Now showing 1 - 2 of 2
  • Publication
    Geopolymer ceramic application: a review on mix design, properties and reinforcement enhancement
    ( 2022) ; ;
    Rafiza Abdul Razak
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    Ikmal Hakem Aziz
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    Marcin Nabiałek
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    Ramadhansyah Putra Jaya
    ;
    Augustin Semenescu
    ;
    Rosnita Mohamed
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    Geopolymers have been intensively explored over the past several decades and considered as green materials and may be synthesised from natural sources and wastes. Global attention has been generated by the use of kaolin and calcined kaolin in the production of ceramics, green cement, and concrete for the construction industry and composite materials. The previous findings on ceramic geopolymer mix design and factors affecting their suitability as green ceramics are reviewed. It has been found that kaolin offers significant benefit for ceramic geopolymer applications, including excellent chemical resistance, good mechanical properties, and good thermal properties that allow it to sinter at a low temperature, 200 °C. The review showed that ceramic geopolymers can be made from kaolin with a low calcination temperature that have similar properties to those made from high calcined temperature. However, the choice of alkali activator and chemical composition should be carefully investigated, especially under normal curing conditions, 27 °C. A comprehensive review of the properties of kaolin ceramic geopolymers is also presented, including compressive strength, chemical composition, morphological, and phase analysis. This review also highlights recent findings on the range of sintering temperature in the ceramic geopolymer field which should be performed between 600 °C and 1200 °C. A brief understanding of kaolin geopolymers with a few types of reinforcement towards property enhancement were covered. To improve toughness, the role of zirconia was highlighted. The addition of zirconia between 10% and 40% in geopolymer materials promises better properties and the mechanism reaction is presented. Findings from the review should be used to identify potential strategies that could develop the performance of the kaolin ceramic geopolymers industry in the electronics industry, cement, and biomedical materials.
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  • Publication
    Influence of sintering temperature of kaolin, slag, and fly ash geopolymers on the microstructure, phase analysis, and electrical conductivity
    ( 2021)
    Nur Nadiah Izzati Zulkifli
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    ;
    Anna Przybył
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    Paweł Pietrusiewicz
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    ;
    Ikmal Hakem Aziz
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    Dariusz Kwiatkowski
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    Marcin Gacek
    ;
    Marek Gucwa
    ;
    Jitrin Chaiprapa
    This paper clarified the microstructural element distribution and electrical conductivity changes of kaolin, fly ash, and slag geopolymer at 900 °C. The surface microstructure analysis showed the development in surface densification within the geopolymer when in contact with sintering temperature. It was found that the electrical conductivity was majorly influenced by the existence of the crystalline phase within the geopolymer sample. The highest electrical conductivity (8.3 × 10−4 Ωm−1) was delivered by slag geopolymer due to the crystalline mineral of gehlenite (3Ca2Al2SiO7). Using synchrotron radiation X-ray fluorescence, the high concentration Ca boundaries revealed the appearance of gehlenite crystallisation, which was believed to contribute to development of denser microstructure and electrical conductivity.
      1  17