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  • Publication
    Comparative mechanical and microstructural properties of high calcium fly ash one-part geopolymers activated with Na₂SiO₃-anhydrous and NaAlO₂
    ( 2021)
    Ooi Wan-En
    ;
    ; ; ; ; ;
    Ong Shee-Ween
    ;
    Ng Hui-Teng
    ;
    Ng Yong-Sing
    ;
    ;
    Long-Yuan Li
    This paper investigates the effect of varying solid alkali activators on the fresh and hardened properties and microstructural changes of one-part geopolymers (OPGs). Single and binary solid alkali activators were used to activate high calcium fly ash. The alkali activators were either solely sodium metasilicate (Na₂SiO₃) or a combination of sodium aluminate (NaAlO₂) and sodium metasilicate (Na₂SiO₃). The OPG activated with anhydrous Na₂SiO₃ achieved an excellent 28-day compressive strength of 83.6 MPa while OPG activated with NaAlO₂ and Na₂SiO₃ attained a compressive strength of 45.1 MPa. The Na₂SiO₃-activated OPG demonstrated better fluidity than the OPG activated with NaAlO₂ and Na₂SiO₃ due to the thixotropic behaviour caused by the NaAlO₂. The Na₂SiO₃-activated OPG consisted of sodium-calcium aluminium silicate hydrate ((N,C)-A-S-H) gel phase, while the OPG activated with NaAlO₂ and Na₂SiO₃ comprised of the coexistence of sodium aluminium silicate hydrate (N-A-S-H) and calcium aluminium silicate hydrate (C-A-S-H) gel phases. Regardless of the distinctive properties, the OPGs are adequate for building materials applications.
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