Now showing 1 - 2 of 2
  • Publication
    Photocatalytic fuel cell based on zinc oxide loaded carbon plate photoanode for simultaneous photocatalytic degradation of azo dyes and electricity generation
    ( 2020-01-01)
    Ong Y.P.
    ;
    Ho L.N.
    ;
    Ong S.A.
    ;
    ;
    Photocatalytic fuel cell (PFC) is promising to own its synchronous degradation of organic pollutants with electricity generation under illumination of light. The oxidation and reduction process promote the conversion of chemical energy in the pollutants into electrical energy. In this study, PFC is driven by the electrode reactions between the zinc oxide loaded carbon plate (ZnO/C) photoanode and carbon plate cathode under irradiation of UVA light. The ZnO/C photoanode was successfully fabricated by using simple ultrasonication-annealed method and investigated by XRD, SEM and EDX. To investigate the capability of the PFC, reactive red 120 (RR120), congo red (CR) and acid orange 7 (AO7) are employed well compared among themselves. The results indicated that the molecular structure of azo dyes with different adsorption of light by dye itself, number of azo bonds and sulfonic groups can be the crucial factors of decolorization in the PFC. The photocatalytic fuel cell with AO7 as sacrificial agent was able to perform 82.43% of decolorization efficiency, a maximum short circuit current (JSC) of 0.0017 mA cm-2 and maximum power density (Pmax) of 0.0886 µW cm -2.
  • Publication
    UVA-irradiated dual photoanodes and dual cathodes photocatalytic fuel cell: Mechanisms and Reactive Red 120 degradation pathways
    ( 2022-11-01)
    Ong Yong Por
    ;
    ; ; ; ;
    Thor Shen Hui
    ;
    Lee Sin Li
    ;
    Teoh Tean Peng
    To enhance dye removal and energy recovery efficiencies in single-pair electrode photocatalytic fuel cell (PFC-AC), dual cathodes PFC (PFC-ACC) and dual photoanodes PFC (PFC-AAC) were established. Results revealed that PFC-AAC yielded the highest decolorization rate (1.44 h−1) due to the promotion of active species such as superoxide radical (•O2−) and hydroxyl radical (•OH) when the number of photoanode was doubled. The results from scavenging test and UV-Vis spectrophotometry disclosed that •OH was the primary active species in dye degradation of PFC. Additionally, PFC-AAC also exhibited the highest power output (17.99 μW) but the experimental power output was much lower than the theoretical power output (28.24 μW) due to the strong competition of electron donors of doubled photoanodes to electron acceptors at the single cathode and its high internal resistance. Besides, it was found that the increments of dye volume and initial dye concentration decreased the decolorization rate but increased the power output due to the higher amount of sacrificial agents presented in PFC. Based on the abovementioned findings and the respective dye intermediate products identified from gas chromatography-mass spectrometry (GC-MS), the possible degradation pathway of RR120 was scrutinized and proposed.