasse in Catatest Reactor System
    ( 2020-04-30)
    Faraheen Kabir Ahmad S.
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    ; ; ;
    Sataimurthi O.
    Catalytic pyrolysis is a favourable process used to enhance the quality of bio-oil. Based on reviews from previous research there are only scarce of studies on the comparison of catalytic and non-catalytic pyrolysis of biomass such as rice husk, olive husk and corncob. In this study, sugarcane bagasse was selected as it has not been explored much yet. The target of this research is to compare the impact of catalytic and non-catalytic pyrolysis of sugarcane bagasse in terms of the yield, properties, and also the compositions of bio-oil. Catalytic and non-catalytic pyrolysis was executed in catatest bed reactor at temperatures 400°C to 550°C with the aids of ZSM-5 zeolite catalyst. Bio-oil from catalytic and no-catalytic pyrolysis which gives the maximum yield was used to be studied further in terms of the properties and chemical compositions. The result shows that the maximum yield of bio-oil was accomplished from catalytic pyrolysis at temperature 500°C which was 21.4%. The properties and composition of bio-oil from catalytic pyrolysis shows better result compare to non-catalytic pyrolysis.
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