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  1. Home
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  3. Center of Excellence Geopolymer & Green Technology (CeGeoGTech)
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  5. Corrosion studies of fly ash and fly ash-slag based geopolymer
 
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Corrosion studies of fly ash and fly ash-slag based geopolymer

Journal
IOP Conference Series: Materials Science and Engineering
ISSN
1757-8981
1757-899X
Date Issued
2017-06
Author(s)
F F Zainal
Universiti Malaysia Perlis
S F M Amli
Universiti Malaysia Perlis
K Hussin
Universiti Malaysia Perlis
A Rahmat
Universiti Malaysia Perlis
M M A B Abdullah
Universiti Malaysia Perlis
DOI
10.1088/1757-899X/209/1/012026
Abstract
This paper presents the results of corrosion studies between Fly Ash Geopolymer (FG) paste and Fly Ash-Slag Geopolymer (FSG) paste. Geopolymer was made from aluminosilicate inorganic polymers mixed with the alkaline activator in order to reduce the carbon dioxide (CO₂) to the ecosystem. Samples then were cured at 60ºC for 24 hours in the oven. Reinforcement bar is placed at the center of the paste. The samples were examined after 7, 14 and 28 days in terms of Open Circuit Potential (OCP) test, phase analysis and morphology analysis. The potential values regarding OCP test for FSG paste from 7 days until 28 days are 0.464 V, 0.474 V and 0.498 V more positive than FG paste which the potential values are 0.087 V, 0.133 V and 0.206 V respectively. From the Pourbaix diagram, all the potential values for FG paste and FSG paste were located in the same Fe₂O₃, passivity region. Passive layer which is the oxide form exists in this region to protect the reinforcement bar from corrosion agents. It can be proved from phase analysis results which iron oxide hydroxide (FeOOH), hematite (Fe₂O₃) and magnetite (Fe₃O₄) peaks exist. The differences of morphological structures of these pastes were observed by Scanning Electron Microscope (SEM). It shows that FSG paste had good corrosion resistance and low corrosion rate compared to FG paste.
File(s)
Corrosion studies of fly ash and fly ash-slag based geopolymer (160424).pdf (1.6 MB)
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