Mohd Fairus Ahmad
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Preferred name
Mohd Fairus Ahmad
Official Name
Mohd Fairus , Ahmad
Alternative Name
Shahimin, Mohd Faidz Mohamad
Mohamad Shahimin, M. F.
Main Affiliation
Scopus Author ID
57006554500
Researcher ID
B-9547-2018

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  • Publication
    Photoluminescence measurement of triplet sensitizer-emitter solution using a customized 3D-printed sample holder
    ( 2024-06)
    Kelvin Voon Yan Jie
    ;
    Safizan Shaari
    ;
    Mohd Fairus Ahmad
    ;
    Nor Farhani Zakaria
    ;
    Norhayati Sabani
    This study explores the photoluminescence (PL) measurement of triplet sensitizer-emitter (TSE) solutions using a custom 3D-printed sample holder, within the context of triplet-triplet annihilation based molecular photon upconversion (TTA-UC) systems targeting the Vis-to-UV spectral region. TTA-UC converts low-energy visible photons to higher-energy ultraviolet (UV) photons, holding promise for solar energy harvesting and photonics applications. Two TSE couples, 4CzIPN/TP and 4CzIPN/QP, were investigated, and their upconverted fluorescence spectra showed peaks at 344 nm and 354 nm / 370 nm, respectively, confirming efficient upconversion capabilities. The 3D-printed sample holder facilitated reproducible PL measurements, enabling the calculation of quantum yields (ΦUC). The 4CzIPN/TP and 4CzIPN/QP couples exhibited low quantum yields (0.028% and 0.043%, respectively), suggesting the need for improved deoxygenation methods to enhance the triplet-triplet annihilation process and overall quantum efficiency. Despite modest yields, successful UV upconverted fluorescence observation underscores the feasibility of the Vis-to-UV TTA-UC system. This study provides insights into TTA-UC optimization and demonstrates the utility of the 3D-printed sample holder for affordable and precise PL measurements, paving the way for future advancements in photonics and solar energy applications.