Synthesis of zinc sulfide luminescent nanoparticles using zinc metal complexes of S-benzyl dithiocarbonate via microwave irradiation route

This paper reported highly luminous zinc sulfide (ZnS) nanoparticles grown by microwave-irradiated single molecular precursors. The precursor was obtained by Schiff bases of S-benzyl dithiocarbazate (SBDTC) ligand using 5-Bromo-4-hydroxy-3-methoxy-2-nitro Benzaldehyde; 4NNbiscyno diethylamino benzaldehyde and p-amino acetophenone. The nanoparticles obtained were characterized by X-ray diffraction studies for structural analysis, transmission electron micrographs (TEM) for morphological analysis, and UV-Vis spectra for optical analysis. X-ray diffractograms exhibit mixed structures analysis (wurtzite and cubic) for particles obtained using 5-Bromo-4-hydroxy-3-methoxy-2-nitro benzaldehyde and 4NNbiscyno diethylamino benzaldehyde. However, the particles obtained by p-amino acetophenone Schiff bases of SBDTC exhibit only wurtzite structure. Variation in optical properties is also observed with the precursors used. The excellent optical properties of ZnS nanoparticles signify the role of microwave irradiation in synthesis. The Photoluminescence (PL) study shows the luminescence in the visible region and the maximum intensity for ZnS particles obtained by zinc complex of p-amino acetophenone Schiff base of S-benzyl dithiocarbazate. The microwave-assisted process can be used for large-scale production of nanoparticles for emitting light in the visible region in various detecting and sensing applications