Glycerolysis of Lauric Acid with Strontium Enhanced 12-Tungstophosphoric Acid Incorporated SBA-15: Material Characterization and Reusability Elucidation
Journal
Key Engineering Materials
ISSN
10139826
Date Issued
2022-01-01
Author(s)
Samsun N.S.
Abdullah A.Z.
Enche Ab Rahim S.K.
Teoh Y.P.
Shuit S.H.
DOI
10.4028/p-k8pd67
Handle (URI)
Abstract
SBA-15 was modified with strontium before being functionalized with HPW acid to investigate its performance and stability in the glycerolysis of lauric acid. The physical and chemical characteristics of the catalyst was analyzed using Fourier Transformed Infrared (FTIR), Scanning Electron Morphology (SEM), Surface analysis (BET), Transmission Electron Microscopy (TEM), and X-ray Diffraction (XRD). The collective evidence and finding from material characterizations, including the successfully formed and retained SBA-15 mesopores after modification twice, SrO formation and disappearance, post SrO modification and HPW incorporation, respectively, further strengthen the claim of the strong anchoring of HPW onto the SBA-15 via the strontium-salt bridge. The reusability of the lauric acid conversion was also evaluated. The superior stability of the synthesized catalyst (HPW/SrSBA-15) was demonstrated minimal to none change in both lauric acid conversion (75.34%) and monolaurin yield (38.9%). Such result was attributed to the good interaction between HPW and SBA-15 via strontium modification and proved that the catalyst does not undergo severe deactivation and showed good catalytic activity in recycled use.
Funding(s)
Ministry of Higher Education, Malaysia
Subjects
File(s)